剪切场下两亲性棒状粒子对聚异丁烯/聚二甲基硅氧烷共混物相形态的影响

合成了具有两亲表面性质的棒状SiO₂粒子,借助共聚焦激光扫描显微镜研究了两亲性棒状SiO₂粒子在共混物中的选择性分布,并通过在线剪切-显微技术和流变技术研究了其对聚异丁烯/聚二甲基硅氧烷（PIB/PDMS）不相容共混物形态结构的影响.研究表明,两亲性棒状SiO₂粒子倾向于分布在两相界面处及PIB相中.分散相的剪切诱导凝聚行为强烈依赖于粒子的含量和共混物的组成比.少量两亲性SiO₂粒子会促进分散相的凝聚,而加入足够量的粒子则能抑制分散相凝聚.     

A nonlinear planar beam formulation with stretch and shear deformations under end forces and moments

A new nonlinear planar beam formulation with stretch and shear deformations is developed in this work to study equilibria of a beam under arbitrary end forces and moments. The slope angle and stretch strain of the centroid line, and shear strain of cross-sections, are chosen as dependent variables in this formulation, and end forces and moments can be either prescribed or resultant forces and moments due to constraints. Static equations of equilibria are derived from the principle of virtual work, which consist of one second-order ordinary differential equation and two algebraic equations. These equations are discretized using the finite difference method, and equilibria of the beam can be accurately calculated. For practical, geometrically nonlinear beam problems, stretch and shear strains are usually small, and a good approximate solution of the equations can be derived from the solution of the corresponding Euler–Bernoulli beam problem. The bending deformation of the beam is the only important one in a slender beam, and stretch and shear strains can be derived from it, which give a theoretical validation of the accuracy and applicability of the nonlinear Euler–Bernoulli beam formulation. Relations between end forces and moments and relative displacements of two ends of the beam can be easily calculated. This formulation is powerful in the study of buckling of beams with various boundary conditions under compression, and can be used to calculate post-buckling equilibria of beams. Higher-order buckling modes of a long slender beam that have complex configurations are also studied using this formulation.     

Granular vortices: Identification,characterization and conditions for the localization of deformation

We relate the micromechanics of vortex evolution to that of force chain buckling and, on this basis, formulate the conditions for strain localization in a continuum model of dense granular media. Using the traditional bifurcation analysis of shear bands, we show that kinematic vortex fields are in fact solutions to the boundary value problem satisfying null boundary conditions. To establish an empirical basis for our study, we first develop a method to identify the location of the core and boundary of each vortex from a given displacement field in two dimensions. We then employ this method to characterize the residual deformation field (i.e., the deviation of particle motions from the continuum deformation) in a physical experiment and a discrete element simulation of dense granular samples submitted to biaxial compression. Vortices in the failure regime are essentially confined to the shear band. Primary vortices, the clear majority, rotate in the same direction as the shear band; secondary vortices, the so-called wakes, rotate in the opposite direction. Primary vortices align in spatial succession along the central axis of the band; wakes form next to the band boundaries, in between and beside two adjacent primary vortices. Force chain buckling, the governing mechanism for shear bands, is responsible for vortex formation in the failure regime. Vortex dynamics are consistent with stick-slip dynamics. From quiescent conditions of jamming or stick, vortical motions arise from force chain buckling and associated relative particle rotations and sliding; these in turn precipitate intermittent periods of unjamming or slip, evident in the attendant drops in stress ratio and bursts in both kinetic energy and local nonaffine deformation. A kinematic vortex field inside shear bands is proposed that is consistent with the equations of continuum mechanics and the underlying instability of force chain buckling: such a field is periodic with a repeating unit cell comprising a primary vortex at the center of the band, with two trailing wakes close next to the band boundaries.     

Can secondary nucleation exist in ice banding of freezing colloidal suspensions?

The formation mechanism of ice banding in the system of freezing colloidal suspensions, which is of significance in frost heaving, ice-templating porous materials and biological materials, is still a mystery. Recently, the theory of secondary nucleation and growth of ice has been proposed to explain the emergence of a new ice lens. However, this theory has not been quantitatively examined. Here, we quantitatively measure the initial interfacial undercooling of a new ice lens and the nucleation undercoolings of suspensions. We find that the interfacial undercooling cannot satisfy the nucleation undercooling of ice and hence disprove the secondary nucleation mechanism for ice banding.     

Dissolution and reconstitution of casein micelle containing dairy powders by high shear using ultrasonic and physical methods

The effect of shear on the solubilization of a range of dairy powders was investigated. The rate of solubilization of low solubility milk protein concentrate and micellar casein powders was examined during ultrasonication, high pressure homogenization and high-shear rotor–stator mixing and compared to low-shear overhead stirring. The high shear techniques were able to greatly accelerate the solubilization of these powders by physically breaking apart the powder agglomerates and accelerating the release of individual casein micelles into solution. This was achieved without affecting the structure of the solubilized proteins. The effect of high shear on the re-establishment of the mineral balance between the casein micelles and the serum was examined by monitoring the pH of the reconstituted skim milk powder after prior exposure to ultrasonication. Only minor differences in the re-equilibration of the pH were observed after sonication for up to 3 min, suggesting that the localized high shear forces exerted by sonication did not significantly affect the mass transfer of minerals from within the casein micelles.     

High order shear horizontal modes for minimum remnant thickness

Thickness mapping in aging structures suffering from corrosion is challenging especially when the structure is only partially accessible. In plates the high order shear horizontal guided wave modes all have a cutoff frequency thickness product below which they cannot propagate. This property is potentially attractive to estimate the minimum remnant thickness between two transducers. When using a source and a sensor array it is possible to control the number of modes being excited and the size of the region interrogated by the technique. Finite element simulations were used to show that by exciting multiple guided wave modes simultaneously and identifying which modes are received by a sensor array it is possible to estimate the minimum remaining thickness along the propagation path. Initial experimental results showed excellent agreement with the finite element simulations when the plate is uniform and with a thickness reduction between the source and the sensor arrays the minimum remnant thickness was underestimated by approximately 20%.     

Molecular dynamics study of the torsional vibration characteristics of boron-nitride nanotubes

In recent years, synthesizing inorganic nanostructures such as boron nitride nanotubes (BNNTs) has led to extensive studies on their exceptional properties. In this study, the torsional vibration behavior of boron-nitride nanotubes (BNNTs) is explored on the basis of molecular dynamics (MD) simulation. The results show that the torsional frequency is sensitive to geometrical parameters such as length and boundary conditions. The axial vibration is found to be induced by torsional vibration of nanotubes which can cause instability in the nanostructure. It is also observed that the torsional frequency of BNNTs is higher than that of their carbon counterpart. Moreover, the shear modulus is predicted by incorporating MD simulation numerical results into torsional vibration frequency obtained through continuum-based model of tubes. Finally, it is seen that the torsional frequency of double-walled boron-nitride nanotubes (DWBNNTs) is between the frequencies of their constituent inner and outer tubes.     

On the influence of material non-linearities in geometric modeling of kink band instabilities in unidirectional fiber composites

The axial compressive failure of aligned fiber composites triggered by kink band instabilities is the topic of investigation herein. Particular emphasis is put on the accurate prediction of the post-failure regime, where fiber composites are known to exhibit substantial post-failure strength. In this regard, a previous analytical model, based on geometric relationships and energy principles, is enhanced by consistently taking into account material non-linearities. Therefore, a non-linear constitutive law is introduced herein based on a newly developed exponential formulation. This non-linear constitutive law is subsequently implemented into the stress–strain response in interlaminar shearing as well as the compression response. The model enhancements are validated against published experimental data yielding excellent comparisons. Furthermore, the relevance of modeling non-linear material behavior in interlaminar dilation and bending is assessed using a bilinear constitutive law. However, implementing non-linear material behavior does not yield any improvements and can therefore be neglected.     

Correlation of powder flow properties to interparticle interactions at ambient and high temperatures

A combination of a continuum approach and a particle–particle approach to describe the multi-scale nature of the mechanical properties of bulk solids may be beneficial to scientific and engineering applications. In this paper, a procedure is proposed to estimate the interparticle forces beginning with the bulk flow properties as measured with standardized techniques. In particular, the relationship between interparticle forces and bulk solid tensile strength is adopted based on the microscale approaches of Rumpf(1970) and Molerus(1975). The flow properties of fluid cracking catalyst(FCC), corundum and glass bead powders were all characterized with a modified Schulze ring shear cell capable of operating at temperatures up to 500℃. The powder test conditions were selected such that the van der Waals forces were the most significant particle–particle interactions. The model equations describe two cases, in which either elastic or plastic deformation of the contact points is assumed. The results indicate that the model provides the correct order of magnitude for the values of the tensile strength when proper values for the mean curvature radius at the contact points are taken into account. A sensitivity analysis for the main parameters in the model was performed. This analysis indicated that the assumption of plastic deformation at contact surfaces coupled with a decrease in porosity justified an increase of the tensile strength with consolidation stress. Furthermore, the effect of temperature on the measured flow behavior can be explained as a change in the strength of the material.     

Prediction of vascular injury by cavitation microbubbles in a focused ultrasound field

Many studies have shown that microbubble cavitation is one mechanism for vascular injury under ultrasonic excitation. Previous work has attributed vascular damage to vessel expansions and invaginations due to the expansion and contraction of microbubbles. However, the mechanisms of vascular damage are not fully understood. In this paper, we investigate, theoretically and experimentally, the vessel injury due to stress induced by ultrasound-induced cavitation (UIC). A bubble-fluid-vessel coupling model is constructed to investigate the interactions of the coupling system. The dynamics process of vessel damage due to UIC is theoretically simulated with a finite element method, and a focused ultrasound (FU) setup is carried out and used to assess the vessel damage. The results show that shear stress contributes to vessel injury by cell detachment while normal stress mainly causes distention injury. Similar changes in cell detachment in a vessel over time can be observed with the experimental setup. The severity of vascular injury is correlated to acoustic parameters, bubble-wall distance, and microbubble sizes, and the duration of insonation..