全文获取类型
收费全文 | 692篇 |
免费 | 60篇 |
国内免费 | 39篇 |
专业分类
化学 | 89篇 |
晶体学 | 6篇 |
力学 | 118篇 |
综合类 | 7篇 |
数学 | 411篇 |
物理学 | 160篇 |
出版年
2023年 | 10篇 |
2022年 | 6篇 |
2021年 | 19篇 |
2020年 | 13篇 |
2019年 | 23篇 |
2018年 | 17篇 |
2017年 | 22篇 |
2016年 | 27篇 |
2015年 | 28篇 |
2014年 | 38篇 |
2013年 | 70篇 |
2012年 | 29篇 |
2011年 | 31篇 |
2010年 | 28篇 |
2009年 | 31篇 |
2008年 | 36篇 |
2007年 | 43篇 |
2006年 | 30篇 |
2005年 | 21篇 |
2004年 | 30篇 |
2003年 | 23篇 |
2002年 | 30篇 |
2001年 | 26篇 |
2000年 | 21篇 |
1999年 | 14篇 |
1998年 | 21篇 |
1997年 | 16篇 |
1996年 | 11篇 |
1995年 | 8篇 |
1994年 | 8篇 |
1993年 | 3篇 |
1992年 | 9篇 |
1991年 | 3篇 |
1990年 | 8篇 |
1989年 | 2篇 |
1988年 | 4篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 5篇 |
1984年 | 4篇 |
1983年 | 2篇 |
1982年 | 4篇 |
1981年 | 5篇 |
1980年 | 3篇 |
1979年 | 1篇 |
1977年 | 1篇 |
1975年 | 1篇 |
1973年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有791条查询结果,搜索用时 15 毫秒
51.
Temperature modulation has long been used in various aspects of thermal methods. Historically, the principle areas of application
have been the determination of kinetic parameters using variants of the temperature jump method and the measurement of heat
capacity by AC calorimetry. More recently the introduction of temperature modulation in a variety of techniques has been used
in combination with deconvolution algorithms to separate sample responses that are dependent on rate of change of temperature
from those principally dependent on temperature. Finally, temperature modulation is important in the new field of micro-thermal
analysis.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
52.
This paper presents a modified descent method for solving co-coercive variational inequalities. Incorporating with the techniques of identifying descent directions and optimal step sizes along these directions, the new method improves the efficiencies of some existing projection methods. Some numerical results for an economic equilibrium problem are reported. 相似文献
53.
Tin oxalate as a precursor of tin dioxide and electrode materials for lithium-ion batteries 总被引:2,自引:0,他引:2
R. Alcántara Fernández F. Madrigal P. Lavela C. Pérez-Vicente J. Tirado 《Journal of Solid State Electrochemistry》2001,6(1):55-62
Tin(II) oxalate was studied as a novel precursor for active electrode materials in lithium-ion batteries. The discharge of
lithium cells using tin oxalate electrodes takes place by three irreversible steps: tin reduction, forming a lithium oxalate
matrix; solvent decomposition to form a passivating layer; and oxalate reduction in a two-electron process. These are followed
by reversible alloying of tin with lithium, leading to a maximum discharge of 11 F/mol. Cycling of the cells showed reversible
capacities higher than 600 mAh/g during the first five cycles and ca. 200 mAh/g after 50 cycles. Tin oxalate was converted
to tin dioxide by thermal decomposition at 450 °C and also by a chemical method by dissolving tin oxalate powder in 33% v/v
hydrogen peroxide at room temperature. The ultrafine nature of the tin dioxide powders obtained by this procedure allow their
use as electrodes in lithium cells. The best capacity retention during the first five cycles was achieved for a sample heat
treated to 250 °C to eliminate surface water.
Electronic Publication 相似文献
54.
55.
J. Ledieu R. McGrath Q. Chen T.A. Lograsso K.J. Caspersen B. Unal P.A. Thiel 《Surface science》2005,583(1):4-15
We compare step morphologies on surfaces of Al-rich metallic alloys, both quasicrystalline and crystalline. We present evidence that the large-scale step structure observed on Al-rich quasicrystals after quenching to room temperature reflects equilibrium structure at an elevated temperature. These steps are relatively rough, i.e., have high diffusivity, compared to those on crystalline surfaces. For the fivefold quasicrystal surface, step diffusivity increases as step height decreases, but this trend is not obeyed in a broader comparison between quasicrystals and crystals. On a shorter scale, the steps on Al-rich alloys tend to exhibit local facets (short linear segments), with different facet lengths, a feature which could develop during quenching to room temperature. Facets are shortest and most difficult to identify for the fivefold quasicrystal surface. 相似文献
56.
There have been a few recent numerical implementations of the stress‐jump condition at the interface of conjugate flows, which couple the governing equations for flows in the porous and homogenous fluid domains. These previous demonstration cases were for two‐dimensional, planar flows with simple geometries, for example, flow over a porous layer or flow through a porous plug. The present study implements the interfacial stress‐jump condition for a non‐planar flow with three velocity components, which is more realistic in terms of practical flow applications. The steady, laminar, Newtonian flow in a stirred micro‐bioreactor with a porous scaffold inside was investigated. It is shown how to implement the interfacial jump condition on the radial, axial, and swirling velocity components. To avoid a full three‐dimensional simulation, the flow is assumed to be independent of the azimuthal direction, which makes it an axisymmetric flow with a swirling velocity. The present interface treatment is suitable for non‐flat surfaces, which is achieved by applying the finite volume method based on body‐fitted and multi‐block grids. The numerical simulations show that a vortex breakdown bubble, attached to the free surface, occurs above a certain Reynolds number. The presence of the porous scaffold delays the onset of vortex breakdown and confines it to a region above the scaffold. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
57.
This paper illustrates an application of impulse control systems analysis to the management of renewable resources. We obtain an explicit definition for the impulse optimal strategy in the case of a nonlinear natural system which models certain types of forests. The result is in agreement with an econo-ecological conservative action on the forest. The examples developed in this paper associate new theories on impulse or jump control with natural forest management. In addition, we compare our results with the classical ones. We also show that a nonoptimal managing action on the forest is frequently the cause for significant medium-term losses.This work was supported by CONICET, Consejo Nacional de Investigaciones Científicas y Técnicas, and by the Universidad Nacional del Litoral, Argentina. 相似文献
58.
Dynamics of a stochastic rumor propagation model incorporating media coverage and driven by Lévy noise
下载免费PDF全文
![点击此处可从《中国物理 B》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Liang-An Huo 《中国物理 B》2021,30(8):80201-080201
With the development of information technology, rumors propagate faster and more widely than in the past. In this paper, a stochastic rumor propagation model incorporating media coverage and driven by Lévy noise is proposed. The global positivity of the solution process is proved, and further the basic reproductive number R0 is obtained. When R0 < 1, the dynamical process of system with Lévy jump tends to the rumor-free equilibrium point of the deterministic system, and the rumor tends to extinction; when R0 > 1, the rumor will keep spreading and the system will oscillate randomly near the rumor equilibrium point of the deterministic system. The results show that the oscillation amplitude is related to the disturbance of the system. In addition, increasing media coverage can effectively reduce the final spread of rumors. Finally, the above results are verified by numerical simulation. 相似文献
59.
Results of classical molecular dynamics simulations are presented for the re-orientational dynamics of water hydrogen bonded to perchlorate anion. Different mechanisms of bond formation are presented. Due to its regular tetrahedron geometry the perchlorate anion can make classical as well as bifurcated and trifurcated hydrogen bonds. The angular variation of water in the first solvation shell of perchlorate suggests the transitional character of multi-centred hydrogen bonds. As a result water molecules can slide around the anion. 相似文献
60.
高温超导磁通跳跃过程中的磁致伸缩效应 总被引:1,自引:0,他引:1
文中基于超导磁通动力学理论,考虑电磁力与热激活对磁通运动的影响,基本模型包括由等效电阻率随超导体温度和磁场变化的磁通扩散方程,以及比热随超导体温度变化的热传导方程组成.在此基础上,用数值方法求解了这组非线性磁热耦合方程,主要研究了有磁通跳跃状发生状态时环境温度和外磁场速度对于高温超导磁致伸缩的影响.结果表明:磁通进入超... 相似文献