静电喷雾结合热压处理制备荷负电PVA-SA/PAN纳米纤维基复合滤膜及其纳滤性能研究

以静电纺丝聚丙烯腈(PAN)纳米纤维作为多孔支撑层,以亲水材料聚乙烯醇(PVA)和海藻酸钠(SA)为亲水表层材料,通过静电喷雾技术将亲水表层材料沉积在纳米纤维多孔基膜表面,然后将表层PVA-SA纳米串珠层通过水蒸气加湿辅助热压成膜处理在PAN基膜上软化压延形成完整的致密薄膜,最后经过戊二醛交联制备PVA-SA/PAN纳米纤维基复合滤膜.通过对加湿时间、热压温度、热压时间以及PVA-SA静电喷雾时间等成膜工艺条件和交联条件进行优化制备出结构完整的PVA-SA/PAN纳米纤维基复合滤膜.所制备的复合滤膜荷负电,它对阴离子染料具有较好的过滤效果:在0.6 MPa的操作压力下对100 mg/kg的固绿染料的渗透通量为57.1 L/(m~2h),截留率为96.8%.     

The influence of radiation-induced vacancy on the formation of thin-film of compound layer during a reactive diffusion process

A theoretical approach is developed that describes the formation of a thin-film of AB-compound layer under the influence of radiation-induced vacancy. The AB-compound layer is formed as a result of a chemical reaction between the atomic species of A and B immiscible layers. The two layers are irradiated with a beam of energetic particles and this process leads to several vacant lattice sites creation in both layers due to the displacement of lattice atoms by irradiating particles. A- and B-atoms diffuse via these lattice sites by means of a vacancy mechanism in considerable amount to reaction interfaces A/AB and AB/B. The reaction interfaces increase in thickness as a result of chemical transformation between the diffusing species and surface atoms (near both layers). The compound layer formation occurs in two stages. The first stage begins as an interfacial reaction controlled process, and the second as a diffusion controlled process. The critical thickness and time are determined at a transition point between the two stages. The influence of radiation-induced vacancy on layer thickness, speed of growth, and reaction rate is investigated under irradiation within the framework of the model presented here. The result obtained shows that the layer thickness, speed of growth, and reaction rate increase strongly as the defect generation rate rises in the irradiated layers. It also shows the feasibility of producing a compound layer (especially in near-noble metal silicide considered in this study) at a temperature below their normal formation temperature under the influence of radiation.     

Classification of Gauge Orbit Types for SU(n)-Gauge Theories

A method for determining the orbit types of the action of the group of gauge transformations on the space of connections for gauge theories with gauge group SU(n) in spacetime dimension d4 is presented. The method is based on the one-to-one correspondence between orbit types and holonomy-induced reductions of the underlying principal SU(n)-bundle. It is shown that the orbit types are labelled by certain cohomology elements of spacetime satisfying two relations. Thus, for every principal SU(n)-bundle the corresponding stratification of the gauge orbit space can be explicitly determined. As an application, a criterion characterizing kinematical nodes for physical states in Yang–Mills theory with the Chern–Simons term proposed by Asorey et al. is discussed.     

Infinite-dimensional gauge groups and special nonlinear gravitons

A gauge theory in flat space—time, in which the gauge algebra is the (infinite-dimensional) algebra of vector fields on a surface, determines a curved space—time metric. This note deals with some completely integrable examples, concentrating on the N → ∞ limit of the Euler—Arnol'd equations [geodesics on SO(N)]. In this case, the metric turns out to be flat, which points the way to a coordinate transformation that solves the original equations.     

Variations on the warped deformed conifold

The warped deformed conifold background of type IIB theory is dual to the cascading SU(M(p+1))×SU(Mp) gauge theory. We show that this background realizes the (super-)Goldstone mechanism where the U(1) baryon number symmetry is broken by expectation values of baryonic operators. The resulting massless pseudo-scalar and scalar glueballs are identified in the supergravity spectrum. A D-string is then dual to a global string in the gauge theory. Upon compactification, the Goldstone mechanism turns into the Higgs mechanism, and the global strings turn into ANO strings. To cite this article: S.S. Gubser et al., C. R. Physique 5 (2004).

Résumé

La configuration de fond pour la théorie de type IIB donnée par le conifold voilé déformé est duale à la cascade de théorie de jauge SU(M(p+1))×SU(Mp). Nous montrons que cette configuration donne une réalisation du mécanisme de (super-)Goldstone où la symètrie baryonique U(1) est brisée par la valeur moyenne dans le vide des opérateurs baryoniques. Les boules de glue pseudo-scalaires et scalaires de masse nulle résultantes sont identifiées dans le spectre de supegravité. Une D-corde est alors duale à une corde globale dans la théorie de jauge. Après compactification, le mécanisme de Goldstone devient un mécanisme de Higgs, et une corde globale devient une corde ANO. Pour citer cet article : S.S. Gubser et al., C. R. Physique 5 (2004).     

Higher spin gauge theories in any dimension

Some general properties of higher spin gauge theories are summarized, with the emphasize on the nonlinear theories in any dimension. To cite this article: M.A. Vasiliev, C. R. Physique 5 (2004).

Résumé

Des propriétés générales des théories de jauge de grands spins sont présentées, en insistant particulièrement sur les théories non-linéaires en dimensions diverses. Pour citer cet article : M.A. Vasiliev, C. R. Physique 5 (2004).     

Gauge-Invariant Regularization of Quantum Field Theory on the Light Front

We briefly describe problems of the Hamiltonian approach for quantizing gauge fields on the light front for space–time bounded by the inequality |x ^–|L with periodic boundary conditions in the variable x ^– imposed on all fields (the DLCQ method). With these restrictions, we consider the gauge-invariant ultraviolet regularization by passing to a lattice in transverse coordinates. We remove the remaining ultraviolet divergences in the longitudinal momentum p _– by imposing a gauge-invariant finite-mode regularization. It turns out that the canonical formalism on the light front with such a regularization imposed does not contain the usual most complicated second-class constraints between zero and nonzero modes of fields. The described scheme can be used both to regularize the standard gauge theory and to provide a gauge-invariant formulation of effective low-energy models on the light front. Because the manifest Lorentz invariance is broken in our formalism, the vacuum state is poorly defined. We discuss this problem, in particular, in relation to the problem of passing to the continuous space limit.     

Infrared Variables for the SU(3) Yang–Mills Field

We generalize the self-dual parameterization of the SU(2) Yang–Mills field proposed by Niemi and Faddeev for describing the infrared limit of the theory to the case of the gauge group SU(3). We demonstrate that the duality property intrinsic to the SU(2) gauge field cannot be transferred automatically to the higher-rank group case. We interpret the algebraic structures appearing in the Lagrangian for the new compact variables in terms of the group products SU(2)³.     

On fillable contact structures up to homotopy

Let be a closed, oriented -manifold. The set of homotopy classes of positive, fillable contact structures on is a subtle invariant of , known to always be a finite set. In this paper we study under the assumption that carries metrics with positive scalar curvature. Using Seiberg-Witten gauge theory, we prove that two positive, fillable contact structures on are homotopic if and only if they are homotopic on the complement of a point. This implies that the cardinality of is bounded above by the order of the torsion subgroup of . Using explicit examples we show that without the geometric assumption on such a bound can be arbitrarily far from holding.

     

On the Evaluation of the Evolution Operator Z Reg( R 2, R 1) in the Diakonov–Petrov Approach to the Wilson Loop

We evaluate the evolution operator Z _Reg(R ₂,R ₁) introduced by Diakonov and Petrov for the definition of the Wilson loop in terms of a path integral over gauge degrees of freedom. We use the procedure suggested by Diakonov and Petrov (Physics Letters B 224 (1989) 131) and show that the evolution operator vanishes. PACS numbers: 11.10.-z; 11.15.-q; 12.38.-t; 12.38.Aw; 12.90.+b.