双曲余弦高斯列阵光束通过湍流大气传输的角扩展及方向性

 采用积分变换,推导出了双曲余弦高斯（ChG）列阵光束通过湍流大气传输的二阶矩束宽和角扩展的解析公式,给出了ChG列阵光束与一束高斯光束具有相同角扩展的条件。研究表明:相干合成的ChG列阵光束的角扩展比非相干合成的小,但是,非相干合成的ChG列阵光束的角扩展受湍流影响比相干合成ChG光束小;相干合成情况下,ChG列阵光束的角扩展随离心参数、束腰宽度和相对子光束间距的变化均出现振荡,但在湍流中的振荡减弱,非相干合成情况下,ChG列阵光束的角扩展与相对子光束间距和光束数无关。     

Directionality and mode structure of radiation of semiconductor lasers with electron-beam pumping

We present results of investigations of the directionality diagram and mode structure of radiation of semiconductor lasers with electron pumping that have microrelief reflectors instead of a blind mirror and output mirrors, whose coefficient of reflection depends on the wavelength and the angle of light propagation. Application of such mirrors allows one to narrow the spectrum of output radiation of the lasers, simultaneously reducing the threshold and increasing the output power. The discovered multilobe structure of the directionality diagrams is explained on the basis of geometrical optics. The possibility of controlling the directionality of radiation depending on the spectral and angular characteristics of the output mirror is shown. Reported at the Second International Scientific and Technical Conference on Quantum Electronics, Minsk, November 23–25, 1998. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 66, No. 5, pp. 092–697, Septemter–October, 1999.     

Molecular design of corrole‐based D‐π‐A sensitizers for dye‐sensitized solar cell applications

First principles calculations based on density functional theory (DFT) have been performed to design a new set of donor‐corrole‐bridge‐acceptor type systems based on the gallium corroles for dye‐sensitized solar cell applications. The design strategy for these systems is based on the benchmark studies done on the experimentally tested aluminum, gallium, and tin metallocorroles. Unfortunately, corrole analogues display poor light to current conversion efficiencies in spite of their desirable photophysical properties. Thus, improving the efficiency of corrole analogues has become a major challenge and ways to identify solutions to this is of outstanding fundamental importance. This study shows the lack of charge directionality toward anchoring group as plausible reason for the poor efficiencies of reported corrole systems, which enabled us to fine‐tune the electronic and optical properties of new D‐π‐A type systems, COR1‐COR4. The molecular geometries, electronic structure, and binding orientation of these systems on TiO₂ surface were investigated using DFT, TD‐DFT, and PBC methods. When compared with the reported corroles, COR1‐COR4 have a smaller band gaps, red‐shifted absorption spectra with higher extinction coefficients (10⁵ M^?1 cm^?1) and improved nonlinear optical properties. Importantly, results revealed that these dyes bind with two‐arm mode to TiO₂ surface and the density of states of the dye@TiO₂ elucidate strong coupling between the dyes and TiO₂ surface. We anticipate that the unique photophysical properties of these sensitizers will trigger the experimental efforts to yield a new generation of sensitizers based on corrole macrocyle. © 2015 Wiley Periodicals, Inc.     

辐射器漫反射定向管表面热辐射方向性

为了得到辐射能的方向分布特性,利用蒙特卡罗法,研究了定向管内壁面为不等温灰体、其底部假想圆型辐射器为黑体时,管内壁发射率、管长与半径比、管内空气流速等参数的变化对管口表面当量定向发射率的影响,计算结果表明:管长与半径比增加,管口表面较大的当量定向发射率向小角度的天顶角方向移动,空气流速仅影响当量定向发射率数值大小。     

Broadband Unidirectional Forward Scattering with High Refractive Index Nanostructures: Application in Solar Cells

High refractive index dielectric (HRID) nanoparticles are a clear alternative to metals in nanophotonic applications due to their low losses and directional scattering properties. It has been demonstrated that HRID dimers are more efficient scattering units than single nanoparticles in redirecting the incident radiation towards the forward direction. This effect was recently reported and is known as the “near zero-backward” scattering condition, attained when nanoparticles forming dimers strongly interact with each other. Here, we analyzed the electromagnetic response of HRID isolated nanoparticles and aggregates when deposited on monolayer and graded-index multilayer dielectric substrates. In particular, we studied the fraction of radiation that is scattered towards a substrate with known optical properties when the nanoparticles are located on its surface. We demonstrated that HRID dimers can increase the radiation emitted towards the substrate compared to that of isolated nanoparticles. However, this effect was only present for low values of the substrate refractive index. With the aim of observing the same effect for silicon substrates, we show that it is necessary to use a multilayer antireflection coating. We conclude that dimers of HRID nanoparticles on a graded-index multilayer substrate can increase the radiation scattered into a silicon photovoltaic wafer. The results in this work can be applied to the design of novel solar cells.     

脉冲激光测距机最大测程校准方法

激光测距机的最大测程是激光测距机最主要的性能指标之一，是激光测距机有关性能参数的一种综合反映。简要介绍校准脉冲激光测距机最大测程的几种主要方法，并对各种方法的优、缺点进行详细分析。     

The Pnictogen Bond: The Covalently Bound Arsenic Atom in Molecular Entities in Crystals as a Pnictogen Bond Donor

In chemical systems, the arsenic-centered pnictogen bond, or simply the arsenic bond, occurs when there is evidence of a net attractive interaction between the electrophilic region associated with a covalently or coordinately bound arsenic atom in a molecular entity and a nucleophile in another or the same molecular entity. It is the third member of the family of pnictogen bonds formed by the third atom of the pnictogen family, Group 15 of the periodic table, and is an inter- or intramolecular noncovalent interaction. In this overview, we present several illustrative crystal structures deposited into the Cambridge Structure Database (CSD) and the Inorganic Chemistry Structural Database (ICSD) during the last and current centuries to demonstrate that the arsenic atom in molecular entities has a significant ability to act as an electrophilic agent to make an attractive engagement with nucleophiles when in close vicinity, thereby forming σ-hole or π-hole interactions, and hence driving (in part, at least) the overall stability of the system’s crystalline phase. This overview does not include results from theoretical simulations reported by others as none of them address the signatory details of As-centered pnictogen bonds. Rather, we aimed at highlighting the interaction modes of arsenic-centered σ- and π-holes in the rationale design of crystal lattices to demonstrate that such interactions are abundant in crystalline materials, but care has to be taken to identify them as is usually done with the much more widely known noncovalent interactions in chemical systems, halogen bonding and hydrogen bonding. We also demonstrate that As-centered pnictogen bonds are usually accompanied by other primary and secondary interactions, which reinforce their occurrence and strength in most of the crystal structures illustrated. A statistical analysis of structures deposited into the CSD was performed for each interaction type As···D (D = N, O, S, Se, Te, F, Cl, Br, I, arene’s π system), thus providing insight into the typical nature of As···D interaction distances and ∠R–As···D bond angles of these interactions in crystals, where R is the remainder of the molecular entity.