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91.
Dispersion of MoO3, NiO, ZnO on rutile TiO2 with low specific surface area was studied with Mercury Porosimeter, SEM, XPS and Ammonia Extraction method. The dispersion thresholds of MoO3, NiO, ZnO on three rutile TiO2 carriers were obtained with XPS, and com-pared with those on anatase TiO2 with high specific surf are area. Ammonia Extraction method was used to identify the surface oxide species interarting with support surface in different strength and it was found that the proportions of oxides that can not be extracted by ammonia extraction are different for MoO3, NiO and ZnO which are supported on rutile TiO2. 相似文献
92.
采用XAFS方法研究浸渍法制备并于低温焙烧的CuO/γ-Al2O3催化剂的局域结构.对于CuO负载量小于单层分散阈值的CuO/γ-Al2O3(0.4 mmol/100 m2),结果表明,CuO物种是以层状分散的孤立原子簇存在于γ-Al2O3载体表面,其第一近邻Cu-O配位环境的结构与晶态CuO的相似,键长和配位数分别为0.195 nm和4.对于CuO负载量等于单层分散阈值的CuO/γ-Al2O3(0.8 mmol/100 m2),已有少量的CuO纳米颗粒生成.对于CuO负载量大于单层分散阈值的CuO/γ-Al2O3(1.2 mmol/100 m2),其结构与多晶CuO的相近.基于CuO在γ-Al2O3载体上的三种不同分散状态的结构特点,我们提出了CuO/γ-Al2O3催化剂的结构模型. 相似文献
93.
R.-L. Yun Y.-M. Chang C.-H. Lin K.-H. Hu C.-M. Shu 《Journal of Thermal Analysis and Calorimetry》2006,85(1):107-113
In industrial processes, information
on the safety property of chemicals is essentially crucial for safe handling
during unit operations. Ensuring the safe use of combustible or flammable
substances in processes is unlikely without detailed investigations of their
flammability characteristics and related hazards. We studied 3-methyl pyridine
(3-picoline), e.g., flammability limits (LFL/UFL), maximum explosion pressure
(P
max), maximum
explosion pressure rise (dP/dt)max, minimum oxygen concentration
(MOC), vapor deflagration index (K
g),
and characterized the influence of inert steam (H2O)
on critical parameters for 3-picoline/water mixtures at 270°C, 1 atm,
various oxygen concentrations, and vapor mixing ratios (100/0, 30/70, 10/90
and 5/95 vol.%) with a 20-L-Apparatus in simulated conditions, respectively.
The results showed that the flammability characteristics
of 3-picoline(aq) all increased with the oxygen concentration.
However, as the composition of inert steam increased, the flammability parameters
and the degree of fire and explosion hazards were significantly reduced, instead.
This study elucidated the flammability properties of 3-picoline mixed with
inert steam. The conclusions could be applied to proactively prevent the relevant
processes from incurring fire and explosion accidents. 相似文献
94.
Minshou Zhao Xinbo Zhang Yujun Chai Changying Sun 《Research on Chemical Intermediates》2006,32(5):403-417
The structures and the electrochemical characteristics of La0.7−x
CexMg0.3Ni2.8Co0.5 (x = 0.1–0.5) alloy, Ti0.25−x
ZrxV0.35Cr0.1Ni0.3 (x = 0.05–0.15) alloy and AB3<x<5-type alloy, which are the representative examples of AB3-type alloy, solid solution alloy and non-AB5-type alloy, respectively, have been investigated, and the performances of MH-Ni battery in which AB3<x<5 type alloy is used as the negative electrode material are examined at relatively low temperature. 相似文献
95.
J. L. Daft 《Journal of separation science》1983,6(9):480-487
Residue mixtures of pesticides in foods which were difficult to separate by packed-column gas chromatography were determined by capillary gas chromatography and electron capture detection. Manual injections of sample and reference standard were made with a 10 μL syringe on a septum-enclosed, split/ splitless inlet system. Optimal peak height repeatability (± 3%( was achieved with three-μL injections which were made within time periods of four hours or less. The average linearity coefficient (slope( obtained for detector response as a function of solution concentration was 1.1. 相似文献
96.
Dispersion of copper(Ⅱ) phthalocyanine (CuPc), copper(Ⅱ) phthalocyaninesulfonate (CuPcS) and cobalt(Ⅱ)phthalocyaninetetrasulfonate (CoPcTS) on the surface of titanium dioxide was investigated by XRD, XPS, FT-IR and UV-Vis techniques. Results show that interaction between CuPc and TiO2 was very weak and CuPc was difficult to disperse on the surface of the support. While partly sulfurized CuPcS could be dispersed on the surface of support through sulfo-groups and its dispersion capacity was determined to be 0.085 g CuPcS/g TiO2. Completely sulfurlzed CoPcTS could also be dispersed on the surface of TiO2 as a monolayer and its dispersion capacity was 0.12 g CoPcTS/g TiO2. Interactions of the sulfo-groups as well as the electrons of CoPcTS with the surface of TiO2 could be evidenced by FT-IR characterization. Therefore, it was suggested that CoPcTS molecules be adsorbed on the surface of TiO2 in a flat-lying mode while CuPcS in a slanting one. UV-Vis spectra show that the dispersed CuPcS and CoPcTS molecules exist in both forms of monomers and dimers. 相似文献
97.
Application of matrix solid-phase dispersion in the analysis of priority polycyclic aromatic hydrocarbons in fish samples 总被引:1,自引:0,他引:1
The performance of matrix solid-phase dispersion (MSPD) for the extraction of polycyclic aromatic hydrocarbons (PAHs) in fish tissue is described. The suitability of different solid supports was tested as well as the influence on the extraction efficiency of the natural fat content in samples. Under optimal conditions 0.6-0.8 g of tissue sample, are dispersed with 2 g of octadecylsiloxane (C18) and 0.5 g of anhydrous sodium sulphate and transferred to the top of a polyethylene solid-phase extraction cartridge which already contains 2 g of florisil and 1 g of C18. Cartridges were eluted with acetonitrile. The analysis of the extracts was carried out by high-performance liquid chromatography (HPLC) coupled with fluorescence detection. The proposed method provides detection limits between 0.04 and 0.32 ng/g for the different considered PAHs, below the maximum levels established by the some regulatory bodies for the six PAHs after recent oil spill episodes and European Union regulations. Recoveries over 80% were obtained for all compounds. Accuracy validation was carried out using the US National Institute of Standards and Technology (NIST) SRM 2977 reference material. 相似文献
98.
A. R. Demlow D. V. Eldred D. A. Johnson E. F. Westrum Jr. 《Journal of Thermal Analysis and Calorimetry》1998,52(3):1055-1062
This paper represents a fitting (modeling) of the temperature dependence of the Komada-Westrum characteristic temperature
for those γ-, δ- and ε-phase lanthanide sesquisulfides for which the total heat capacities, including internal degrees of
freedom (e.g., Schottky and magnetic contributions), were connected to the residue of only lattice vibrations yielding lattice
heat-capacity contributions. These characteristic temperatures (θKW) at 298.15 K are seen to behave smoothly (nearly linearly) as a function of (cationic) atomic number within the region of
stability of each phase as does the density. The trends between the phases also show some consistency but not predictability
of one from the other.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
99.
Fernando A Iñón 《Analytica chimica acta》2003,477(1):59-71
A mathematical model for fitting the experimental ICM (integrated conductimetric method) curves developed by the authors in a previous work, is presented for the first time in this study. The proposed model fits the experimental curves with great precision and allows to predict physical dispersion for single-line flow injection system. The correlation of the model’s parameters with typical reactionless FIA peak parameters is also assessed. The IDQ coefficient—a novel dispersion estimator previously reported by the authors—can also be predicted when operational FIA variables are changed. Experimental and modelled profiles are compared as a function of the system’s variables, showing an excellent agreement. 相似文献
100.
Surface composition and property of film prepared with aqueous dispersion of polyurethaneurea-acrylate including fluorinated block copolymer 总被引:1,自引:0,他引:1
The aqueous dispersion of polyurethaneurea-acrylate (PUA) including small amount of fluorinated block copolymers containing carboxyl groups (PATF), which can be dissolved in water, was used to make films and the surface properties of these films were examined. The experimental data show that the modified PUA film exhibits a hydrophobic surface property, although the original surface of PUA film is hydrophilic. The surface composition of the modified PUA film was measured by ATR and XPS. The results indicate that there is a concentration gradient of the fluorine groups along the lines of thickness of the modified film and towards the outmost surface layer, resulting from the migration of fluorinated blocks to the air side surface of the modified PUA film during the film formation process. However, the PUA film can not be modified effectively by adding the sodium salt of PATF, since the urethane groups in the system are easy to occupy on the surface of the film. 相似文献