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101.
"在非水介质中合成了纳米氧化锌,测定了纳米氧化锌的紫外吸收光谱,并用有效质量模型计算了粒子大小,开发并命名了一种称之为纳米粒子过饱和控制生长的技术,该技术涉及将小的纳米粒子悬浊液加入到大的粒子悬浊液中,结果因为不同大小粒子间的溶解度差异小的粒子将全部溶解,大的粒子将整体长大,大粒子悬浊液的粒子数将保持不变,大粒子的生长速度显著比Ostwald老化的高.该技术最显著的特征是只要最初两悬浊液粒子大小的差异足够大,分布不是太宽,则粒子大小的分布将会因为粒子如此长大而变窄." 相似文献
102.
The etching conditions of an indigenously prepared thin film of pentaerythritol tetrakis(allyl carbonate) (PETAC) were standardised for the use as a nuclear track detector. The optimum etching times in 6?N NaOH at 70°C for the appearance of fission and alpha tracks recorded in this detector from a 252Cf solid source were found to be 30 min and 1.50?h, respectively. The experimentally determined values for the bulk and track-etch rates for this detector in 6?N NaOH at 70°C were found to be 1.7?±?0.1 and 88.4?±?10.7?µm/h, respectively. From these results, the important track etching properties such as the critical angle of etching, the sensitivity and the fission track registration efficiency were calculated and compared with the commercially available detectors. The activation energy value for bulk etching calculated by applying Arrhenius equation to the bulk etch rates of the detector determined at different etching temperatures was found to be 0.86?±?0.02?eV. This compares very well with the value of about 1.0?eV reported for most commonly used track detectors. The effects of gamma irradiation on this new detector in the dose range of 200–1000?kGy have also been studied using bulk etch rate technique. The activation energy values for bulk etching calculated from bulk etch rates measurements at different temperatures were found to decrease with the increase in gamma dose indicating scission of the detector due to gamma irradiation. The optical band gap of this detector was also determined using UV–visible spectrometry and the value was found to be 4.37?±?0.05?eV. 相似文献
103.
研究了供应商歧视定价时网络零售商店内推介策略。首先,以供应商统一定价模型为基准,通过逆推归纳法求解不同推介策略组合下零售商和供应商的均衡利润,研究发现:仅当消费者对两家零售商认知差异较小时四种推介策略组合才能同时成立,且随着推介费用的增大两零售商均衡推介策略依次为:都不推介、仅强势零售商1推介和双向推介。其次,构建供应商歧视定价模型,发现歧视定价有利于弱势零售商2获得市场空间,随着消费者对两家零售商感知差异和推介费用的变化呈现出多样化的均衡推介策略。最后,探讨了两种定价模型下供应商的最优利润,发现受推介策略的影响歧视定价未必能够为供应商带来更多利润。 相似文献
104.
105.
106.
First-principles study on the electronic structure and optical properties of T12Cd2(SO4)3 and Rb2Cd2(SO4)3 下载免费PDF全文
With the help of ab initio full-potential linearized augmented plane wave (FPLAPW) method, calculating the electronic structure and linear optical properties is carried out for XCd2(SO4)3 (X =Tl, Rb). The results show that Tl2Cd2(SO4)3 (TlCdS) has a larger band gap than Rb2Cd2(SO4)3 (RbCdS) and the energy bands for RbCdS are more dispersive than those of TlCdS. From their partial densities of states (PDOS), we have observed that the hybridization between S ionic 2p and O atomic 2p orbitals forms SO4 ionic groups. The remarkable difference between RbCdS and TlCdS is, however, the degree of hybridization between cation (Tl and Rb) and its surrounding oxygen atoms. In the view of quantum chemistry, the strong p-d hybridization indicates the existence of their cation ionic bonds (Cd-O, Rb-O, and Tl-O). The calculations of TlCdS and RbCdS show their optical properties to be less anisotropic. Their anisotropies in the optical properties mainly occur in a low photon energy region of 5-16 eV. 相似文献
107.
108.
Thin films of ZnO-SnO2 composites have been deposited on Si(1 0 0) and glass substrates at 500 °C by pulsed laser ablation using different composite targets with ZnO amount varying between 1 and 50 wt%. The effect of increasing ZnO-content on electrical, optical and structural properties of the ZnO-SnO2 films has been investigated. X-ray diffraction analysis indicates that the as-deposited ZnO-SnO2 films can be both crystalline (for ZnO <1 wt%) and amorphous (for ZnO ≥ 10 wt%) in nature. Atomic force microscopy studies of the as-prepared composite films indicate that the surfaces are fairly smooth with rms roughness varying between 3.07 and 2.04 nm. The average optical transmittance of the as-deposited films in the visible range (400-800 nm), decreases from 90% to 72% for increasing ZnO concentration in the film. The band gap energy (Eg) seems to depend on the amount of ZnO addition, with the maximum obtained at 1 wt% ZnO. Assuming that the interband electron transition is direct, the optical band gap has been found to be in the range 3.24-3.69 eV for as-deposited composite films. The lowest electrical resistivity of 7.6 × 10−3 Ω cm has been achieved with the 25 wt% ZnO composite film deposited at 500 °C. The photoluminescence spectrum of the composite films shows a decrease in PL intensity with increasing ZnO concentration. 相似文献
109.
从点光源均匀发光模型出发,重点导出了回转半椭球面镜的阴极荧光(Cathodoluminescence,简称CL)光谱有效收集效率η_λ~(eff)的计算公式,分析讨论了收集效率η_λ~(eff)与椭球参数e、收集角、Δφ出射角Δ(?)以及出射光束方位角θ_N的关系,给出了相应的理论计算和模拟实验结果.研究表明,理论计算与实验结果一致. 相似文献
110.
R. G. Stoneham 《BIT Numerical Mathematics》1970,10(4):481-500
In the computing literature, there are few detailed analytical studies of the global statistical characteristics of a class of multiplicative pseudo-random number generators.We comment briefly on normal numbers and study analytically the approximately uniform discrete distribution or (j,)-normality in the sense of Besicovitch for complete periods of fractional parts {x
0
1
i
/p} on [0, 1] fori=0, 1,..., (p–1)p–1–1, i.e. in current terminology, generators given byx
n+1
1
x
n mod p wheren=0, 1,..., (p–1)p
–1–1,p is any odd prime, (x
0,p)=1,
1 is a primitive root modp
2, and 1 is any positive integer.We derive the expectationsE(X, ),E(X
2, ),E(X
nXn+k); the varianceV(X, ), and the serial correlation coefficient k. By means of Dedekind sums and some results of H. Rademacher, we investigate the asymptotic properties of k for various lagsk and integers 1 and give numerical illustrations. For the frequently used case =1, we find comparable results to estimates of Coveyou and Jansson as well as a mathematical demonstration of a so-called rule of thumb related to the choice of
1 for small k.Due to the number of parameters in this class of generators, it may be possible to obtain increased control over the statistical behavior of these pseudo-random sequences both analytically as well as computationally. 相似文献