NiO@SnO2@Zn2TiO4@TiO2同轴四层纳米电缆的制备、表征及形成机理研究

采用静电纺丝技术, 通过改进实验装置, 在最佳的纺丝条件下制备了[Ni(CH₃COO)₂＋PVP]@[SnCl₄＋PVP]@[Zn(CH₃COO)₂＋PVP]@[Ti(OC₄H₉)₄＋CH₃COOH＋PVP]前驱体复合电缆, 将其进行热处理, 制备出NiO@ SnO₂@Zn₂TiO₄@TiO₂同轴四层纳米电缆. 采用热重-差热(TG-DTA)、X射线衍射(XRD)、傅立叶变换红外光谱(FTIR)、扫描电子显微镜(SEM)和透射电子显微镜(TEM)等分析技术对样品进行了表征. 结果表明, 所得产物为同轴四层纳米电缆, 芯层为NiO, 直径为35～55 nm|第二层为SnO₂, 厚度为30～50 nm|第三层为Zn₂TiO₄, 厚度为25～40 nm|壳层为TiO₂, 厚度为40～90 nm. 对同轴四层纳米电缆的形成机理进行了探讨.     

Secondary Flows of Simplified Phan-Thien Tanner (SPTT) Non-Linear Viscoelastic Fluid Between Parallel Rotating Disks

Summary: The steady state laminar flow of non-linear viscoelastic fluid with Simplified Phan-Thien Tanner (SPTT) model between coaxial rotating disks is studied analytically. With linearized stress coefficient in the constitutive equation (SPTT), primary flow and weak secondary flow have been investigated by perturbation techniques while the aspect ratio is very small. Axial and radial velocity profiles arising from secondary flow are completely analyzed for various boundary conditions and properties of the viscoelastic fluid. The results indicate the strong effects of the elasticity and boundary conditions on velocity profiles. The inertial secondary flow consists of a single vortex for co-rotating disks and two vortices for counter-rotating disks which is well represented by the approximate analytical solution.     

CuO/ZnO量子点异质结及同轴纳米线异质结构的研制

采用离子束溅射技术和热氧化工艺,对预先制备的ZnO纳米线表面进行纳米CuO修饰,研究了不同溅射工艺条件下对形成的CuO/ZnO纳米线异质结构的影响,通过控制溅射参数成功地合成出不同CuO量子点尺寸和分布密度的CuO/ZnO量子点异质结和CuO为壳层的CuO/ZnO同轴纳米线异质结构.将X射线衍射仪（XRD）、扫描电子显微镜（SEM）和透射电子显微镜（TEM）用于研究样品的结构和形貌.实验结果表明,溅射在ZnO纳米线表面的Cu膜的厚度对形成的CuO/ZnO异质结构起着重要的作用.在Cu膜适度较薄时,获得了直径仅5 nm、分布较均匀的高密度（2.05×1010mm-2）CuO/ZnO量子点异质结;而Cu膜较厚时,形成的是CuO/ZnO同轴纳米线异质结构.利用高分辨透射电子显微镜（HRTEM）进一步对量子点异质结和同轴纳米线异质结的界面晶体结构进行了研究.     

Flow of a Jeffery-Six Constant Fluid Between Coaxial Cylinders withHeat Transfer Analysis

In the present investigation we have discussed the flow of a Jeffrey-six constant incompressible fluid between two infinite coaxial cylinders in the presence of heat transfer analysis. The governing equations of Jeffrey-six constant fluid along with energy equation have been derived in cylindrical coordinates. The highly nonlinear equations are simplified with the help of non-dimensional parameters and then solved analytically with the help of homotopy analysis method (HAM) for two fundamental flows namely Couette and Generalized Couette flow. The effects of emerging parameters are discussed through graphs. The convergence of the HAM solution has been discussed by plotting h-curves.     

微波同轴腔高阶TM模式参数的计算

 用FORTRAN语言编程计算了微波圆柱同轴谐振腔TM工作模式的系列关联参数。给定合适的几何结构参数范围与模式参数范围,就可快速算出同轴腔内所有可能存在的腔体尺寸、本征频率、纵向电场强度极大值的位置对应的半径以及该位置处的特性阻抗。这样,设计者就可以根据特定的需要,从计算出的大量结果中选取符合要求的结构参数,为下一步仿真和实验提供依据,减少了设计初期冗长反复的仿真模拟和试错实验。用3维电磁场软件ISFEL 3D对计算结果进行仿真发现：计算结果与仿真结果有很好的一致性,说明自编程序的计算结果可以作为多注速调管谐振腔设计的优选或优化数据库,可以提高其设计的准确性和效率。     

Analysis of Rotenoids by High Temperature High Resolution Gas Chromatography-Mass Spectrometry

A short glass capillary column coated with PS-090 (20% phenyl–80% methylpolysiloxane, of 10 m × 0.30 mm i.d.; with 0.1 μm film thickness) was used to analyze samples from Tephrosia candida; eighteen rotenoids were separated and identified without derivatization by HT-HRGC and HT-HRGC-MS. The mass spectra show the typical fragmentation pattern for rotenoids, with the base peaks either at M⁺, or originating from RDA (Retro Diels-Alder) rearrangements. HT-HRGC and HT-HRGC-MS were shown to be extremely valuable and neglected techniques for structural studies as well as the routine analysis of rotenoids in crude extracts. Possible applications to other classes of aromatic natural products, e.g. flavonoids, are envisaged.     

缺陷态同轴布拉格波导传输特性

采用基于Ansoft HFSS的电磁仿真平台,研究了一个工作于Ka波段（37.5 GHz附近）的缺陷态同轴布拉格波导在不同的开槽方式及缺陷位置条件下的传输特性。结果表明：该波导只有在内外导体壁单面开槽并引入缺陷,或者双面开槽且两个开槽面同时引入缺陷的条件下才能够有效地产生出传输通带;对于后者而言,将内外导体壁的波纹初始相位差设置为且让缺陷位于波导中间时,可以获得带宽极窄、阻带抑制范围较宽的传输通带,此时,给内外导体壁的缺陷引入适度的错位能够对通带的中心频率、带宽等性能指标起到微调作用,而引入大间距的错位则能够在禁带中产生出多个通带,从而起到多通道滤波的作用。     

同轴共线阵列天线低副瓣设计

对流层风廓线雷达对阵列天线的要求是结构简单,在满足高增益条件下,低副瓣是其关键指标。针对该应用背景,提出了一种辐射单元长度可变的同轴共线天线 (COCO)模型。该天线模型利用不同数量辐射节COCO线源组阵,其口径幅度为修正Taylor分布。在该模型基础上,采用数值计算和优化,COCO阵列天线增益为25.7 dB,E面副瓣为-23 dB,H面副瓣为-22.3 dB。该天线阵样品的测试表明,所设计的低副瓣COCO阵列天线完全达到了设计目标。     

国产磁合金环性能的测试

通过搭建谐振电路的方法对国产磁合金环性能进行了测试。测试的主要参数包括磁合金环的磁导率、Q值及其并联阻抗值等。测试结果表明：该磁合金环的Q值很低,随频率的变化不明显;磁导率很大,随频率的增加而减小;并联阻抗值随频率增加而变大。在100 ℃温度以内,其性能参数变化很小。     

10~45 GHz宽频段同轴输入窗设计

为满足微波管放大器对宽频段输入窗的需求,并保证馈源的真空密封需求,提出并设计了一种适用于宽频段微波放大器的同轴输入窗。该宽频段同轴输入窗采用渐变圆环形陶瓷,材料介电常数为9.3,窗片厚度为2.5 mm, 内径为2.14 mm,外径为5 mm,渐变段长度为6.5 mm。利用三维高频电磁仿真软件CST对其建模分析,并对同轴内外结构尺寸和陶瓷渐变结构进行优化仿真,得出该宽频带同轴输入窗能够在10～45 GHz频带内实现插入损耗小于0.5 dB。