全文获取类型
收费全文 | 19937篇 |
免费 | 2305篇 |
国内免费 | 5383篇 |
专业分类
化学 | 17374篇 |
晶体学 | 447篇 |
力学 | 945篇 |
综合类 | 215篇 |
数学 | 2670篇 |
物理学 | 5974篇 |
出版年
2024年 | 29篇 |
2023年 | 207篇 |
2022年 | 479篇 |
2021年 | 501篇 |
2020年 | 608篇 |
2019年 | 522篇 |
2018年 | 507篇 |
2017年 | 597篇 |
2016年 | 685篇 |
2015年 | 611篇 |
2014年 | 932篇 |
2013年 | 1617篇 |
2012年 | 1799篇 |
2011年 | 1147篇 |
2010年 | 948篇 |
2009年 | 1251篇 |
2008年 | 1424篇 |
2007年 | 1491篇 |
2006年 | 1410篇 |
2005年 | 1330篇 |
2004年 | 1218篇 |
2003年 | 1040篇 |
2002年 | 906篇 |
2001年 | 707篇 |
2000年 | 727篇 |
1999年 | 657篇 |
1998年 | 594篇 |
1997年 | 522篇 |
1996年 | 453篇 |
1995年 | 437篇 |
1994年 | 384篇 |
1993年 | 291篇 |
1992年 | 347篇 |
1991年 | 259篇 |
1990年 | 201篇 |
1989年 | 151篇 |
1988年 | 122篇 |
1987年 | 96篇 |
1986年 | 92篇 |
1985年 | 75篇 |
1984年 | 46篇 |
1983年 | 28篇 |
1982年 | 48篇 |
1981年 | 29篇 |
1980年 | 23篇 |
1979年 | 14篇 |
1978年 | 16篇 |
1977年 | 16篇 |
1976年 | 8篇 |
1973年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
11.
R. Pizzoferrato L. Lagonigro T. Ziller A. Di Carlo R. Paolesse F. Mandoj A. Ricci C. Lo Sterzo 《Chemical physics》2004,300(1-3):217-225
We study the infrared emission at 1.54 μm of an organolanthanide complex, Er(III)-tetraphenylporphyrin [Er(TPP)acac], both as a result of direct optical excitation and via energy transfer from host π-conjugate polymers of type poly(arylene–ethynylene) [PAE]. In the first case, the emission of the neat complex is characterized in inert transparent materials and a value of the quantum yield at 1.54 μm φIR=4×10−4 is measured. Then, fluorescence resonance transfer is investigated in blends of Er(TPP)acac with PAEs by monitoring the quenching of the polymer fluorescence along with the enhancement of both the visible emission of the ligand and the near-infrared band of Er3+. These different procedures allow a detailed analysis of the transfer efficiency within a specific implementation of the Förster model for polymeric donors. The experimental values of the critical radius R0, ranging from 1.3 to 2.5 nm for the different blends, are in good agreement with theory for a wide interval of the physical and spectroscopic parameters. This suggests that other mechanisms for excitation transfer do not play a significant role in these materials. 相似文献
12.
Guangchang Zhou Jibao He Issifu I. Harruna 《Journal of polymer science. Part A, Polymer chemistry》2007,45(18):4204-4210
Amphiphilic tris(2,2′‐bipyridine)ruthenium‐cored star‐shaped polymers consisting of one polystyrene block and two poly(N‐isopropylacrylamide) blocks were prepared by the “arm‐first” method in which RAFT polymerization and nonconvalent ligand–metal complexation were employed. The prepared amphiphilic star‐shaped metallopolymers are able to form micelles in water. The size and distribution of the micelles were studied by dynamic light scattering and transmission electron microscopy techniques. Preliminary studies indicate that the polymer concentration and the hydrophilic poly(N‐isopropylacrylamide) block length can affect the morphologies of the formed metal‐interfaced core–shell micelles in water. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4204–4210, 2007 相似文献
13.
In mononuclear HgI2[(C5H4N)3N], mercury is tetrahedrally coordinated by two nitrogen atoms of a tris(2‐pyridyl)amine ligand and two iodides. The coordination moieties are connected by weak intermolecular Hg(II)···I interactions to give a one‐dimensional structure. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
14.
Jack Harrowfield Dominique Matt 《Journal of inclusion phenomena and macrocyclic chemistry》2004,50(3-4):133-150
The problems involved in identifying and quantifying labile interactions considered to influence complex compound structures are highlighted through the assessment of four different families of metal complexes for which extensive crystallographic data are available. Modification of the charge distribution within a ligand molecule as a result of coordination is one factor with a number of ramifications. A detailed analysis of evidence for both intra- and inter-molecular attractions in dimethylsulfoxide complexes of metal perchlorates is used to provide a basis for the consideration of weak interactions between complex ions involving forces including phenyl-group attractions, hydrogen bonding and cavity inclusion. 相似文献
15.
Continuous dependence on a modelling parameter is established for solutions of a problem for a complex Ginzburg–Landau equation. A homogenizing boundary condition is also used to discuss the continuous dependence results. We derive a priori estimates that indicate that solutions depend continuously on a parameter in the governing differential equation. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
16.
The association of complex formation with static quenching in CT systems was investigated. Evaluation of the data made evident
that the inner filter effect must be allowed for. Time-resolved and temperature-dependent stationary measurements of fluorescence
led to the separation of dynamic and static quenching components. The static quenching constant is discussed with respect
to the equilibrium constant of complex formation determined by absorption spectroscopy. 相似文献
17.
L. A. Sakhnovich 《Functional Analysis and Its Applications》2002,36(3):205-211
The conjecture according to which the mean energy of an equilibrium system in quantum theory exceeds the mean energy of the corresponding classical system is considered. It is rigorously proved that the conjecture holds for the potential well. The estimates for the mean energy of the potential well at high and low temperatures are of special interest. 相似文献
18.
19.
One influential parameter which mediates interactions between many types of molecules and biological membranes stems from
the lumped contributions of the transmembrane potential, dipole potential and the difference in the surface potentials on
both sides of a membrane. With relevance to cell physiology, such electrical features of a biomembrane are prone to undergoing
changes as a result of interactions with the aqueous surrounding. Among the most useful tools devoted to exploring changes
of electrical parameters of a lipid membrane induced by certain extracellular ions, lipid composition, and embedded membrane
peptides and proteins, are spectroscopic imaging and the inner field compensation (IFC) method. In this work we layout the
principles of a fully computerized version of the IFC method, which makes it more readily available to users. As a direct
application, we deployed this improved version of the IFC method to time-resolve changes induced by alamethicin monomers upon
membrane dipole potential, following their aggregation within an artificial lipid membrane. Intriguingly, even prior crossing
the membrane core, the membrane-bound alamethicin monomers are shown to significantly increase the dipole potential of the
monolayer they reside in. Such data further emphasize the yet less-explored interplay between membrane-based protein and peptides,
and the membrane dipole potential. 相似文献
20.
王胜奎 《数学的实践与认识》2006,36(5):5-10
根据松纵坑切梢小蠹的主要生物学特征,通过分析抚育间伐持续控制松纵坑切梢小蠹虫害的机理,应用复杂适应系统(CA S)理论,建立了模拟松纵坑切梢小蠹虫害的一种动态演化数学模型,并讨论了模型的收敛性.然后选用昆明小哨林场为背景,进行了各种抚育间伐决策的仿真,从中优选抚育间伐决策.结果表明:模拟优化方案与实际调查统计分析结果一致:均为弱度间伐与中弱度间伐控制蠹害效果最好.最后通过森林积材量与虫害程度之间的优化,给出了抚育间伐的优化策略. 相似文献