Application of a multivariate approach for analyte focusing by micelle collapse‐micellar electrokinetic chromatography for analyzing sunscreen agents in cosmetics

The operating parameters that affect the performance of the online preconcentration technique “analyte focusing by micelle collapse‐MEKC (AFMC‐MEKC)” were examined using a multivariate approach involving experimental design to determine the sunscreen agents in cosmetics. Compared to the single‐variable approach, the advantage of the multivariate approach was that many factors could be investigated simultaneously to obtain the best separation condition. A fractional factorial design was used to identify the fewest significant factors in the central composite design (cCD). The cCD was adopted for evaluating the location of the minimum or maximum response in this study. The influences of the experimental variables on the response were investigated by applying a chromatographic exponential function. The optimized condition and the relationship between the experimental variables were acquired using the JMP software. The ANOVA analysis indicated that the Tris pH value, SDS concentration, and ethanol percentage influenced the separation quality and significantly contributed to the model. The optimized condition of the running buffer was 10 mM Tris buffer (pH 9.5) containing 60 mM SDS, 7 mM γ‐CD, and 20% v/v ethanol. The sample was prepared in 100 mM Tris buffer (pH 9.0) containing 7.5 mM SDS and 20% v/v ethanol. The SDS concentration in the sample matrix was slightly greater than the CMC value that makes the micelle be easily collapsed and the analytes be accumulated in the capillary. In addition, sunscreen agents in cosmetics after 1000‐fold dilution were successfully determined by AFMC‐MEKC.     

基于可拓和组合赋权的矿井通风系统优化评价

矿井通风系统具有随机性、模糊性和不确定性等特征,一般单一的赋权评价法难以对其进行准确的优化评价.采用模糊层次分析法和熵权法的组合赋权法不仅可以提升对目标评价的准确性还能避免单一赋权的偶然性和局限性,结合可拓学的优度评价法,依据优度排序,得到最优方案.事实证明,基于组合赋权的可拓评价模型较其他评价方法更为客观,评价结果更加符合实际,可为解决类似优化方案问题提供一种新思路和方法.     

矿山层状反倾边坡岩体移动规律的试验研究

本文基于现代工程地质力学理论与相似模拟原理, 采用地质力学模拟试验方法, 以某矿顶帮边坡为工程实例, 结合大量滑坡实例综合分析, 研究了层状反倾边坡岩体随采矿工程发展的移动规律和潜在滑坡模式。     

岩爆与围岩分类

岩爆是高地应力条件下完整脆性硬质围岩失稳的一种表现型式,岩爆烈度如何影响围岩类别尚不清楚,探索岩爆与围岩分类的关系,对准确判别高地应力条件下的围岩类别有着重要意义。本文以某深埋隧洞围岩分类为依据,对我国水利水电地下洞室围岩分类中岩爆烈度与围岩类别的关系、岩爆判别指标的选取等问题进行了探讨。     

澜沧江某电站左岸地下洞室群围岩稳定性的FLAC~(3D)分析

在岩体结构模型概化的基础上,采用FLAC3D数值分析方法,系统研究了澜沧江某大型水电站大跨度、高边墙地下洞室群开挖完成后围岩的二次应力场、变形场和塑性破坏区的变化特征。总结了地下洞室群围岩应力、变形和破坏区的分布特征和变化规律,为洞室群稳定性评价和工程施工设计提供了基础资料和参考依据。     

阶梯AlGaN外延新型Al0.25Ga0.75N/GaNHEMTs器件实验研究

本文报道了作者提出的阶梯AlGaN外延层新型AlGaN/GaN HEMTs结构的实验结果. 实验利用感应耦合等离子体刻蚀(ICP)刻蚀栅边缘的AlGaN外延层, 形成阶梯的AlGaN 外延层结构, 获得浓度分区的沟道2DEG, 使得阶梯AlGaN外延层边缘出现新的电场峰, 有效降低栅边缘的高峰电场, 从而优化了AlGaN/GaN HEMTs器件的表面电场分布. 实验获得了阈值电压-1.5 V的新型AlGaN/GaN HEMTs器件. 经过测试, 同样面积的器件击穿电压从传统结构的67 V提高到新结构的106 V, 提高了58%左右; 脉冲测试下电流崩塌量也比传统结构减少了30%左右, 电流崩塌效应得到了一定的缓解.     

A solution approach for optimizing long- and short-term production scheduling at LKAB’s Kiruna mine

We present a mixed-integer program to schedule long- and short-term production at LKAB’s Kiruna mine, an underground sublevel caving mine located in northern Sweden. The model minimizes deviations from monthly preplanned production quantities while adhering to operational constraints. Because of the mathematical structure of the model and its moderately large size, instances spanning a time horizon of more than a year or two tend to be intractable. We develop an optimization-based decomposition heuristic that, on average, obtains better solutions faster than solving the model directly. We show that for realistic data sets, we can generate solutions with deviations that comprise about 3-6% of total demand in about a third of an hour.     

平面张弦结构抗连续倒塌的动力分析

杆件由于爆炸、腐蚀等发生脆性破坏后引起剩余结构的振动和压杆由于失稳过程中的弹性突跳（Snap-through）引起的相邻结构振动是张弦结构倒塌过程中常伴生的两种动力现象。本文对第一种动力响应产生的原因、失效构件的模拟方法进行了分析,说明进行张弦结构抗连续倒塌的动力分析应采用初始条件法模拟构件的失效。根据张弦结构的特点,从构件失效和结构失效两方面提出了张弦结构倒塌失效的评估准则,并采用变换荷载路径法通过静力连续倒塌分析找出张弦结构各部分的关键构件;然后采用初始条件法按考虑几何非线性、阻尼比、材料非线性等分别模拟这些关键构件失效引起的动力响应,得到了平面张弦结构各部分构件失效的动力特性、动力放大系数和失效构件的位置,并对不同失效时间进行动力响应分析得到张弦结构动力效应与构件失效时间的关系曲线。最后给出张弦结构进行抗连续倒塌分析的一些结论和建议,如进行连续倒塌动力时程分析时初始失效杆件选取和失效时间取值以及弹性动力放大系数与塑性动力放大系数的区别等,为张弦结构的抗连续倒塌设计提供技术支持和参考。     

砌体结构破坏倒塌过程的离散单元模拟

基于传统颗粒离散单元模型（DEM）,开发了一种绑定式离散单元模型（BTDEM）用于砌体结构崩塌机制的研究,并对一个典型砌体结构的破坏倒塌过程进行数值模拟。结果证实BTDEM方法能够详细地模拟出砌体建筑结构的崩塌过程,同时还可以模拟出砌块的破碎,是一种普适性较强的模拟砌体结构建筑的高效数值方法。BTDEM方法具有计算速度...     

Scattering experiments on polymer solutions

Laser light-scattering characterization of poly(tetrafluoroethylene) (PTFE) in a perfluoroalkane (perfluorotetracosane) or oligomers of poly(chlorotrifluoroethylene) at temperatures near the crystalline melting point of PTFE and studies of the coil-to-globule transition for polystyrene in cyclohexane are reviewed. Discussions on approach to solving some experimental problems are emphasized. © 1993 John Wiley & Sons, Inc.