全文获取类型
收费全文 | 58796篇 |
免费 | 4007篇 |
国内免费 | 4137篇 |
专业分类
化学 | 28042篇 |
晶体学 | 447篇 |
力学 | 4569篇 |
综合类 | 572篇 |
数学 | 10778篇 |
物理学 | 22532篇 |
出版年
2024年 | 88篇 |
2023年 | 510篇 |
2022年 | 1303篇 |
2021年 | 1278篇 |
2020年 | 1399篇 |
2019年 | 1396篇 |
2018年 | 1275篇 |
2017年 | 1486篇 |
2016年 | 1653篇 |
2015年 | 1376篇 |
2014年 | 2019篇 |
2013年 | 3633篇 |
2012年 | 2578篇 |
2011年 | 2616篇 |
2010年 | 2148篇 |
2009年 | 3181篇 |
2008年 | 3430篇 |
2007年 | 3889篇 |
2006年 | 3364篇 |
2005年 | 2642篇 |
2004年 | 2297篇 |
2003年 | 2554篇 |
2002年 | 2900篇 |
2001年 | 2201篇 |
2000年 | 2133篇 |
1999年 | 1848篇 |
1998年 | 1771篇 |
1997年 | 1159篇 |
1996年 | 1060篇 |
1995年 | 930篇 |
1994年 | 951篇 |
1993年 | 698篇 |
1992年 | 775篇 |
1991年 | 540篇 |
1990年 | 532篇 |
1989年 | 413篇 |
1988年 | 366篇 |
1987年 | 336篇 |
1986年 | 285篇 |
1985年 | 262篇 |
1984年 | 266篇 |
1983年 | 160篇 |
1982年 | 210篇 |
1981年 | 195篇 |
1980年 | 137篇 |
1979年 | 160篇 |
1978年 | 134篇 |
1977年 | 123篇 |
1976年 | 80篇 |
1973年 | 60篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
71.
An effective residual interaction between particles and holes for shell model calculations around 208Pb, derived from the interaction between free nucleons, is compared with the measured properties of proton-hole neutron states
in 208Tl and the interaction between proton holes is adjusted to newly measured level energies in 206Hg. These interaction elements are particularly relevant for neutron-rich nuclei. The adjustment of two mixing elements reproduces
the known γ-decay data in 208Tl.
Received: 2 April 2002 / Accepted: 2 May 2002 相似文献
72.
K. Weibert J. Main G. Wunner 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,19(3):379-388
In the periodic orbit quantization of physical systems, usually only the leading-order ? contribution to the density of states is considered. Therefore, by construction, the eigenvalues following from semiclassical
trace formulae generally agree with the exact quantum ones only to lowest order of ?. In different theoretical work the trace formulae have been extended to higher orders of ?. The problem remains, however, how to actually calculate eigenvalues from the extended trace formulae since, even with ? corrections included, the periodic orbit sums still do not converge in the physical domain. For lowest-order semiclassical trace formulae the convergence problem can be elegantly, and universally, circumvented by application of the
technique of harmonic inversion. In this paper we show how, for general scaling chaotic systems, also higher-order
? corrections to the Gutzwiller formula can be included in the harmonic inversion scheme, and demonstrate that corrected semiclassical
eigenvalues can be calculated despite the convergence problem. The method is applied to the open three-disk scattering system,
as a prototype of a chaotic system.
Received 10 September 2001 and Received in final form 3 January 2002 相似文献
73.
We show that the LF-algebra considered by Akkar and Nacir in [1] is topologically simple. 相似文献
74.
75.
Semi-empirical molecular orbital calculations were carried out for the compounds (C2H5)3As, (C2H5)3Ga and RAsH2 (R = C2H5, i-C3H7, i-C4H9, and t-C4H9) by using the CNDO/2-U program, and their capability of β-elimination reaction is compared on the basis of the torsion energy to the transition state, electrostatic interactions and orbital overlapping between the central atom and the β-hydrogen, and bond order of the metal-carbon, and carbon-hydrogen bond. In the comparison of (C2H5)3As with (C2H5)3Ga, we found that the β-elimination of (C2H5)3As could hardly be expected to take place in the thermal decomposition. The capability of β-elimination would be smaller in C2H5AsH2 than that in (C2H5)3As. Moreover when the ethyl group is replaced by a t-butyl group in RAsH2, the β-elimination reaction appears to become more difficult and a large possibility for a radical process is suggested. 相似文献
76.
A. S. Lobach B. P. Tarasov Yu. M. Shul'ga A. A. Perov A. N. Stepanov 《Russian Chemical Bulletin》1996,45(2):464-465
Fullerene deuteride was obtained by the reaction of deuterium with solid palladium fulleride C60Pd4.9 under fairly mild conditions. The compound was identified by FD-MS, UV-Vis and IR spectroscopies, and TLC.Translated from Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 483–484, February, 1996 相似文献
77.
The phase behavior of binary blends of poly(ether ether ketone) (PEEK), sulfonated PEEK, and sulfamidated PEEK with aromatic polyimides is reported. PEEK was determined to be immiscible with a poly(amide imide) (TORLON 4000T). Blends of sulfonated and sulfamidated PEEK with this poly(amide imide), however, are reported here to be miscible in all proportions. Blends of sulfonated PEEK and a poly(ether imide) (ULTEM 1000) are also reported to be miscible. Spectroscopic investigations of the intermolecular interactions suggest that formation of electron donoracceptor complexes between the sulfonated/sulfamidated phenylene rings of the PEEKs and the n-phenylene units of the polyimides are responsible for this miscibility. © 1993 John Wiley & Sons, Inc. 相似文献
78.
Jing Zhang Dan Shan Shaolin Mu 《Journal of polymer science. Part A, Polymer chemistry》2007,45(23):5573-5582
A copolymer, poly(aniline‐co‐o‐aminophenol), was prepared chemically by using ammonium peroxydisulfate as an oxidant. The monomer concentration ratio of o‐aminophenol to aniline strongly influences the copolymerization rate and properties of the copolymer. The optimum composition of a mixture for the chemical copolymerization consisted of 0.3 M aniline, 0.021 M o‐aminophenol, 0.42 M ammonium peroxydisulfate, and 2 M H2SO4. The result of cyclic voltammograms in a potential region of ?0.20 to 0.80 V (vs.SCE) indicates that the electrochemical activity of the copolymer prepared under the optimum condition is similar to that of polyaniline in more acid solutions. However, the copolymer still holds the good electrochemical activity until pH 11.0. Therefore, the pH dependence of the electrochemical property of the copolymer is improved, compared with poly(aniline‐co‐o‐aminophenol) prepared electrochemically, and is much better than that of polyaniline. The spectra of IR and 1H NMR confirm that o‐aminophenol units are included in the copolymer chain, which play a key role in extending the usable pH region of the copolymer. The visible spectra of the copolymers show that a high concentration ratio of o‐aminophenol to aniline in a mixture inhibits the chain growth. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5573–5582, 2007 相似文献
79.
引入了随机环境中双移民生灭过程的概念,定义了过程的模态指示函数,在此基础上研究了其转移矩阵的平稳分布,给出了平稳分布众数的位置与模态指示函数之间的关系.研究了平稳分布的众数与边界关系. 相似文献
80.
《Journal of Chemical Sciences》2005,117(5):525-531
The silicon atom may increase its coordination number to values greater than four, to form pentacoordinated compounds. It
has been observed experimentally that, in general, pentacoordinated compounds show greater reactivity than tetracoordinated
compounds. In this work, density functional theory is used to calculate the global softness and the condensed softness of
the silicon atom for SiH
n
F4−n
and SiH
n
F
5−n
1−
. The values obtained show that the global and condensed softness are greater in the pentacoordinated compounds than in the
tetracoordinated compounds, a result that explains the enhanced reactivity. If the results are analysed through a local version
of the hard and soft acids and bases principle, it is possible to suggest that in nucleophilic substitution reactions, soft
nucleophiles preferably react with SiH
n
F
5−n
1−
, and hard nucleophiles with SiH
n
F4−n
. 相似文献