全文获取类型
收费全文 | 11361篇 |
免费 | 2024篇 |
国内免费 | 2711篇 |
专业分类
化学 | 12677篇 |
晶体学 | 158篇 |
力学 | 328篇 |
综合类 | 63篇 |
数学 | 195篇 |
物理学 | 2675篇 |
出版年
2024年 | 54篇 |
2023年 | 200篇 |
2022年 | 550篇 |
2021年 | 516篇 |
2020年 | 748篇 |
2019年 | 547篇 |
2018年 | 490篇 |
2017年 | 562篇 |
2016年 | 709篇 |
2015年 | 665篇 |
2014年 | 754篇 |
2013年 | 1276篇 |
2012年 | 866篇 |
2011年 | 891篇 |
2010年 | 730篇 |
2009年 | 752篇 |
2008年 | 742篇 |
2007年 | 730篇 |
2006年 | 629篇 |
2005年 | 568篇 |
2004年 | 567篇 |
2003年 | 467篇 |
2002年 | 335篇 |
2001年 | 284篇 |
2000年 | 225篇 |
1999年 | 204篇 |
1998年 | 202篇 |
1997年 | 156篇 |
1996年 | 125篇 |
1995年 | 122篇 |
1994年 | 87篇 |
1993年 | 94篇 |
1992年 | 44篇 |
1991年 | 36篇 |
1990年 | 31篇 |
1989年 | 18篇 |
1988年 | 18篇 |
1987年 | 15篇 |
1986年 | 12篇 |
1985年 | 12篇 |
1984年 | 11篇 |
1983年 | 10篇 |
1982年 | 11篇 |
1981年 | 7篇 |
1980年 | 5篇 |
1979年 | 7篇 |
1976年 | 2篇 |
1975年 | 2篇 |
1972年 | 4篇 |
1971年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 8 毫秒
71.
72.
73.
J. A. Azizi D. Dollimore P. J. Dollimore G. R. Heal P. Manley W. A. Kneller W. Jin Yong 《Journal of Thermal Analysis and Calorimetry》1993,40(2):831-847
In this study a relationship between the surface and textural properties of carbon blacks and the gasification process induced thermally in air is noted. A temperature jump method was used to follow the gasification in air and to establish the relevant Arrhenius parameters. This can be associated with the activity of ‘basal’ plane carbon atoms as well as ‘edge’ carbon atoms at the surface. This is based on a model of carbon black structure consisting of the irregular packing of small graphite carbon structures. The carbon black surface was measured using a single measurement of adsorption based essentially on the BET volumetric method. The carbon black surface had a rate of oxidation per unit are which clearly indicated that the lower area carbon blacks had a predominately active area of ‘edge’ atoms at the surface while the surface of the higher area carbon blacks had a predominate amount of ‘basal’ plane graphite carbon atoms. 相似文献
74.
A simple and convenient reduction of 3,4-diamino derivatives of 2,5-thiadiazole-1-oxide to the corresponding 1,2,5-thiadiazoles has been accomplished using Ph3P and CCl4 in dichloromethane. 相似文献
75.
Treatment of (thd)H (thd=2,2,6,6-tetramethyl-3,5-heptandionate) with excess Os3(CO)12 in an autoclave at 180°C gives the formation of a brown metal chain complex [Os2(CO)5(thd)2]2 (1) and a yellow CO2 cluster complex [Os4(-H)(-CO2)(thd)(CO)13] (2) in low yields. Complex 2 was fully identified by a combination of spectroscopic methods and X-ray diffraction study, showing a unique CO2 ligand bridging a triosmium metal fragment, Os3(-H)(CO)10 and a monometallic osmium fragment, Os(CO)3(thd). Upon treatment of 1 with Me3NO at an elevated temperature, oxidation of the CO ligand occurred at the position trans to the unique CO2 ligand on the Os(CO)3(thd) fragment, giving the formation of a second CO2 cluster [Os4(-H)(-CO2)(thd)(CO)12(NCMe)] (3), which is stabilized by a weakly coordinated acetonitrile molecule. 相似文献
76.
77.
Stability constant for mercury binding by commercial and natural humic acids (HA) were determined using a new potentiometric mercury(II) sensor based on dithiosalicylic acid modified carbon paste electrode. The sensor present a high selective and sensitive response to mercury(II) ions, and a low detection limit of 1.8×10?8 M. The potentiometric titrations curves of humic acids against mercury(II) ions were modeled. For 1.00×10?7 to 3.00×10?4 M mercury(II) ion concentration levels the results are consistent with the presence of two different binding sites in the humic acid macromolecule. The strongest binding sites (log K1 ranging from 10.1 to 6.8) are probably due to interaction with carboxylic acid and amine groups in the molecule, whereas weakest binding sites (log K2 ranging from 8.8 to 4.5) can be associated to phenolic groups. 相似文献
78.
CuO/活性炭和Fe2O3/活性炭催化还原NO 总被引:4,自引:0,他引:4
CuO/活性炭和Fe_2O_3/活性炭催化还原NO高志明,赵震,杨向光,吴越(中国科学院长春应用化学研究所长春130022)关键词活性炭,还原,NO,氧化铜,氧化铁目前,对固定源的NO处理是采用V2O5/TiO2作催化剂,NH3作还原剂的选择催化还原方... 相似文献
79.
为观察二硫化碳(CS2)对机体铜,锌水平的影响,对某化纤厂35名接触CS2工人和41名非接触工人的血铜,锌值进行调查,比较,并进行了动物染毒实验。SD大鼠吸入CS2浓度分别为5和50mg/m^3,每日5h,每周6d,连续6个月,于染毒2,4,6个月时测定血浆铜,锌值及染毒6个月时肝脏铜,锌含量。结果显示,CS2接触组工人血铜,锌水平较对照组显著降低(P<0.05)。在CS2染毒6个月时,50mg/m^3 CS2染毒组血浆及肝脏铜水平均较对照组及5mg/m^3 CS2染毒组显著降低(P<0.05)。可见接触CS2能干扰机体铜,锌代谢,导致体内铜,锌含量减少。 相似文献
80.
Tadatomi Nishikubo Atsushi Kameyama Jun Yamashita Masao Tomoi Wakichi Fukuda 《Journal of polymer science. Part A, Polymer chemistry》1993,31(4):939-947
The addition reaction of oxiranes ( 26a—e ) with carbon dioxide (CO2) was performed using insoluble polystyrene beads containing pendant quaternary ammonium or phosphonium salts as catalysts under atmospheric pressure. The reaction of 26a—e with CO2 proceeded smoothly catalyzed by 1–2 mol % of the polymer-supported quaternary onium salts to give the corresponding cyclic carbonates ( 27a—e ) in high yields at 80–90°C. In this reaction system, the catalytic activity of the polymer-supported quaternary onium salts was strongly affected by the following factors: degree of ring substitution (DRS) of the onium salt residues to the polymer, degree of crosslinking (DC) of the polystyrene beads, chain length of the alkylene spacer between the polymer back-bone and the onium salt, hydrophobicity of the alkyl group on the onium salts, and kind of onium salts. That is, the polymer-supported quaternary phosphonium salts with low DRS and DC and with long alkylene spacer chain were found to have higher catalytic activity than low molecualr weight quaternary onium salts. The above polymer-supported catalysts can easily be separated at the end of a reaction by filtration and can be reused for at least seven runs. It was also found that the rate of reaction was proportional to the products of catalyst concentration and oxirane concentration. © 1993 John Wiley & Sons, Inc. 相似文献