Tetra chlorocopper(II) chemistry: delineation of optical, thermal properties

The thermal decomposition paths of pyridinium tetra chlorocopper(II) (A) differs from the anilinium tetra chlorocopper(II) (B). In the case of pyridinium tetra chlorocopper(II) it loses two molecules of pyridinium hydrochloride and CuCl₂ is formed in the temperature range of 140–350 °C. Whereas the anilinium tetra chlorocopper(II) (B) loses one mole of anilinum hydrochoride along with one molecule of aniline. The compound B has a well define structural change taking place in the region of 70–110 °C which is reflected in DSC as well as resistance measurements. The p-methoxy anilinium tetra chlorocopper(II) monohydrate (C) shows solvatochromicity. The absorption maximum of p-methoxy anilinium tetra chlorocopper(II)monohydrate in acetonitrile (460 nm) changes to 570 nm on addition of methanol. The absorption at 570 nm can be switched back to 460 nm by suppression of ligand exchange with addition of hydrochloric acid. Thus, chemically driven optical switching properties can be observed.     

On pressure separation algorithms (PSepA) for improving the accuracy of incompressible flow simulations

We investigate a special technique called ‘pressure separation algorithm’ (PSepA) (see Applied Mathematics and Computation 2005; 165 :275–290 for an introduction) that is able to significantly improve the accuracy of incompressible flow simulations for problems with large pressure gradients. In our numerical studies with the computational fluid dynamics package FEATFLOW ( www.featflow.de ), we mainly focus on low‐order Stokes elements with nonconforming finite element approximations for the velocity and piecewise constant pressure functions. However, preliminary numerical tests show that this advantageous behavior can also be obtained for higher‐order discretizations, for instance, with Q₂/P₁ finite elements. We analyze the application of this simple, but very efficient, algorithm to several stationary and nonstationary benchmark configurations in 2D and 3D (driven cavity and flow around obstacles), and we also demonstrate its effect to spurious velocities in multiphase flow simulations (‘static bubble’ configuration) if combined with edge‐oriented, resp., interior penalty finite element method stabilization techniques. Copyright © 2008 John Wiley & Sons, Ltd.     

Optically driven actuators using poly(vinylidene difluoride)

Optically driven actuators have a feature of a non-contact method supplied by light energy. A new method is proposed with three poly(vinylidene difluoride) (PVDF) cantilevers as the legs and a polymer film as the body. The PVDF cantilevers are coated with silver on one surface. When one side of the cantilever is irradiated by a laser beam, an electric field is produced along a cross-section of the cantilever by the pyroelectric effect and a mechanical displacement occurs by the piezoelectric effect. Its response time and its generated force are measured experimentally. Two types of optically driven actuators using PVDF film are proposed to move using different characteristics.     

Ultrasound velocimetry of ferrofluid spin-up flow measurements using a spherical coil assembly to impose a uniform rotating magnetic field

Ferrofluid spin-up flow is studied within a sphere subjected to a uniform rotating magnetic field from two surrounding spherical coils carrying sinusoidally varying currents at right angles and 90° phase difference. Ultrasound velocimetry measurements in a full sphere of ferrofluid shows no measureable flow. There is significant bulk flow in a partially filled sphere (1-14 mm/s) of ferrofluid or a finite height cylinder of ferrofluid with no cover (1-4 mm/s) placed in the spherical coil apparatus. The flow is due to free surface effects and the non-uniform magnetic field associated with the shape demagnetizing effects. Flow is also observed in the fully filled ferrofluid sphere (1-20 mm/s) when the field is made non-uniform by adding a permanent magnet or a DC or AC excited small solenoidal coil. This confirms that a non-uniform magnetic field or a non-uniform distribution of magnetization due to a non-uniform magnetic field are causes of spin-up flow in ferrofluids with no free surface, while tangential magnetic surface stress contributes to flow in the presence of a free surface.Recent work has fitted velocity flow measurements of ferrofluid filled finite height cylinders with no free surface, subjected to uniform rotating magnetic fields, neglecting the container shape effects which cause non-uniform demagnetizing fields, and resulting in much larger non-physical effective values of spin viscosity η′∼10⁻⁸−10⁻¹² N s than those obtained from theoretical spin diffusion analysis where η′≤10⁻¹⁸ N s. COMSOL Multiphysics finite element computer simulations of spherical geometry in a uniform rotating magnetic field using non-physically large experimental fit values of spin viscosity η′∼10⁻⁸−10⁻¹² N s with a zero spin-velocity boundary condition at the outer wall predicts measureable flow, while simulations setting spin viscosity to zero (η′=0) results in negligible flow, in agreement with the ultrasound velocimetry measurements. COMSOL simulations also confirm that a non-uniform rotating magnetic field or a uniform rotating magnetic field with a non-uniform distribution of magnetization due to an external magnet or a current carrying coil can drive a measureable flow in an infinitely long ferrofluid cylinder with zero spin viscosity (η′=0).     

Spike patterns in a reaction–diffusion ODE model with Turing instability

We explore a mechanism of pattern formation arising in processes described by a system of a single reaction–diffusion equation coupled with ordinary differential equations. Such systems of equations arise from the modeling of interactions between cellular processes and diffusing growth factors. We focus on the model of early carcinogenesis proposed by Marciniak‐Czochra and Kimmel, which is an example of a wider class of pattern formation models with an autocatalytic non‐diffusing component. We present a numerical study showing emergence of periodic and irregular spike patterns because of diffusion‐driven instability. To control the accuracy of simulations, we develop a numerical code on the basis of the finite‐element method and adaptive mesh grid. Simulations, supplemented by numerical analysis, indicate a novel pattern formation phenomenon on the basis of the emergence of nonstationary structures tending asymptotically to a sum of Dirac deltas. Copyright © 2013 John Wiley & Sons, Ltd.     

Goal achieving probabilities of cone‐constrained mean‐variance portfolios

In this paper, we establish closed‐form formulas for key probabilistic properties of the cone‐constrained optimal mean‐variance strategy, in a continuous market model driven by a multidimensional Brownian motion and deterministic coefficients. In particular, we compute the probability to obtain to a point, during the investment horizon, where the accumulated wealth is large enough to be fully reinvested in the money market, and safely grow there to meet the investor's financial goal at terminal time. We conclude that the result of Li and Zhou [Ann. Appl. Prob., v.16, pp.1751–1763, (2006)] in the unconstrained case carries over when conic constraints are present: the former probability is lower bounded by 80% no matter the market coefficients, trading constraints, and investment goal. We also compute the expected terminal wealth given that the investor's goal is underachieved, for both the mean‐variance strategy and the aforementioned hybrid strategy where transfer to the money market occurs if it allows to safely achieve the goal. The former probabilities and expectations are also provided in the case where all risky assets held are liquidated if financial distress is encountered. These results provide investors with novel practical tools to support portfolio decision‐making and analysis. Copyright © 2013 John Wiley & Sons, Ltd.     

Strong competition model with non-uniform dispersal in a heterogeneous environment

In this study, a strong competition model was considered between two species in a heterogeneous environment. For a system with two different constant diffusion rates for each competitor, the fast diffuser can be selected evolutionally under suitable assumptions if the competing interaction between the species is strong. We also claim that a strongly interacting competition leads to a more evolutionary selection than that with the same population dynamics if a species moves with a certain non-uniform dispersal. Furthermore, species with a certain non-uniform dispersal have a competitive advantage over linear random diffusers. In addition, a species with highly sensitive dispersal response to the environment may survive. These strongly competitive advantages were demonstrated by investigating the stability of semi-trivial solutions of the system with non-uniform dispersal and comparing it to the conditions of the model with constant diffusion.     

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对EAST中性束反向注入过程中等离子体加热和电流驱动进行了实验研究,并采用了美国普林斯顿大学等离子体物理实验室开发的TRANSP程序对高功率中性束注入过程中能量热输运进行了分析.结果表明,中性束注入可有效提高本底等离子体温度,产生束驱动非感应电流,提高等离子体旋转以及有效改善等离子体约束.     

格子Boltzmann方法中的曲边界处理

研究了格子Boltzmann方法中实现曲边界条件的3种格式,对它们的精度和稳定性进行了分析和比较.通过二维Poiseuille流和等边三角域上空腔流的模拟,讨论了这3种格式的数值精度和稳定性.