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141.
Anik Peeters C. Van Alsenoy F. Bartha F. Bogr M.‐L. Zhang V. E. Van Doren 《International journal of quantum chemistry》2002,87(5):303-310
In earlier works the supermolecule model has been applied to the calculation of the Young's modulus of crystalline polyethylene and polyamide‐6. In the supermolecule model a crystalline polymer is represented as a single finite chain divided into a head, body, and tail part. The body contains a number of monomer units and is representative for a polymer chain. In this article, this model has been used to study the geometric properties and the elastic moduli of the α form of other polyamides: polyamide‐2 (or polyglycine), polyamide‐3, polyamide‐4, polyamide‐11, and polyamide‐6,6. All calculations have been performed with a linearly constrained body. The results have been compared to other theoretical and experimental results if available. © 2002 Wiley Periodicals, Inc.; DOI 10.1002/qua.2002;10121 相似文献
142.
《Physics letters. A》2014,378(38-39):2876-2880
In recent years, synthesizing inorganic nanostructures such as boron nitride nanotubes (BNNTs) has led to extensive studies on their exceptional properties. In this study, the torsional vibration behavior of boron-nitride nanotubes (BNNTs) is explored on the basis of molecular dynamics (MD) simulation. The results show that the torsional frequency is sensitive to geometrical parameters such as length and boundary conditions. The axial vibration is found to be induced by torsional vibration of nanotubes which can cause instability in the nanostructure. It is also observed that the torsional frequency of BNNTs is higher than that of their carbon counterpart. Moreover, the shear modulus is predicted by incorporating MD simulation numerical results into torsional vibration frequency obtained through continuum-based model of tubes. Finally, it is seen that the torsional frequency of double-walled boron-nitride nanotubes (DWBNNTs) is between the frequencies of their constituent inner and outer tubes. 相似文献
143.
对食管黏膜组织沿轴向分别以不同的延伸率进行延伸,再通过往复摩擦试验近似模拟内镜前端进入食管的过程,研究了食管黏膜组织在不同轴向延伸率伸长下的摩擦性能变化.结果表明:从轴向无延伸到延伸率达到80%时,内镜前端与食管黏膜组织间的摩擦运行行为从食管黏膜组织只发生弹性变形的黏着状态变化到黏着和滑移的混合状态,摩擦阻力和能耗增大,摩擦系数增加.食管黏膜组织的摩擦学性能与其表面结构和力学性能密切相关.在沿轴向延伸率逐渐增加的延伸状态下,食管黏膜表面的皱褶被拉平,维持黏液润滑的特性变差;随着食管黏膜组织轴向延伸率的增加,黏膜组织的弹性模量增加,抵抗摩擦变形的能力增强,摩擦阻力增大.研究结果为临床胃镜诊疗的安全操作提供了理论依据. 相似文献
144.
Prof. Dr. Yoshinobu Isono Toshihiro Kamohara Atsushi Takano Toshio Kase 《Rheologica Acta》1997,36(3):245-251
Simultaneous measurements of stress relaxation and differential dynamic modulus were made at 268 K over a time scale of 10 to 1045 s for nearly monodisperse polybutadiene (M
w
=2.2x105, 1,2-structure 70%, M
e
=3600) and also one having coarse cross-linking (M
c
=29000). Static shear strain ranged from 0.1 to 2.0. In a long-time region (t>
k
), the relaxation modulus G (; t) could be expressed by the product G (0; t) h (y). The observed h() agreed well with the Doi-Edwards theory without use of IA approximation. Both the cured and uncured samples showed initial drop of the differential storage modulus G (), ; t) followed by gradual recovery, but did not attain the value before shearing G (, ; t) for the uncured sample showed smaller values than that for the cured one in the whole measured time scale at the higher strain, confirming the two origins of nonlinear viscoelasticity of well entangled polymer; induced chain anisotropy and induced decrement in entanglement density. G (, ; t) curves for the cured sample agreed well with the BKZ predictions. But the curves for the uncured sample agreed well with the BKZ prediction only at the time scale of t<
k
. BKZ prediction showed significant upward deviations at t>
k
. Such the differences are discussed in terms of the two origins.Dedicated to Prof. John D. Ferry on the occasion of his 85th birthday. 相似文献
145.
146.
The elastic and thermodynamic characteristics of OsC crystal have been predicted through a method of density functional theory within the generalized gradient approximation (GGA). Compared with WC-type OsC, NaCl-type OsC is not only energy unfavorable but also mechanics unstable. The five independent elastic constants (Cij), bulk modulus (B0), the dependence of bulk modulus on temperature and pressure as well as the thermal expansion coefficient (αV) at various temperatures for WC-type OsC are discussed. According to our calculations, WC-type OsC should be an ultra-incompressible material with high bulk modulus about 381 GPa. In addition, the bulk modulus will increase with increasing pressure while decrease with increasing temperature. The researches on the thermal expansion coefficient indicate that there will be a knee point during the process of thermal expansion coefficient variation versus increasing temperature. Our results may provide useful information for theoretical and experimental investigation of OsC. 相似文献
147.
Tooru Kitagawa Kohji Tashiro Kazuyuki Yabuki 《Journal of Polymer Science.Polymer Physics》2002,40(13):1281-1287
Fourier transform Raman spectra were measured for poly‐p‐phenylenebenzobisoxazole (PBO) fiber subjected to a tensile stress, and the Raman shift factor (the frequency shift caused by 1 GPa tensile stress) depended strongly on the sample‐preparation condition. To clarify the reasons of this dependency, a mechanical series parallel model was adopted that could successfully and quantitatively explain the observed Raman shift factors and gave a concreate heterogeneous stress distribution in the PBO fibers. As a result, a mechanical series model was reasonable for PBO fiber. Broadening of Raman bands, which was observed when the PBO fiber was tensioned, could also be interpreted on the basis of an idea of heterogeneous stress distribution. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 1281–1287, 2002 相似文献
148.
Thirty four distinct composition series arising out of the 32 crystallographic double point groups are employed to re-derive
in a simple and elegant fashion all the 169 distinct colour symmetry groups generated by the 32 double point groups, exploiting
the idea of colour generators. The advantage of the method employed and some possible applications of these colour groups
are discussed. The resulting colour groups are tabulated. 相似文献
149.
Joaquin Valencia Juan Baselga Ines F. Pierola 《Journal of Polymer Science.Polymer Physics》2009,47(11):1078-1087
Several hydrogels of N‐vinylimidazole and sodium styrenesulfonate have been prepared by radical cross‐linking copolymerization in aqueous solution, using N,N′‐methylene‐bisacrylamide as crosslinker. Depending on composition, these hydrogels were neutral, amphoteric, cationic or anionic. Compression‐strain measurements were performed on samples as‐synthesized and swollen in deionized water or in acid aqueous solutions, with and without salt. It was thus found that the cross‐linking densities determined by compression measurements on as‐synthesized samples are in good accordance with those calculated by means of the model of polymer networks with pendant vinyl groups. A non‐Gaussian parameter (β) was introduced to explain that the elastic moduli (G) of samples swollen at equilibrium are larger than predicted by the Gaussian model. The β values of the neutral or ionized systems increase with swelling and fall into a single curve, which denotes a common behavior. Swelling has two opposite effects on G; on the one hand G decreases because the polymer volume fraction diminish and the system shifts from the affine limit to the phantom one; on the other, β increases and contributes to increasing G. The balance of those two opposite effects determines the variation of G with swelling. The possible contribution of ionic crosslinks to νe for the polyampholyte and for the polycation wearing divalent counteranions was discussed. A peculiar system is poly(sodium styrenesulfonate), whose cross‐linking density is much lower than expected. © 2009 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 47: 1078–1087, 2009 相似文献
150.
Jessica A. Zimberlin Alfred J. Crosby 《Journal of polymer science. Part A, Polymer chemistry》2010,48(13):1423-1427
Using the cavitation rheology (CR) technique developed in our labs, we show that fluids with negligible interfacial tensions with a surrounding material can be used to induce an elastic, cavitation instability in that material. We do this by changing the cavitation media from air, which was demonstrated to induce cavitation at the tip of a syringe needle in previous studies, to water, which has a negligible surface tension with the surrounding poly(vinyl alcohol) hydrogel material. In this case, the critical pressure in which this instability occurs can be directly related to the elastic modulus of the surrounding network and is shown to be nearly independent of length scale. This independence of size scale has important implications in the use of CR for the characterization of mechanical properties from molecular to macroscopic length scales. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 1423–1427, 2010 相似文献