同步相机测量任意频率光信号时的S/N理论分析

本文从理论上分析了同步扫描相机在测量由双波长激光器产生的差频信号时信噪比的问题.这一差频信号的频率和同步相机的扫描频率并非整数倍关系.我们从光电阴极的发射噪音(shotnoise)理论出发,得出了在这种特殊应用情况下相机的信嗓比比正常应用情况下(即入射光脉冲的频率和扫描频率为整数倍关系)至少要小23倍.     

On generalized shock models for deteriorating systems

Standard assumptions in shock models are that failures of items are related either to the cumulative effect of shocks (cumulative models) or that they are caused by shocks that exceed a certain critical level (extreme shocks models). In this paper, we present useful generalizations of this setting to the case when an item is deteriorating itself, for example, when the boundary for the fatal shock magnitude is decreasing with time. Three stochastic failure models describing different impacts of shocks on items are considered. The cumulative effect of shocks is modeled in a way similar to the proportional hazards model. Explicit formulas for the corresponding survival functions are derived and several simple examples are considered. Copyright © 2012 John Wiley & Sons, Ltd.     

A Multivariate Regime-Switching Mean Reverting Process and Its Application to the Valuation of Credit Risk

In this article, we study the counterparty risk on a credit default swap (CDS) and the valuation of a first-to-default basket swap on three underlyings under a common shock model with regime-switching intensities. We assume that the defaults of all the names are driven by some shock events, whose arrivals are governed by a multivariate regime-switching shot noise process. Based on some expressions for the joint Laplace transform of the regime-switching shot noise processes, we give explicit formulas for the spread of the CDS contract with and without counterparty risk and the spread of the first-to-default basket swap on the three underlyings.     

Spin-dependent negative differential conductance in transport through single-molecule magnets

Transport properties are theoretically studied through an anisotropy single-molecule magnet symmetrically connected to two identical ferromagnetic leads. It is found that even though in parallel configuration of leads’ magnetizations, the total current still greatly depends on the spin polarization of leads at certain particular bias region, and thus for large polarization a prominent negative differential conductance (NDC) emerges. This originates from the joint effect of single-direction transitions and spin polarization, which removes the symmetry between spin-up and spin-down transitions. The present mechanism of NDC is remarkably different from the previously reported mechanisms. To clarify the physics of the NDC, we further monitored the shot noise spectroscopy and found that the appearance of the NDC is accompanied by the rapid decrease of Fano factor.     

On the noise limit of stress and temperature measurements with micro‐Raman spectroscopy

We report for the first time on the thorough experimental and theoretical assessment of the noise limit of mechanical stress and temperature measurements with micro‐Raman spectroscopy. A comprehensive study has been performed in which, for different incident laser light intensities and acquisition times, 1000 Raman spectra of mono‐crystalline silicon were acquired per setting. Curve fitting was employed to obtain the peak positions of all the spectra, from which the standard deviations of the measured peak positions were obtained versus the total accumulated amount of laser light incident on the sample during one measurement. It has been found that the noise in the obtained peak position decreases as 1/sqrt(n) over more than three decades of the incident amount of laser light. At very low light conditions, the noise decreases as 1/n. By comparing the experimental results obtained to recent theoretical work, we show that the acquisition is limited by photon shot noise over most of the range and is limited by electronic detector noise at very low light conditions only. Pixelation errors do not play a role. It is concluded that the low electronic noise of typical Raman spectroscope detectors is overkill for the investigation of mechanical stress and temperature in silicon and other materials with comparable peaks, as it has absolutely no influence on the noise level of such an experiment. Maximum Raman signal intensity on the detector and high quantum efficiency detection are more important. Copyright © 2013 John Wiley & Sons, Ltd.     

相干介观系统中散粒噪声的Monte Carlo模拟方法研究

根据电荷通过低温量子导体时具有的二项分布导致散粒噪声这一结论,结合Landauer电流公式的物理内涵建立了相干介观系统中的散粒噪声模型,并通过Monte Carlo模拟方法产生了散粒噪声时间序列.介观系统中散粒噪声的抑制来源于电子输运时的相关性,传输本征值双峰分布导致量子混沌腔和无序金属中的散粒噪声抑制.根据这两个结论,通过Monte Carlo模拟定性地分析了传输本征值分布与电子输运相关性之间的关系. 关键词： 散粒噪声 Landauer公式 介观系统     

Comparison of monomethoxy‐, dimethoxy‐, and trimethoxysilane anchor groups for surface‐initiated RAFT polymerization from silica surfaces

The immobilization of reversible addition–fragmentation chain transfer (RAFT) agents on silica for surface‐initiated RAFT polymerizations (SI‐RAFT) via the Z‐group approach was studied systematically in dependence of the functionality of the RAFT‐agent anchor group. Monoalkoxy‐, dialkoxy‐, and trialkoxy silyl ether groups were incorporated into trithiocarbonate‐type RAFT agents and bound to planar silica surfaces as well as to silica nanoparticles. The immobilization efficiency and the structure of the bound RAFT‐agent film varied strongly in dependence of the used solvent (toluene vs. 1,2‐dimethoxyethane) and the anchor group functionality, as evidenced by atomic force microscopy, transmission electron microscopy, dynamic light scattering, and UV/Vis spectroscopy. Surface‐initiated RAFT polymerizations using functionalized silica nanoparticles revealed that grafted oligomers, which often occur in SI‐RAFT, are not formed within the crosslinked structures that originate from the immobilization, and that RAFT‐agent films that show less aggregation during the immobilization are more efficient during SI‐RAFT in terms of polymer grafting density. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 103–113     

单链系泊浮体受外碰撞时的锚链动态张力

介绍系泊浮体受外碰撞时锚链动态张力计算方法,并对动态张力的若干问题进行了讨论．     

Examining ligand-protein interactions with binding-energy landscapes

Binding-energy landscapes are used to investigate the thermodynamics of molecular recognition for the pteridine ring, a recognition anchor in binding with dihydrofolate reductase, and two molecules with the same shape but different heteroatom substitutions. The relative importance of hydrogen bonding and hydrophobic interactions in this system is analyzed by comparing these three different decorations of the pteridine scaffold. Received: 5 May 1998 / Accepted: 3 September 1998 / Published online: 17 December 1998     

一种利用激波进行落点测量的新方法

目前用于确定弹刃或导弹落点的声测方法多数是基于这样一个假定：其所发出的声波是一个平面波。但当其下落速度大于声速时,这个假定就不成立了,这时产生了一个锥面激波＾（４）,本文介绍了一种利用正方形基阵对其进行测量的方法。