首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   2918篇
  免费   193篇
  国内免费   119篇
化学   1024篇
晶体学   11篇
力学   117篇
综合类   4篇
数学   1213篇
物理学   861篇
  2024年   3篇
  2023年   28篇
  2022年   49篇
  2021年   41篇
  2020年   106篇
  2019年   71篇
  2018年   67篇
  2017年   42篇
  2016年   84篇
  2015年   82篇
  2014年   141篇
  2013年   299篇
  2012年   127篇
  2011年   154篇
  2010年   139篇
  2009年   226篇
  2008年   174篇
  2007年   217篇
  2006年   184篇
  2005年   123篇
  2004年   127篇
  2003年   126篇
  2002年   90篇
  2001年   77篇
  2000年   74篇
  1999年   57篇
  1998年   68篇
  1997年   54篇
  1996年   40篇
  1995年   28篇
  1994年   31篇
  1993年   13篇
  1992年   14篇
  1991年   16篇
  1990年   3篇
  1989年   6篇
  1988年   8篇
  1986年   4篇
  1985年   7篇
  1984年   5篇
  1983年   3篇
  1982年   2篇
  1981年   4篇
  1978年   4篇
  1977年   4篇
  1975年   1篇
  1974年   1篇
  1973年   1篇
  1971年   1篇
  1967年   1篇
排序方式: 共有3230条查询结果,搜索用时 15 毫秒
991.
We are concerned with magneto-micropolar fluid equations (1.3)(1.4). The global existence of solutions to the Cauchy problem is investigated under certain conditions. Precisely, for the magneto-micropolar-Navier–Stokes (MMNS) system, we obtain global existence and large time behavior of solutions near a constant states in R3. Appealing to a refined pure energy method, we first obtain a global existence theorem by assuming that the H3 norm of the initial data is small, but the higher order derivatives can be arbitrary large. If the initial data belongs to homogeneous Sobolev norms H˙?s (0s<32) or homogeneous Besov norms B˙2,?s (0<s32), we obtain the optimal decay rates of the solutions and its higher order derivatives. As an immediate byproduct, we also obtain the usual Lp?L2 (1p2) type of the decay rates without requiring that the Lp norm of initial data is small. At last, we derive a weak solution to (1.3)(1.4) in R2 with large initial data.  相似文献   
992.
The hydrodynamic limit of the Ginzburg–Landau ?? interface model was derived in Funaki and Spohn (1997) and Nishikawa (2003) for strictly convex potentials. This paper deals with non-convex potentials under suitable assumptions on the free energy and identification of the extremal Gibbs measures which have been recently established at sufficiently high temperature in Cotar and Deuschel (2012). Because of the non-convexity, many difficulties arise, especially, on the identification of equilibrium states. We show the equivalence between the stationarity and the Gibbs property under quite general settings, and we complete the identification of equilibrium states. We also establish some uniform estimates for variances of extremal Gibbs measures.  相似文献   
993.
More than two decades ago, in a seminal paper John Cahn proposed scaling arguments for the possibility of a wetting transition in two coexisting fluid phases near the critical point. Since then, Cahn's model has been tested in many fluid systems and further refined by including the real interactions between the fluid and the solid wall. A fascinating consequence of the existence of a wetting transition is the possibility for a transition from weak to strong adsorption in the homogeneous phase. The situation is further enriched in nonstandard geometries having special geometrical constraints. The subject of this review concerns one such situation, where charge-stabilized colloidal particles are suspended in the homogeneous region of a binary liquid mixture. In this case, the preferential adsorption of one of the liquid components on to the colloid surface completely modifies the stability of the particles leading to an aggregation process. Although the exact mechanism underlying the adsorption phenomenon is still debated, it is closely related to the wetting transition. Recent experimental developments concerning the static and dynamic aspects of this phenomenon are reviewed. In addition, the main findings of a theoretical model based on the adsorption-modified electrostatic interactions between the colloidal particles are discussed.  相似文献   
994.
The active oxygen gas arising from a plasma reactor is used to realize progressive chemical modifications onto silane coatings that could be particularly interesting as alignment layers for liquid crystal display applications. Depending on the oxygen density grafted onto the substrate, these alignment layers provide different zenithal anchoring angles, or pretilt angles, with anchoring transitions, for polar and non-polar nematic liquid crystals as 5CB and MBBA, respectively. The anchoring transitions are found to be smoother with the polar nematics. Such a behavior is discussed in terms of the differential wetting model by adding a cosine term to the interaction energy between the nematic and the substrate. A local justification is proposed for this symmetry breaking term. Received: 18 May 1998  相似文献   
995.
We consider the electrostatic interaction between two rigid membranes, with different surface charge densities of opposite sign, across an aqueous solution without added salt. Exact solutions to the nonlinear Poisson-Boltzmann equation are obtained and their physical meaning discussed. We also calculate the electrostatic contribution to the free energy and discuss the renormalization of the area per head group of the charged lipids arising from the Coulomb interaction. Received 13 October 1998  相似文献   
996.
报道对芳香氮化物吡咯(C4H5N)、苯(C6H5NH2)、对位氯代吡啶(C5H4NCl)、吡啶(C5H5N)及吡咯负离子(C4H4N^-)与三氯甲烷(CHCl3)形成的系列弱作用复合物的理论计算结果。把复合物看作是一个超分子在密度泛函B3LYP/6-311G(d,p)的水平上进行计算,探讨该系列复合物的稳定性规律、电荷转移及主要几何参数变化等规律,计算结果表明:此类芳香氮化物与三氯甲(CH3l3)  相似文献   
997.
A selection of recent theoretical and experimental studies on electrolytic hydrogen evolution is presented. It is demonstrated with well-defined model surfaces that this reaction is a very structure-sensitive process. Crystallographic orientation, defect density and surface composition are parameters that determine the local geometric and electronic surface structure, and are thus crucial for the electrocatalytic activity as characterised by the exchange current density. The observed trends can be understood within a recent theory by J. K. N?rskov et al., which is based on density functional calculations and which emphasises the impact of hydrogen chemisorption energies on the reaction rate, that is, on the exchange current density. The particular electrocatalytic activities of ultrathin metal films and of nanostructures are addressed.  相似文献   
998.
We study the charge profile of a C60-FET (field effect transistor) as used in the experiments of Sch?n, Kloc and Batlogg. Using a tight-binding model, we calculate the charge profile treating the Coulomb interaction in a mean-field approximation. At low doping, the charge profile behaves similarly to the case of a continuous space-charge layer and becomes confined to a single interface layer for doping higher than 0.3 electron (or hole) per C60 molecule. The morahedral disorder of the C60 molecules smoothens the structure in the density of states. Received 21 June 2001  相似文献   
999.
Nacre, stratified ceramic layers surrounded by organic matrix, is a tough material found inside certain seashells. We construct a coarse-grained elastic energy for such an anisotropic system and present an analytic solution for a notch crack normal to the stratified sheets. This analysis proves the reduction in stress concentration which was announced in our earlier work (P. G. de Gennes and K. Okumura, C. R. Acad. Sci. Paris 1, Ser. IV, 257 (2000)) and the related increase in toughness. Received 18 March 2000  相似文献   
1000.
The knowledge of the structure and orientation of polymer chains adsorbed at an interface could be of major importance to predict the level of interfacial interactions and adhesion that depend strongly on the properties of the interface formed between the two materials (polymer and substrate) brought into contact. In this work, we were interested to study thin films of atactic polystyrene after adsorption (spin‐coating) on two chemically different substrates (inert and OH‐grafted gold substrates). The main aim is to analyze the resulting anisotropy due to the confinement in a quasi‐bidimensional geometry, as well as to investigate the incidence of the interfacial interactions, potentially established between the polymer and the surface, on the chain organization. Our infrared spectroscopy results allowed us to access the adsorption model of polystyrene chains and to highlight the relation between chain orientation and interfacial acid–base interactions. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 1268–1276, 2006  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号