激基复合物给体作间隔层对激子复合区域的调节

为研究激基复合物器件激子复合区域的变化,在TPD/BPhen界面可形成激基复合物发光的基础上,以Ir(pq)2(acac)为探测层,制备器件ITO/Mo O_3(2.5 nm)/TPD((40-x)nm)/Ir(pq)2(acac)(0.5 nm)/TPD(x,x=0,3,6,10 nm)/BPhen(40 nm)/Cs2CO_3/Al,其中靠近BPhen的TPD称之为间隔层。电致发光光谱表明,该组器件的激子复合区域主要位于Ir(pq)2(acac)薄层和TPD/BPhen界面,分别发射595 nm和478 nm的光。随着TPD间隔层厚度的增加和电压的升高,发光区域向激基复合物区域(TPD/BPhen界面)移动,即更多的电子和空穴在TPD/BPhen界面形成激基复合物发光,Ir(pq)2(acac)发光减弱。当间隔层厚度由0 nm增至10nm时,6 V电压下的Ir(pq)2(acac)和激基复合物发光强度的比值由44降至1.5。对于间隔层厚度为6 nm的器件,Ir(pq)2(acac)和激基复合物发光强度的比值由6 V时的2.8降至10 V时的1.0。由此可见,激基复合物给体作间隔层能有效调节激子复合区域。     

纵波速度径向层析成像分析

钻井会造成近井壁附近岩石的声学性质改变,为研究纵波径向探测特性,本文使用径向柱状分层模型,应用二维轴对称有限差分法详细考察了过渡带厚度、声源频率以及接收器源距变化下,单极子测井响应的变化特征,并采用慢度-时间相关法研究了不同条件下所测量到的声速变化。最后基于射线理论,分析了不同条件下的首波到时变化特征。基于地层速度逐渐增加的模型表明,纵波的径向探测特性受源距影响较大,通过不同源距信号的组合,可以实现对近井壁纵波速度进行层析成像。     

Strength and equation of state of molybdenum triboride under 80 GPa pressure,using radial X-ray diffraction

The strength and equation of state of molybdenum triboride have been determined under nonhydrostatic compression up to 80?GPa, using an angle-dispersive radial X-ray diffraction technique in a diamond anvil cell (DAC). The RXD data yield a bulk modulus and its pressure derivative as K_0?=?342(6)?GPa with K₀′?=?2.11(17) at ψ?=?54.7°. Analysis of diffraction data using the strain theory indicates that the ratio of differential stress to shear modulus (t/G) ranges from 0.002 to 0.050 at pressures of 4–80?GPa. Together with theoretical results on the high pressure shear modulus, our results here show that molybdenum triboride sample under uniaxial compression can support a differential stress of ～10?GPa when it started to yield with plastic deformation at ～30?GPa. In addition, we draw a conclusion that MoB₃ is not a superhard material but a hard material.     

Effect of power ultrasound on crystallization characteristics of magnesium ammonium phosphate

Magnesium ammonium phosphate (MAP) crystallization could be utilized for the recovery of phosphorus from wastewater. However, the effectiveness of the recovery is largely determined by the crystallization process, which is very hard to be directly observed. As a result, a specific ultrasonic device was designed to investigate the crystallization characteristics of MAP under various ultrasonic conditions. The results demonstrated that the metastable zone width (MZW) narrowed along with the rising of the ultrasonic power. Similarly, for the 6 mM MAP solution, with the ultrasonic power gradually enhanced from 0 W to 400 W, the induction time was shortened from 340 s to 38 s. Meanwhile, the crystallization rate was accelerated till the power reached 350 W, and then remained a constant value. It can be observed from the scanning electron microscopy (SEM), the MAP crystal became bigger in size as well as the crystal size distribution (CSD) became broad and uneven, with the increase of ultrasonic power. The results indicate that the crystallization process enhanced by power ultrasound could be used as an effective method to eliminate and recover the phosphorus from wastewater.     

基于激光光解诱导荧光技术实现燃烧反应区及中间产物CH_3瞬态可视化

实现火焰反应区和不同中间组分的在线二维瞬态成像,在湍流燃烧的基础研究中具有十分重要的意义。用Nd∶YAG激光器的5倍频输出(212.8nm)作为光源,通过激光光解诱导荧光技术在甲烷/空气预混火焰中,成功实现了火焰反应区的瞬态成像,并首次采用该技术实现了CH_3的在线瞬态成像测量。分析了该方法同其他荧光标示物在反应区二维瞬态成像方法的优势,并研究了火焰燃烧过程中其他燃烧中间产物和不同燃空比对CH_3单脉冲成像的影响,讨论了现有条件下该技术的应用范围。根据实验结果,在燃空比Φ=1.2的条件下,在反应区我们获得了信噪比约为8的单脉冲成像,分析火焰中CH_3的单脉冲成像结果可知火焰燃空比在1.0~1.4之间时,或者火焰中CH_3的浓度大于9.3×1015 molecules·cm-3信噪比较好。该项技术在动力机械及其他研究领域的应用有十分重要的参考价值。     

调制自由载流子吸收测量半导体载流子输运参数的三维理论

推导出用于测量半导体载流子输运特性(载流子寿命、载流子扩散系数和前表面复合速度)的调制自由载流子吸收(modulated free carrier absorption, MFCA)检测技术的三维理论模型,给出了调制自由载流子吸收检测信号与调制频率和抽运-探测光相对距离的关系.定性分析了在不同调制频率时各个载流子输运参数对径向位置扫描曲线(信号与两束光相对距离的关系)的影响,结果表明调制自由载流子吸收检测信号对各个参数的灵敏度随抽运-探测光相对距离的增加而增加.仿真和实验结果表明,通过拟合不同调制频率时调 关键词： 调制自由载流子吸收 载流子输运特性 径向位置扫描     

Sonoluminescence intensity and ultrasonic cavitation temperature in organic solvents: Effects of generated radicals

Ultrasonic cavitation in organic solvents remains poorly understood in contrast with aqueous systems, largely because of complexities related to solvent decomposition. In this study, we sonicated different types of organic solvents (i.e. linear alkanes, aliphatic alcohols, aromatic alcohols, and acetate esters) under argon saturation. The average temperature of the cavitation bubbles was estimated using the methyl radical recombination method. We also discuss the effects of the physical properties of the solvents, such as vapor pressure and viscosity, on the cavitation temperature. The average cavitation bubble temperature and sonoluminescence intensity were higher in organic solvents with lower vapor pressure; for aromatic alcohols, these values were particularly high. It was found that the specific high sonoluminescence intensities and average cavitation temperatures exhibited in aromatic alcohols are caused by the highly resonance-stable generated radicals. The results obtained in this study are very useful for acceleration of sonochemical reaction in organic solvents, which are indispensable for organic synthesis and material synthesis.     

小角度纵波水浸超声检测技术在消除锻件结构盲区中的应用

航空发动机中的后轴颈锻件一般采用水浸超声纵波直入射方法检测内部缺陷。由于型面结构的问题,在锻件的直筒和锥形段连接区域存在检测盲区。该文针对某型号发动机中的后轴颈锻件,开展了水浸超声检测工艺研究,提出利用小角度纵波覆盖盲区的思路。通过对含有人工缺陷的模拟样件的检测实验,比较了水浸纵波直入射和小角度纵波斜入射两种检测方法对后轴颈连接区域的覆盖能力。结果表明,该文提出的小角度纵波方法,可以有效检测出水浸纵波直入射检测方法无法发现的人工缺陷,消除由结构引起的检测盲区,保障零件的服役安全。     

毛细管电泳法快速分离和检测肠毒性大肠杆菌

 建立了快速分离和检测引起仔猪腹泻的肠毒性大肠杆菌K88、K99和 987P细菌细胞的毛细管区带电泳方法 ,并进行了腹泻仔猪粪便中肠毒性大肠杆菌的应用检测分析。结果表明 ,在电泳缓冲液为 0 0 5mol/LNa2 CO3 NaHCO3(pH 9 9)、分离电压为 1 4 1kV、检测波长为 2 1 0nm的电泳条件下 ,E coliK88、K99和 987P的细胞分别具有单一、稳定的特征谱峰 ,其保留时间的相对标准偏差RSD≤ 0 9% ;在确定的实验条件下 ,实现了腹泻仔猪粪便中肠毒性大肠杆菌的快速检测分析 ,发现将出生 5d～ 6d的腹泻仔猪粪便引入培养基中增殖后主要检出K88。     

核物质对称能和重离子碰撞中径向流阈能的同位旋效应

基于同位旋相关的量子分子动力学模型，采用三种不同形式的对称势，研究了¹²⁴Sn+¹²⁴Sn和¹²⁴Ba+¹²⁴Ba对心碰撞时在三种不同对称势下的径向膨胀流，发现径向膨胀流阈能与所采用的对称能形式密切相关，表现出明显同位旋效应，预示着径向膨胀流阈能的同位旋相关性可作为对称能的灵敏探针. 关键词： 径向膨胀流阈能 同位旋效应 重离子碰撞 同位旋相关的量子分子动力学模型