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101.
Dr. Yuki Kishimoto Dr. Osamu Nakagawa Akane Fujii Dr. Kotaro Yoshioka Dr. Tetsuya Nagata Prof. Dr. Takanori Yokota Prof. Dr. Yoshiyuki Hari Prof. Dr. Satoshi Obika 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(7):2427-2438
Artificial nucleic acids are widely used in various technologies, such as nucleic acid therapeutics and DNA nanotechnologies requiring excellent duplex-forming abilities and enhanced nuclease resistance. 2′-O,4′-C-Methylene-bridged nucleic acid/locked nucleic acid (2′,4′-BNA/LNA) with 1,3-diaza-2-oxophenoxazine (BNAP ( BH )) was previously reported. Herein, a novel BH analogue, 2′,4′-BNA/LNA with 9-(2-aminoethoxy)-1,3-diaza-2-oxophenoxazine (G-clamp), named BNAP-AEO ( BAEO ), was designed. The BAEO nucleoside was successfully synthesized and incorporated into oligodeoxynucleotides (ODNs). ODNs containing BAEO possessed up to 104-, 152-, and 11-fold higher binding affinities for complementary (c) RNA than those of ODNs containing 2′-deoxycytidine ( C ), 2′,4′-BNA/LNA with 5-methylcytosine ( L ), or 2′-deoxyribonucleoside with G-clamp ( PAEO ), respectively. Moreover, duplexes formed by ODN bearing BAEO with cDNA and cRNA were thermally stable, even under molecular crowding conditions induced by the addition of polyethylene glycol. Furthermore, ODN bearing BAEO was more resistant to 3′-exonuclease than ODNs with phosphorothioate linkages. 相似文献
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103.
The energetic stability, atomic and electronic structures of α-graphyne and its derivatives (α-GYs) with extended carbon chains were investigated by density functional (DF) calculations in this work. The studied α-GYs consist of hexagon carbon rings sharing their edges with carbon atoms N=1–10. The structure and energy analyses show that α-GYs with even-numbered carbon chains have alternating single and triple C–C bonds (polyyne), energetically more stable than those with odd-numbered carbon chains possessing continuous double C–C bonds (polycumulene). The calculated electronic structures indicate that α-GYs can be either metallic (odd N) or semiconductive (even N) depending on the parity of number of atoms on hexagon edges despite the edge length. The semiconducting α-graphyne derivatives are found to possess Dirac cones (DC) with small direct band gaps 2–40 meV and large electron velocities 0.554×106–0.671×106 m/s, 70–80% of that of graphene. Our DF studies suggest that introducing sp carbon atoms into the hexagon edges of graphene opens up an avenue to switch between metallic and DC electronic structures via tuning the parity of the number of hexagon edge atoms. 相似文献
104.
《Current Applied Physics》2015,15(1):8-13
This paper presents the effects of the Lorentz force on the electrical behaviors of the no-insulation (NI) GdBCO racetrack pancake (RP) coil without turn-to-turn insulation by performing charging/discharging and sudden-discharging tests. The simulation results of the 2-dimensional finite element method showed that the Lorentz forces were generated towards the center of the winding pack consisting of 60-turn GdBCO CCs, which could enhanced the turn-to-turn contact within the RP coil. The charging/discharging test results indicated that the characteristic resistance (Rc) of the NI RP coil decreased with increasing operating current, which was caused by an increase of the Lorentz force. Further, the results of the sudden-discharging tests exhibited that the Lorentz force was dissipated instantly during the sudden-discharge of the coil, since the operating current immediately decreased to zero. Overall, this study clearly demonstrated that the Lorentz force induced by the operating current exerts the electrical behaviors of an NI RP coil. 相似文献
105.
《Current Applied Physics》2015,15(6):675-678
Penetration effects of various electrode materials, namely Al, Au, and Cu, on the physical and electrical characteristics of amorphous oxide semiconductor thin film transistors (TFTs) were investigated. Amorphous indium gallium zinc oxide (a-IGZO) TFTs were fabricated with conventional staggered bottom gate structures on a p-type Si substrate. X-ray photoemission spectroscopy (XPS) analysis under the electrode deposition area revealed variations in the oxygen bonding states and material compositions of the a-IGZO layer. Field-emission scanning electron microscopy (FE-SEM) with the line scan of energy dispersive spectroscopy (EDS) showed lateral penetration by the electrode metal. To compare the electrical characteristics of the tested TFTs, the initial current–voltage (I–V) transfer characteristics were examined. In addition, the tested TFTs fabricated using various electrode materials were tested under bias stress to verify the correlations between variations in TFT characteristics and both the metal work function and penetration-induced oxygen vacancies in the channel around the contact area. 相似文献
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In this contribution, an electron acceptor attached diarylethene derivative was synthesized and fully characterized. The photochromic behavior was investigated in THF. Under exposure of UV and visible light cycles, the solution color can be switched between colorless and yellow smoothly. Fatigue resistance measurements could be repeated 50 times with an acceptable degradation. Due to the electron acceptor attached to the framework of diarylethene, the photo- and thermal-stability were enhanced both. A full-photo mode switch can be established based on the well-defined states by external excitation. The molecular structures of ring-open and ring-closed form were optimized by Dmol3. The distance between photocyclizing atoms in aptiparallel conformation meets the requirement for photochromic reaction. And the calculated absorption wavelengths were also in agreement with the experimental values. 相似文献
109.
Cover Picture: Monitoring Conformational Changes in the NDM‐1 Metallo‐β‐lactamase by 19F NMR Spectroscopy (Angew. Chem. Int. Ed. 12/2014) 下载免费PDF全文
110.
The characterization of novel metal reinforced electro-dialysis ion exchange membranes, for water desalination, by attenuated total reflectance Fourier transform infrared spectroscopy mapping is presented in this paper. The surface of the porous stainless steel fibre meshes was treated in order to enhance the amount of surface oxide groups and increase the material hydrophilicity. Then, the metal membranes were functionalized through a sol–gel reaction with silane coupling agents to enhance the affinity with the ion exchange resins and avoid premature metal oxidation due to redox reactions at the metal–polymer interface. Polished cross sections of the composite membranes embedded into an epoxy resin revealed interfaces between metallic frameworks and the silane layer at the interface with the ion exchange material. The morphology of the metal–polymer interface was investigated with scanning electron microscopy and Fourier transform infrared micro-spectroscopy. Fourier transform infrared mapping of the interfaces was performed using the attenuated total reflectance mode on the polished cross-sections at the Australian Synchrotron. The nature of the interface between the metal framework and the ion exchange resin was shown to be homogeneous and the coating thickness was found to be around 1 μm determined by Fourier transform infrared micro-spectroscopy mapping. The impact of the coating on the properties of the membranes and their potential for water desalination by electro-dialysis are also discussed. 相似文献