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992.
Ryo Kuriki Dr. Keita Sekizawa Prof. Dr. Osamu Ishitani Prof. Dr. Kazuhiko Maeda 《Angewandte Chemie (International ed. in English)》2015,54(8):2406-2409
A heterogeneous photocatalyst system that consists of a ruthenium complex and carbon nitride (C3N4), which act as the catalytic and light‐harvesting units, respectively, was developed for the reduction of CO2 into formic acid. Promoting the injection of electrons from C3N4 into the ruthenium unit as well as strengthening the electronic interactions between the two units enhanced its activity. The use of a suitable solvent further improved the performance, resulting in a turnover number of greater than 1000 and an apparent quantum yield of 5.7 % at 400 nm. These are the best values that have been reported for heterogeneous photocatalysts for CO2 reduction under visible‐light irradiation to date. 相似文献
993.
Stepanka Hrdlickova Kuckova Gabriela Rambouskova Radovan Hynek Pavel Cejnar Doris Oltrogge Robert Fuchs 《Journal of mass spectrometry : JMS》2015,50(11):1270-1278
Matrix‐assisted laser desorption/ionisation–time of flight (MALDI‐TOF) mass spectrometry is commonly used for the identification of proteinaceous binders and their mixtures in artworks. The determination of protein binders is based on a comparison between the m/z values of tryptic peptides in the unknown sample and a reference one (egg, casein, animal glues etc.), but this method has greater potential to study changes due to ageing and the influence of organic/inorganic components on protein identification. However, it is necessary to then carry out statistical evaluation on the obtained data. Before now, it has been complicated to routinely convert the mass spectrometric data into a statistical programme, to extract and match the appropriate peaks. Only several ‘homemade’ computer programmes without user‐friendly interfaces are available for these purposes. In this paper, we would like to present our completely new, publically available, non‐commercial software, ms‐alone and multiMS‐toolbox, for principal component analyses of MALDI‐TOF MS data for R software, and their application to the study of the influence of heterogeneous matrices (organic lakes) for protein identification. Using this new software, we determined the main factors that influence the protein analyses of artificially aged model mixtures of organic lakes and fish glue, prepared according to historical recipes that were used for book illumination, using MALDI‐TOF peptide mass mapping. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
994.
Fan Huang Jianzu Wang Aoting Qu Liangliang Shen Dr. Jinjian Liu Jianfeng Liu Dr. Zhenkun Zhang Yingli An Prof. Linqi Shi 《Angewandte Chemie (International ed. in English)》2014,53(34):8985-8990
The disruption of Aβ homeostasis, which results in the accumulation of neurotoxic amyloids, is the fundamental cause of Alzheimer’s disease (AD). Molecular chaperones play a critical role in controlling undesired protein misfolding and maintaining intricate proteostasis in vivo. Inspired by a natural molecular chaperone, an artificial chaperone consisting of mixed‐shell polymeric micelles (MSPMs) has been devised with tunable surface properties, serving as a suppressor of AD. Taking advantage of biocompatibility, selectivity toward aberrant proteins, and long blood circulation, these MSPM‐based chaperones can maintain Aβ homeostasis by a combination of inhibiting Aβ fibrillation and facilitating Aβ aggregate clearance and simultaneously reducing Aβ‐mediated neurotoxicity. The balance of hydrophilic/hydrophobic moieties on the surface of MSPMs is important for their enhanced therapeutic effect. 相似文献
995.
In this paper, a densimeter based on vibrating tube principle is used to determine experimentally the density of 1-butyl-2,3-dimethylimidazolium tris(pentafluoroethyl)trifluorophosphate and 1-butyl-2,3-dimethylimidazolium bis(trifluoromethylsulfonyl)imide at temperatures between (278.15 and 398.15) K and at pressures up to 120 MPa. The apparatus was calibrated by using water, vacuum and bromobenzene. The Tammann–Tait equation of state was used to correlate (p, T, ρ) results with standard deviations around 2 · 10−4 g · cm−3. Other volumetric properties, such as isothermal compressibility and isobaric thermal expansivity, were obtained from this equation. For each ionic liquid, the αp isotherms present a crossing point within the experimental pressure range. Besides, the effect that the C2-methylation in the imidazolium cation provokes on density values is analyzed. The prediction ability of the group contribution methods of Gardas and Coutinho and Jacquemin et al. were tested with the experimental densities. 相似文献
996.
In the present communication, we report the fundamental thermodynamic properties like volumetric and compressibility of very important bioactive compounds, viz. quinine hydrochloride, guanidine hydrochloride and quinic acid (0.01 to 0.1) mol · kg−1 in water at temperatures T = (278.15, 288.15 and 298.15) K. The experimental values of density (ρ) of aqueous solutions and speed of sound (u) in aqueous solutions of the above compounds within the concentration range (0.01 to 0.1) mol · kg−1 have been obtained. The apparent molar volumes (Vϕ), and apparent molar isentropic compressibilities (κϕ) of quinine hydrochloride, guanidine hydrochloride and quinic acid in water have been computed at three different temperatures. Speed of sound values have also been used to calculate the hydration number (nH) of the solute. The temperature dependence of the apparent molar volume has been used to calculate the thermal expansion coefficient (α1), apparent molar expansivity and Hepler’s constant . The derived parameters have been used to interpret the results in terms of (solute + solute)/(ion + ion), (solute + solvent) interactions, structure making and structure breaking tendencies of solutes in water. 相似文献
998.
光子晶体制备技术和应用研究进展 总被引：4，自引：0，他引：4
从光子晶体概念的提出到现在已经过了20余年,光子晶体不仅成为微纳光子学和量子光学的重要研究领域,而且在信息光学以及其他多个学科中得到广泛应用.本文重点综述了光子晶体的制备工艺,尤其是二维光子晶体和三维光子晶体的制备工艺进展,同时也综述了光子晶体的应用研究的进展,在此基础上,提出了一些光子晶体研究的展望. 相似文献
999.
近年来,人工带隙材料(如声子晶体和光子晶体)由于其优异的性能,已成为新一代智能材料的研究焦点.另一方面,材料拓扑学由凝聚态物理领域逐渐延伸到其他粒子或准粒子系统,而研究人工带隙材料的拓扑性质更是受到人们的广泛关注,其特有的鲁棒边界态,具有缺陷免疫、背散射抑制和自旋轨道锁定的传输等特性,潜在应用前景巨大.本文简要介绍拓扑材料特有的鲁棒边界态的物理图像及其物理意义,并列举诸如光/声量子霍尔效应、量子自旋霍尔效应、Floquet拓扑绝缘体等相关工作;利用Dirac方程,从原理上分析光/声拓扑性质的由来;最后对相关领域的发展方向和应用前景进行了相应的讨论. 相似文献
1000.
针对正则化极端学习机的隐层具有随机选择的特性,提出了一种增加删除机制来自适应地确定正则化极端学习机的隐层节点数. 这种机制以对优化目标函数影响的大小作为评价隐层节点优劣的标准,从而淘汰那些比较“差”的节点,将那些比较“优”的节点保留下来,起到一个优化正则化极端学习机隐层节点数的目的. 与已有的只具有增加隐层节点数的机制相比较,本文提出的增加删除机制在减少正则化极端学习机隐层节点数、增强其泛化性能、提高其实时性等方面具有一定的优势. 典型混沌时间序列的实例证明了具有增加删除机制的正则化极端学习机的有效性和可行性.关键词：混沌时间序列人工神经网络极端学习机 相似文献