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131.
Various state-equations, derived by expanding energy as a function of volume in Taylor series and using different order Pade’s
approximants, have been combined with quasi-harmonic approximation for free energy to reproduce the pressure dependence of
thermodynamic properties of NaBr, NaI and AgCl crystals. We have used these state-equations to compute the reduced volume,
the isothermal bulk modulus and the pressure derivative of isothermal bulk modulus for the three crystals at various pressures
(up to 80 kbar) and at room temperature (T=298 K). The results obtained are reasonably good lending support to the state-equations and the technique used to extend
their applicability. The significant results obtained in the present study include the unified reduced equation of state for
the three crystals which generates almost a single curve for theP – V behaviour at room temperature. 相似文献
132.
133.
A UNIFIED ENERGY APPROACH TO A CLASS OF MICROMECHANICS MODELS FOR MICROCRACKED SOLIDS 总被引:2,自引:0,他引:2
Y.Huang K.C.Hwang 《Acta Mechanica Solida Sinica》1995,8(2):110-120
Micromechanics models have been developed for the determination ofthe elastic moduli of microcracked solids based on different approaches andinterpretations,including the dilute or non-interacting solution,the Mori-Tanakamethod,the self-consistent method,and the generalized self-consistent method.It isshown in the present study that all these micromechanics models can be unified withinan energy-equivalence framework,and that they differ only in the way in which themicrocrack opening and sliding displacements are evaluated.Relevance to thedifferential methods and the verification of these models are discussed. 相似文献
134.
Giuliana Gorrasi Loredana Tammaro Mariarosaria Tortora Vittoria Vittoria Dirk Kaempfer Peter Reichert Rolf Mülhaupt 《Journal of Polymer Science.Polymer Physics》2003,41(15):1798-1805
Isotactic polypropylene nanocomposites were obtained by the melt blending of polypropylene‐graft‐maleic anhydride and organophilic layered silicate (OLS) consisting of synthetic fluorohectorite modified by cation exchange with protonated octadecylamine. The composition of the inorganic clay was varied between 2.5 and 10 wt %, and films of the composites were obtained via hot‐press molding. X‐ray analysis showed that nanocomposites in which silicate layers were either delaminated or ordered as in an intercalated structure were obtained. The elastic modulus of the samples was higher than that of the pure polymer over a wide temperature range and increased with increasing inorganic content. The transport properties, sorption and diffusion, were measured for two organic vapors, dichloromethane and n‐pentane. For both vapors, the sorption was not very different from that of the pure polymer, whereas the zero‐concentration diffusion parameter strongly decreased with increasing OLS content. Therefore, the permeability, that is, the product of sorption and diffusion, decreased for both vapors as a result of the decreased value of the diffusion parameter. The decrease was higher for the less interacting n‐pentane. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1798–1805, 2003 相似文献
135.
136.
Model networks of poly(dimethylsiloxane) (PDMS) were prepared by tetrafunctionally endlinking hydroxyl-terminated chains of various molecular weights. Some networks were prepared from mixtures of chains so as to yield a bimodal distribution of network chain lengths and, in some cases, these networks were prepared in solution. The stress–strain behavior of these unimodal and bimodal networks was studied in pure shear, which was imposed by stretching a sheet of the network having a large ratio of width to length in the direction perpendicular to the width. The pure-shear moduli of both types of networks generally were found to depend markedly on strain. Stress–strain isotherms for unimodal networks prepared from chains of one or the other of two molecular weights were well interpreted using the constrained-junction model of Flory and Erman. The bimodal networks showed large increases in the pure-shear modulus at high strains which were similar to those reported for uniaxial extension and compression. Endlinking in solution decreases the modulus in general and its upturn in particular, presumably because of diminished chain-junction entangling. 相似文献
137.
The problem of approximation by algebraic polynomials is considered on function classes characterized by the value of thekth generalized modulus of smoothness defined by the Jacobi generalized shift operator.
Translated fromMatematicheskie Zametki, Vol. 63, No. 3, pp. 425–436, March, 1998. 相似文献
138.
At relatively high temperatures and low frequencies the electrical properties of many polymers are dominated by ionic conductivity. In cases where the glass transition is obscured by conductivity, it can be revealed by treating the data in terms of the electric modulus. The magnitude of the activation energy for conductivity (24–67 kcal/mol) for Nylons 6, 66, and 6I, polybutylene terephthalate, and polycarbonate indicates that the transport of charged particles requires the motion of polymer segments. 相似文献
139.
140.
借助于光滑模ωψ^rλ(f,t)(0≤λ≤1)给出了Bernstein算子线性组合同时逼近的点态结果。 相似文献