校准电表的一种方法

利用电位差计的高精度，设计出合理的实验电路对C31型电表进行校准，使得电表的准确度等级得以提高。     

Relationship between the 2-body Parameters of the Biswas-Hamann and the Bauer-Maysenholder-Seeger Potential Functions

A theoretical relation between the Bauer-Maysenholder-Seeger (BMS) and the Biswas-Hamann (BH) potential function has been developed herein for the case of 2-body interaction. By equating derivatives of these two potential functions for the 2-body part, a loose form of BMS is expressed in terms of BH parameters with a scaling factor. The validity of the developed parametric relationships has been graphically demonstrated, and the suitability discussed with reference to the extent and direction of bond distortion.     

超短强激光脉冲在等离子体隧道中传输的理论与数值模拟研究

研究了超短强激光脉冲在非扰动抛物型部分电离的预等离子体隧道中的传输特性.从Maxwell方程出发得到了两个包含衍射、三阶强度非线性、等离子体散焦、等离子体隧道聚焦以及相对论自聚焦等效应在内的激光场演化方程，即折射率方程和哈密顿-雅可比方程.在此基础 上得到了激光在等离子体隧道中传输的包络方程以及光斑半径与传输距离、隧道宽度等初始 参量的关系. 关键词： 等离子体隧道聚焦 相对论自聚焦 势阱     

用点正则变换方法求解双原子分子的双曲型Poschl-Teller势的束缚态

采用在点正则变换下形状不变势的映射方法,给出了将Poschl-Teller Ⅰ势映射至Poschl-Teller Ⅱ势的点正则变换,并从Poschl-TellerI势的束缚态能级和波函数求得了Poschl-Teller Ⅱ势的束缚态能级和波函数.     

Hochschild Cohomologies of the Algebra of Smooth Functions

Based on the previously developed technique using the Laplace transformation of distributions with compact support, we calculate the Hochschild cohomologies of the algebra of smooth functions on a finite-dimensional real vector space with coefficients in the adjoint representation.     

The millimeter wave spectrum of the CO dimer

The millimeter wave spectrum of the isotopically substituted CO dimer, (¹³C¹⁶O)₂, has been studied for the first time, confirming and extending a recent infrared study. Eighty-seven transitions in the 77-180 GHz region have been assigned and analyzed in terms of a model-independent term value scheme involving 57 rotational levels with J=0-8. The levels can be classified into 7 “stacks” which have symmetry classifications of either A⁻/B⁺ or A⁺/B⁻ and K-values of either 0 or 1. For the normal isotope, symmetry and nuclear spin statistics cause alternate rotational levels to be missing, but for (¹³C¹⁶O)₂ all levels are present with an intensity alternation of 1:3 between A and B symmetries. The four A⁻/B⁺ stacks have not previously been observed, and the lowest of them establishes the tunneling splitting of (¹³C¹⁶O)₂ to be 3.769 cm⁻¹, slightly larger than the (¹²C¹⁶O)₂ value of 3.731 cm⁻¹. A large amount of precise experimental data is now available for the CO dimer, which should lead to greater theoretical insight into its structure and tunneling dynamics.     

NMR studies on a palladium(II) complex containing an incompletely coordinated facultative pentadentate Schiff base ligand

Palladium(II) dichloride reacts with 1,10‐bis(2‐pyrrolyl)‐2,5,9‐triaza‐1,9‐decadiene to give a [Pd(C₁₅H₂₀N₅)]Cl complex in which the ligand is four‐coordinated, leaving one pyrrole group dangling. By using COSY, gHSQC, gHMBC connectivities and NOE experiments it has been concluded that one linkage isomer exists in DMSO solution, in spite of the fact that different sets of N atoms of potentially pentadentate ligand might be involved in coordination, and that the three chelate rings in the complex cation are arranged in a sequence: five‐membered, six‐membered, five‐membered which is different from that (5–5–6) found by x‐ray studies on the related [Ni(C₁₅H₂₀N₅)]Cl compound. NMR studies allowed an unambiguous assignment of all ¹H and ¹³C NMR resonances for the complex. Results of x‐ray structural analysis of [Pd(C₁₅H₂₀N₅)](CH₃COO)H₂O supported the five‐membered, six‐membered, five‐membered ring sequence in the [Pd(C₁₅H₂₀N₅)]⁺ complex cation and show an E (trans) orientation of the dangling pyrrole group with respect to the metal center. Copyright © 2002 John Wiley & Sons, Ltd.     

双金属氰化络合物催化剂的形态及其对催化剂活性的影响

合成了多个基于钴氰化锌的双金属氰化络合物(DMC)催化剂,并对催化剂的结晶形态进行了表征.考察了制备过程中,有机配体及其引入方式,温度,搅拌速度对DMC催化剂形态的影响.其中有机配体对DMC催化剂形态的影响是最主要的.有机配体中富电子原子的电负性的强弱和数量共同影响着DMC催化剂的形态.该类原子的电负性越强,得到的DMC催化剂的结晶性越差,无定型部分的比例越高,并且单个原子的电负性强弱比该类原子的数量在此间的影响更大.而在有机配体预先存在的情况下,该沉淀体系则更有利于无定型部分的产生.在30℃左右的沉淀反应温度下,得到的DMC催化剂的无定型部分比例最高.在有机配体存在的情况下,搅拌速度对DMC催化剂形态的影响有限.并且发现存在于有机配体中的DMC催化剂随着时间的推移,形态会发生变化.初步揭示了DMC催化剂的形态与其催化活性间的关系.而无定型态的DMC催化剂更有利于PO的聚合.     

Sn/Ge(1 1 1) α-phase: characterization of image resonances by specular electron reflection and selective electron scattering

Image potential resonances on the Sn/Ge(1 1 1) α-phase are investigated by two closely related methods: specular electron reflection and so-called selective electron scattering. Electrons from image resonances are detected on this surface at 120 and 300 K, i.e. below and above the phase transition at about 200 K. The dispersion of the image resonances reveals at these two temperatures equivalent effective electron masses, which are characteristic for this type of electronic surface states. The results of the two methods are consistent according to the similarity of the scattering processes. Changes in the loss peak intensity with the annealing temperature are assigned to the surface quality and are reflected by characteristic photoemission intensities.