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981.
982.
Yan Xiang Jiangju Si Qi Zhang Yang Liu Hong Guo 《Journal of polymer science. Part A, Polymer chemistry》2009,47(3):925-934
A novel series of artificial glycoprotein, peptide‐chitosan copolymers with secondary structural side chain have been synthesized by ring‐opening polymerization of L ‐tryptophan N‐carboxyanhydride under homogeneous conditions. Their chemical structures and polymerization degree (DP) were characterized by IR, 13C NMR, and XRD spectra. Distinctly secondary protein structure has been found in the poly‐L ‐tryptophan side chains of copolymers and with the lengthening of side chain (i.e., the increase of DP at the same time), its conformations could transfer from β‐sheet to α‐helix. The content of α‐helix reaches about 41% when DP of polytryptophan is 22. The solubility of graft copolymers in polar solvent strongly depends on the length of poly‐L ‐tryptophan side chains. Unique fluorescence emission at 360 nm has been observed in the glycopolymers and the intensity shows the positive‐correlation with the increasing of DP of polytryptophan. Importantly, the fluorescence effect can be quenched easily by the coordination with copper ions which provides the possibility on the biosensor design. In comparison with chitosan, glycopolymers also present impressively enhanced compressive strength and elastic modules when it is blended with epoxy E 44 to form epoxy‐copolymer hybrid resin. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 925–934, 2009 相似文献
983.
The Locally Conservative Galerkin (LCG) Method — a Discontinuous Methodology Applied to a Continuous Framework
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Rhodri L. T. Bevan Raoul vanLoon & Perumal Nithiarasu 《advances in applied mathematics and mechanics.》2009,1(3):319-340
This paper presents a comprehensive overview of the element-wise
locally conservative Galerkin (LCG) method. The LCG method was
developed to find a method that had the advantages of the
discontinuous Galerkin methods, without the large computational and
memory requirements. The initial application of the method is
discussed, to the simple scalar transient convection-diffusion
equation, along with its extension to the Navier-Stokes equations
utilising the Characteristic Based Split (CBS) scheme. The
element-by-element solution approach removes the standard finite
element assembly necessity, with an face flux providing continuity
between these elemental subdomains. This face flux provides explicit
local conservation and can be determined via a simple small
post-processing calculation. The LCG method obtains a unique
solution from the elemental contributions through the use of simple
averaging. It is shown within this paper that the LCG method
provides equivalent solutions to the continuous (global) Galerkin
method for both steady state and transient solutions. Several
numerical examples are provided to demonstrate the abilities of the
LCG method. 相似文献
984.
985.
Single atomic manipulation and writing with scanning tunnelling microscopy at low temperatures
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In the work reported in this paper,we have used a low-temperature scanning tunnelling microscope (LT-STM) system to manipulate accurately single atoms.We show how we can use a LT-STM to image and modify a bulk Ag(111) surface and manipulate Ag atoms from substrate and evaporated adsorbates on Ag(111) substrates.We present a synergistic combination of SM-induced modification and ordered arrays of nanometre-scale structures.In particular,we demonstrate the ability to modify Ag atomic nanometre structures on the Ag(111) substrate,and some English letters and a Chinese character can be written by single Ag atoms coming from the substrate and evaporated adsorbates on Ag(111),In this way ,we supply an effective basis to explore the fundamental physical properties of a nanometre structure and to develop nanotechnology with a bottom-up approach, 相似文献
986.
ZhongyiHuang 《计算数学(英文版)》2003,21(1):33-40
In this paper,a new high accuracy numerical method for the thin-film problems of micron and submicron size ferromagnetic elements is proposed,For the computaion of stray field,we use the finite element method(FEM) by introducing a semi-discrete artificial boundary condition [1,2],In our numerical experiments about the domain patterns and their movement,we can see that the results are accordant to that of experments and other numerical methods.Our method are very conveient to deal with arbitrary shape of thin films such as a polygon with high accuracy. 相似文献
987.
A mixed algorithm of central and upwind difference scheme for the solution of steady/unsteady incompressible Navier-Stokes equations is presented. The algorithm is based on the method of artificial compressibility and uses a third-order flux-difference splitting technique for the convective terms and the second-order central difference for the viscous terms. The numerical flux of semi-discrete equations is computed by using the Roe approximation. Time accuracy is obtained in the numerical solutions by subiterating the equations in pseudotime for each physical time step. The algebraic turbulence model of Baldwin-Lomax is ulsed in this work. As examples, the solutions of flow through two dimensional flat, airfoil, prolate spheroid and cerebral aneurysm are computed and the results are compared with experimental data. The results show that the coefficient of pressure and skin friction are agreement with experimental data, the largest discrepancy occur in the separation region where the lagebraic turbulence model of Baldwin-Lomax could not exactly predict the flow. 相似文献
988.
989.
人工神经网络模型及其在遥感中的应用 总被引:9,自引:0,他引:9
人工神经网络是通过模拟人脑神经元活动的过程来处理信息,现已在许多科学领域得以应用,并在分析人工神经网络模型基本原理和运行机制的基础上,探讨其在遥感应用中的优越之处及其与地学知识和专家系统的结合模式。 相似文献
990.