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81.
在考虑自由体积和局部临界扩散势能的基础上,提出一种新的计算自扩散系数模型,并给出新模型中各个因子物理含义.同时还提出一种计算局部临界扩散势能的新方法,并应用于新模型.另外将衍生van der Waals状态方程应用于求解自由体积,式中所需径向分布函数由Morsali-Goharshadi方程得到.在相同条件下,新模型比原自由体积模型更准确. 相似文献
82.
83.
84.
M.Yu. Tretyakov V.V. Parshin M.A. Koshelev A.P. Shkaev A.F. Krupnov 《Journal of Molecular Spectroscopy》2006,238(1):91-97
Extension of the working frequency of modern resonator spectrometers into submillimeter wave range is described. Experimental record of atmospheric absorption spectrum covering 45-370 GHz range is demonstrated for the first time, and measured water vapor J′ka′, kc′-Jka, kc = 51,5-42,2 at 325 GHz line parameters are presented. For the first time pressure lineshift for the 325-GHz water vapor line is measured. Further extension of working range is discussed. New estimations of physical limits of time needed for measurements of absorption in the whole Backward Wave Oscillator (BWO) range are given for phase continuous synthesizer regime. Basic schemes of fast broadband continuous phase synthesized sources are discussed. Verification of the previous measurements of water vapor 31,3-22,0 at 183 GHz line parameters is presented. Comparisons with ringdown resonator spectrometers are given. 相似文献
85.
联合功率谱的高频成份对相关峰识别具有重要作用,实验中记录的联合功率谱随着频率的增加其强度迅速降低。为增强联合功率谱的高频成分,改善其调制程度,可对功率谱进行对数变换,从而有效保留更多的高频成份,压低零级衍射光斑,提高联合变换相关器的识别能力。 相似文献
86.
A new microtensile tester for the study of MEMS materials with the aid of atomic force microscopy 总被引:4,自引:0,他引:4
An apparatus has been designed and implemented to measure the elastic tensile properties (Young's modulus and tensile strength)
of surface micromachined polysilicon specimens. The tensile specimens are “dog-bone” shaped ending in a large “paddle” for
convenient electrostatic or, in the improved apparatus, ultraviolet (UV) light curable adhesive gripping deposited with electrostatically
controlled manipulation. The typical test section of the specimens is 400 μm long with 2 μm×50 μm cross section. The new device
supports a nanomechanics method developed in our laboratory to acquire surface topologies of deforming specimens by means
of Atomic Force Microscopy (AFM) to determine (fields of) strains via Digital Image Correlation (DIC). With this tool, high
strength or non-linearly behaving materials can be tested under different environmental conditions by measuring the strains
directly on the surface of the film with nanometer resolution. 相似文献
87.
邱卫根 《数学的实践与认识》2006,36(1):227-231
提出了物元等价类概念,并利用子集合X和属性子集R对物元集合S(U,A,V,f)在集合论域U上构造了一类可拓集合A~,并讨论了A~关于X和R的一些相关性质. 相似文献
88.
Matthias Heuchel Martin Bhning Ole Hlck Martin R. Siegert Dieter Hofmann 《Journal of Polymer Science.Polymer Physics》2006,44(13):1874-1897
Atomistic packing models have been created, which help to better understand the experimentally observed swelling behavior of glassy polysulfone and poly (ether sulfone), under CO2 gas pressures up to 50 bar at 308 K. The experimental characterization includes the measurement of the time‐dependent volume dilation of the polymer samples after a pressure step and the determination of the corresponding gas concentrations by gravimetric gas‐sorption measurements. The models obtained by force‐field‐based molecular mechanics and molecular dynamics methods allow a detailed atomistic analysis of representative swelling states of polymer/gas systems, with respect to the dilation of the matrix. Also, changes of free volume distribution and backbone mobility are accessible. The behavior of gas molecules in unswollen and swollen polymer matrices is characterized in terms of sorption, diffusion, and plasticization. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 1874–1897, 2006 相似文献
89.
分析了数字剪切散斑干涉条纹图的形成理论,并获得了条纹亮度与摄象机数值孔径等参数的精确关系式,从理论分析和实验验证均得出在采用小的摄象机数值孔径和3mW He-Ne激光器的情况下,仍可获得比较满意的数字剪切散斑干涉条纹图,理论工作及其结论对于进行数字剪切散斑干涉实验的最佳参数选择具有指导作用。 相似文献
90.
The fluorescence dynamics parameters of the fluorescent transient flavin-luciferase species from the typesVibrio fischeri andPhotobacterium leiognathi are presented. The fluorescence anisotropy decay is a single exponential function for both types. The correlation time is 70 ns for theP. leiognathi fluorescent transient intermediate (2°C, aqueous buffer, pH 7.0), consistent with the rotational correlation time of the luciferase macromolecule (77 kD) to which the flavin fluorophore is rigidly attached. In contrast, for theV. fischeri species the observed correlation time for the anisotropy decay function is 133 ns. This suggests that protein self-association occurs in theV. fischeri case and this is confirmed by filtration, where the fluorescent transient fromV. fischeri does not pass through a 100,000 molecular weight cutoff membrane, whereas theP. leiognathi species does. The filtration method also demonstrates self-association in the luciferase peroxyflavin and photoflavin fromV. fischeri. A monomer-dimer equilibrium also explains the previously reported high correlation times for theV. harveyi luciferase-flavin species. It is proposed that the self-association competes with the lumazine protein interaction in the bioluminescence reaction. 相似文献