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21.
Paul Caylor McKinney 《Journal of mathematical chemistry》2002,32(4):381-404
The solution of a generalized non-relativistic Schrödinger equation with radial potential energy V(r)=V
0(r/a
0)2–2 is presented. After reviewing the general properties of the radial ordinary differential equation, power series solutions are developed. The Green's function is constructed, its trace and the trace of its first iteration are calculated, and the ability of the traces to provide upper and lower bounds for the ground eigenvalue is examined. In addition, WKB-like solutions for the eigenvalues and eigenfunctions are derived. The approximation method yields valid eigenvalues for large quantum numbers (Rydberg states). 相似文献
22.
Xiaojing Xiang 《Annals of the Institute of Statistical Mathematics》1995,47(1):105-117
A necessary condition for the asymptotic normality of the sample quantile estimator isf(Q(p))=F(Q(p))>0, whereQ(p) is thep-th quantile of the distribution functionF(x). In this paper, we estimate a quantile by a kernel quantile estimator when this condition is violated. We have shown that the kernel quantile estimator is asymptotically normal in some nonstandard cases. The optimal convergence rate of the mean squared error for the kernel estimator is obtained with respect to the asymptotically optimal bandwidth. A law of the iterated logarithm is also established.This research was partially supported by the new faculty award from the University of Oregon. 相似文献
23.
Ben Salem Nejib 《Journal of Theoretical Probability》1994,7(2):417-436
We consider hypergroups associated with Jacobi functions
()
(x), (–1/2). We prove the existence of a dual convolution structure on [0,+[i(]0,s
0]{{) =++1,s
0=min(,–+1). Next we establish a Lévy-Khintchine type formula which permits to characterize the semigroup and the infinitely divisible probabilities associated with this dual convolution, finally we prove a central limit theorem. 相似文献
24.
Frank J.S. Wang 《Stochastic Processes and their Applications》1977,5(2):173-193
Consider a population consisting of one type of individual living in a fixed region with area A. In [8], we constructed a stochastic population model in which the death rate is affected by the age of the individual and the birth rate is affected by the population density PA(t), i.e., the population size divided by the area A of the given region. In [8], we proposed a continuous deterministic model which in general is a nonlinear Volterra type integral equation and proved that under appropriate conditions the sequence PA(t) would converge to the solution P(t) of our integral equation in the sense that .In this paper, we obtain a “central limit theorem” for the random element √A(PA(t)?P(t)). We prove that under appropriate conditions √A(PA(t)?P(t)) will converge to a Gaussian process. (See Theorem 3.4 for the explicit formula of this Gaussian process.) 相似文献
25.
The capacity for anaerobic decolorization of a sulfonated azo dye, Congo Red, by a strain of a sulfate-reducing bacterium
was evaluated. After optimizing the growth rate of the bacteria on a simple carbon source and terminal electron acceptor pair,
lactate and sulfate, respectively, the effect of the dye concentration on their growth rate was analyzed. The decolorization
rate was affected by the dye concentration in the growth medium. The azo-bond cleavage mechanism of reductive decolorization
with the formation of benzidine was consistent with the results, as this metabolite was identified by high-performance liquid
chromatography. Several fractions of the culture medium, including lysed cell extracts, were examined for the capacity to
reduce the azo dye. This reduction capacity was found in the culture medium in which the cells had previously grown. The results
showed that the mechanism of reductive decolorization of this sulfonated azo dye was extracellular and nonenzymatic, consistent
with the production of sulfide anion by the microorganisms while growing on lactate and sulfate. The sulfide anions were the
cause of the reduction leading to the disappearance of color in the medium. To increase the rate of decolorization, the presence
of ferrous ion was also necessary together with the lactate and sulfate substrates. 相似文献
26.
Ward Whitt 《Queueing Systems》1991,9(3):235-268
A fundamental principle of queueing theory isL=W (Little's law), which states that the time-average or expected time-stationary number of customers in a system is equal to the product of the arrival rate and the customer-average or expected customer-stationary time each customer spends in the system. This principle is now well known and frequently applied. However, in recent years there have been extensions, such as H=G and the continuous, distributional, ordinal and central-limit-theorem versions, which show that theL=W relation, when viewed properly, has much more power than was previously realized. Moreover, connections have been established between H=G and other fundamental relations, such as the rate conservation law and PASTA (Poisson arrivals see time averages), which show that there is a much greater unity in the overall theory than was previously realized. This paper provides a review.This paper is dedicated to the memory of our colleague Professor Peter Franken (1937–1989), who contributed greatly to the subject of this paper and to queueing theory more generally. 相似文献
27.
The rate-of-convergence problem in the central limit theorem is considered for -stable distributions on the noncommutative group of motions in d. The method used here is based on the theory of probability metrics. 相似文献
28.
The conformal charge is an important quantity which characterizes the nature of the two-dimensional phase transition. We report a first attempt to use a new numerical method to calculate the conformal charge. In this paper, we apply our method to the 2-dimensional,
4, continuous-spin Ising model. By varying the parameters in the Hamiltonian, one can change continuously from the known Gaussian limit to the Ising limit. It is well known that the critical points for these two systems are not in the same universality class. We study this behavior for the Gaussian model, the single-well 4 model, the border model, and the double-well
4 model for a large lattice. Our results, while giving a good general picture, are not so far sufficient to differentiate whether the non-Gaussian cases studied belong to the Ising model universality class or not. Further studies of other lattice sizes should serve to improve greatly our conclusions. 相似文献
29.
Nitrogen doped nano porous graphene as a sorbent for separation and preconcentration trace amounts of Pb,Cd and Cr by Ultrasonic assisted in‐syringe dispersive micro solid phase extraction
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Nitrogen doped nano porous graphene was used as an efficient sorbent in solid‐phase extraction process for simultaneous separation and pre‐concentration of metal ions lead (II), cadmium(II), and chromium(III)) in biological samples. Ultrasonic assisted in‐syringe dispersive micro solid phase extraction coupled with micro sampling atomic absorption spectrometry was utilized for the determination of metal ions. Nitrogen doped nano porous graphene was synthesized as a nano sorbent by chemical vapour deposition method. Methane and aniline were used as carbon and nitrogen sources. The characterization of sorbent was performed by field emission scanning electron microscope, transmission electron microscopy, atomic force microscope, fourier transform infrared, chemical element analysis and raman analysis. Effective parameters on the extraction efficiency such as pH, sorbent dosage, eluent volume and eluent concentration were optimized by central composite design and desirability function. Experimental results indicate that the optimal conditions for this extraction were pH = 6.4, 1.42 mg of sorbent, 100 μL of eluent, and 0.84 mol L‐1 of eluent concentration. The detection limits are as low as 1.5, 0.3 and 0.9 μg L‐1 for lead, cadmium, and chromium, respectively. The intra‐day precisions were 3.6, 4.38 and 2.94 and Inter‐day precision were 4.83, 5.26 and 4.52 for lead, cadmium, and chromium, respectively. Method performance was investigated by determination of mentioned heavy metals in complicated biological matrixes such as human plasma, urine and saliva samples with good recoveries. 相似文献
30.
目的探讨经颈内静脉原位导丝法换置中心静脉长期血液透析导管在维持性血液透析(MHD)患者中的应用价值。方法选取近3年在颈内静脉留置的中心静脉长期血液透析导管因功能障碍后,并经颈内静脉原位导丝法换置长期导管,术后及每次透析后均改用尿激酶封管患者16例(原位换置组);选取同期首次经颈内静脉留置中心静脉长期血液透析导管,普通肝素封管患者20例作为对照组;分析两组患者围术期泵控血流量及随访期的反应及开存期率、次开存期率。结果围术期泵控血流量原位换置组高于对照组,有统计学差异(P<0.05);两组比较感染例次/1000导管日0.9%与1.0%,无统计学差异(P>0.05)。原位换置组围术期未发生中重度并发症,12个月开存期率81.2%、次开存期率93.8%;对照组开存期率为65%、次开存期率85%;两组比较无统计学差异(P>0.05)。结论颈内静脉原位导丝法换置中心静脉长期血液透析导管,在MHD患者中的使用是安全的、可行的。 相似文献