CdZnTe晶体位错处的Raman光谱及PL谱研究

利用显微Raman光谱技术,对比研究了CdZnTe晶体无位错区和位锘密集区的Raman光谱.研究发现,CdZnTe晶体无位错区的Raman光谱出现了与Te有关的A1模(119 cm-1)、类CdTe的TO1模(138 cm-1)和类ZnTe 的TO2模(179 cm-1);CdZnTe晶体位错密集区的Raman光谱中仅出现了与Te有关的A1模和类CdTe的TO1模,CdZnTe晶体类ZnTe的TO2模消失.对CdZnTe试样位错密集区进行变温光致发光谱测试,结果表明,束缚在中性施主上的激子的离解为电子空穴对,电子空穴的非辐射复合过程吸收了类ZnTe的TO2模声子能量,造成Raman 光谱中类ZnTe的TO2模缺失.     

热交换法生长c面取向大尺寸蓝宝石晶体的研究

本文使用热交换法直接生长c面取向,尺寸为φ170 mm× 160 mm,重12 kg的蓝宝石晶体.晶体无色透明,内部无散射颗粒.沿c面(0001)方向的晶棒锥光图可观察到同心圆簇的干涉条纹,仅中心较小区域因内应力存在,干涉条纹发生扭曲.将抛光的晶片进行化学腐蚀后,通过金相显微镜检测位错腐蚀坑形貌图,结果显示,腐蚀坑呈三角形,平均位错密度较低,为1.98 × 103 Pits/cm2,X射线衍射半峰宽较小,晶体结构完整.     

Analysis of main shock of thrust fault earthquake by catastrophe theory

The relationship between work and energy increment of a thrust fault system with quasi-static deformation can be decomposed into two parts: volume strain energy and deviation stress energy. The relationship between work and energy increment of the deviation stress of a simplified thrust fault system is analyzed based on the catastrophe theory. The research indicates that the characteristics displayed by the fold catastrophe model can appropriately describe the condition of earthquake generation, the evolvement process of main shock of thrust fault earthquake, and some important aftershock properties. The bigger the surrounding press of surrounding rock is, the bigger the maximum principal stress is, the smaller the incidences of the potential thrust fault surface are, and the smaller the ratio between the tangential stiffness of surrounding rock and the slope is, which is at the inflexion point on the softened zone of the fault shearing strength curve. Thus, when earthquake occurrs, the larger the elastic energy releasing amount of surrounding rock is, the bigger the earthquake magnitude is, the larger the half distance of fault dislocation is, and the larger the displacement amplitude of end face of surrounding rock is. Fracturing and expanding the fault rock body and releasing the volume strain energy of surrounding rock during the earthquake can enhance the foregoing effects together.     

Discrete dislocation dynamics modelling of mechanical deformation of nickel-based single crystal superalloys

Discrete dislocation dynamics (DDD) has been used to model the deformation of nickel-based single crystal superalloys with a high volume fraction of precipitates at high temperature. A representative volume cell (RVC), comprising of both the precipitate and the matrix phase, was employed in the simulation where a periodic boundary condition was applied. The dislocation Frank-Read sources were randomly assigned with an initial density on the 12 octahedral slip systems in the matrix channel. Precipitate shearing by superdislocations was modelled using a back force model, and the coherency stress was considered by applying an initial internal stress field. Strain-controlled loading was applied to the RVC in the [0 0 1] direction. In addition to dislocation structure and density evolution, global stress-strain responses were also modelled considering the influence of precipitate shearing, precipitate morphology, internal microstructure scale (channel width and precipitate size) and coherency stress. A three-stage stress-strain response observed in the experiments was modelled when precipitate shearing by superdislocations was considered. The polarised dislocation structure deposited on the precipitate/matrix interface was found to be the dominant strain hardening mechanism. Internal microstructure size, precipitate shape and arrangement can significantly affect the deformation of the single crystal superalloy by changing the constraint effect and dislocation mobility. The coherency stress field has a negligible influence on the stress-strain response, at least for cuboidal precipitates considered in the simulation. Preliminary work was also carried out to simulate the cyclic deformation in a single crystal Ni-based superalloy using the DDD model, although no cyclic hardening or softening was captured due to the lack of precipitate shearing and dislocation cross slip for the applied strain considered.     

THE DISLOC ATION EQU ATIONS OF A SIMPLE CUBIC CRYSTAL IN THE ISOTROPIC APPROXIMATION-A SOLVABLE MODEL

The dislocation equations of a simple cubic lattice have been obtained by using Green's function method based on the discrete lattice theory with the coefficients of the secondorder differential terms ...     

含非完整界面涂层夹杂中螺型位错的弹性分析

研究了含非完整界面圆形涂层夹杂内部一个螺型位错在夹杂、涂层与无限大基体材料中产生的弹性场.运用复变函数函数方法,获得了三个区域复势函数的解析解答.利用求得的应力场和Peach-Koehler公式,得到了作用在螺型位错上位错力的精确表达式.主要讨论了两个非完整界面对位错力的影响规律.结果表明,涂层界面对夹杂内部螺型位错的吸引力随着界面粘结强度的弱化而变大.界面非完整程度增加削弱材料弹性失配对位错力的影响.在一定条件下,非完整界面可以改变夹杂内位错与涂层/基体系统之间的引斥干涉规律,并使位错在夹杂内部产生一个稳定或非稳定的平衡点.     

Nucleation of partial dislocations at a crack and its implication on deformation mechanisms of nanostructured metals

Nucleation of partial dislocations at a crack is analyzed based a multiscale model that incorporates atomic information into continuum-mechanics approach. The crack and the slip plane as the extension of the crack are modeled as a surface of displacement discontinuities embedded in an elastic medium. The atomic potential between the adjacent atomic layers along the slip plane is assumed to be the generalized stacking fault energy, which is obtained based on atomic calculations. The relative displacements along the slip plane, corresponding to the configurations of partial dislocations and stacking faults, are solved through the variational boundary integral method. The energetics of partial dislocation nucleation at the crack in FCC metals Al and Cu are comparatively studied for their distinctive difference in the intrinsic stacking fault energy. Compared with nucleation of perfect dislocations in previous studies, several new features have emerged. Among them, the critical stress and activation energy for nucleation of partial dislocations are markedly lowered. Depending on the value of stacking fault energy and crack configuration, the saddle-point configurations of partial dislocations can be vastly different in terms of the nucleation sequence and the size of the stacking fault. These findings have significant implication for identifying the fundamental dislocation and grain-boundary-mediated deformation mechanisms, which may account for the limiting strength and the high strain rate sensitivity of nanostructured metals.     

THERMODYNAMIC VARIATIONAL APPROACH FOR CLIMB OF AN EDGE DISLOCATION

A general thermodynamic variational approach is applied to study the force on an edge dislocation, which drives the dislocation to climb. Our attention is focused on the physical mechanism responsible for dislocation climb. A dislocation in a material element climbs as a result of vacancies diffusing into or out from the dislocation core, with the dislocation acting as a source or a sink for vacancy diffusion in the material element. The basic governing equations for dislocation climb and the climb forces on the dislocation are obtained naturally as a result of the present thermodynamic variational approach.     

Analysis of grain size effects on transformation-induced plasticity based on a discrete dislocation-transformation model

There is much interest recently in the possibility of combining two strengthening effects, namely the reduction of grain size (Hall-Petch effect) and the transformation-induced plasticity effect (strengthening due to a martensitic transformation). The present work is concerned with the analysis of the combination of these two effects using a discrete dislocation-transformation model. The transformation-induced plasticity mechanism is studied for aggregates of grains of ferrite and austenite of different sizes. The discrete model allows to simulate the behavior at sub-grain length scales, capturing the complex interaction between pile-ups at grain boundaries and the evolution of the microstructure due to transformation. The simulations indicate that, as the average grain size decreases, the relative strengthening due to the formation of martensite is significantly reduced and that the overall strengthening is mostly due to a Hall-Petch effect. This finding suggests that strengthening by the transformation-induced plasticity mechanism is ineffective in the presence of fine-grained microstructures.     

FeCrNi合金静动态物理本构模型研究

以金属材料塑性变形的位错动力学为基础,将FeCrNi合金的流动应力分解为非热应力和热激活应力两部分.通过对该合金屈服应力随温度变化特性、屈服应力的应变速率特性、孪晶组织的温度特性及位错组态的应变速率特性进行分析,认为非热应力不只是应变的函数,还与温度和应变速率相关,因此对Johnson-Cook模型方程形式进行修正以描述非热应力. 同时认为影响热激活应力的微结构参数主要为位错阻碍间距\Deltal, 定义并推导出表征\Delta l演化的g函数的表达式,将其引入Kocks的热激活方程,从而建立FeCrNi合金的物理型本构模型.该模型初步实现了对FeCrNi合金从室温到高温、从准静态到动态塑性变形行为的描述.