Luminescence sensitivity changes of polymineral fine grains during IRSL and [post-IR] OSL measurements

Sensitivity changes during measurement sequences of infra-red-stimulated luminescence (IRSL) and post-IR optically stimulated luminescence (OSL) are presented for a sample of loess from northwestern China. Together with a dose recovery experiment, the results are used to investigate the ratio of 2.4 found for the D_e values (for IRSL and [post-IR] OSL) obtained when using a single-aliquot regenerative-dose (SAR) protocol in which both D_e values are obtained in a single sequence of measurements. Responses to test doses for both the IRSL and [post-IR] OSL show progressive luminescence sensitivity changes with repeated measurement cycles, with a slight dose dependence for the IRSL. In addition, five modified SAR procedures were used, varying preheats, filter combinations and method of measuring the luminescence signal. The D_e values for all IRSL measurements were at least 50% greater than those for the [post-IR] OSL signal. A modified SAR sequence was also applied in which 0.1 s stimulations (using both IR and blue light sources) were made between all sample treatments. A lack of consistency in the measured luminescence sensitivity of the natural IRSL signal suggests that the [post-IR] OSL signal provides the more reliable value of D_e.     

模拟合成孔径雷达数据片波差的测量和胶片、波差的容限

本文介绍一种用马赫-陈德干涉系统测量模拟合成孔径雷达数据片波差的方法.该法能把两种原因产生的波差区分开来,即把通过胶片变形的波面与平面参考波面比较,求出胶片厚度不平产生的波差;把合成孔径雷达数据片的一级衍射波面与两个半径不等的参考球面波比较,分别求出由模拟装置产生的方位维和斜距维波差.本文给出一些实验结果和分析.这种方法还可以用于测量真实合成孔径雷达数据片的波差.由胶片厚度变化产生的波差可以用液体门补偿.但是,在实际中使用液体门是很繁复的,有时也没有必要.因此,我们认瑞利准则出发导出合成孔径雷达数据片胶片厚度变化产生的波差的容限,以此作为判断是否要用液体门的依据.     

Synthesis,crystal structures,in vitro anticancer,and in vivo acute oral toxicity studies of bis-imidazolium/benzimidazolium salts and respective dinuclear Ag(I)-N-heterocyclic carbene complexes

The synthesis, spectral (FT-IR and NMR), and structural studies of 1,1′-methylene linked 3,3′-2-cyanobenzyl bis-imidazolium salt (L₁) and respective dinuclear Ag(I)-NHC complex (C₁) are reported. The structures of both compounds were established through single-crystal X-ray diffraction. C₁ has a short Ag–Ag separation of 3.16?Å. Both L₁ and C₁ were tested for potential against leukemia (k562) cell line. For comparison, para-xylyl linked bis-benzimidazolium salts (L₂–L₄) and their dinuclear Ag(I)-NHC complexes (C₂–C₄) were synthesized and tested against the same cell line (K562). The IC₅₀ values proved that L₂–L₄ and C₂–C₄ are many fold more active than L₁ and C₁. The mechanism of action and structure activity relationship are discussed. In vivo oral acute toxicity study (sighting study) was carried out which depicts that 2000 mg/kg dose of selected compounds is an appropriate and safe dose for conducting main study on animals.     

A nanosized Ag-silica hybrid complex prepared by γ-irradiation activates the defense response in Arabidopsis

Silver nanoparticles have antimicrobial activity against many pathogenic microbes. Here, the preparation of a nanosized Ag-silica hybrid complex (NSS) prepared by γ-irradiation is described. The effects of both NSS and reduced Ag nanoparticles (Ag⁰) on the growth of the model plant Arabidopsis thaliana were tested. The application of 1-10 ppm NSS complex improved Arabidopsis growth in soil, whereas 100 ppm NSS resulted in weakly curled leaves. In addition, supplementation of Murashige and Skoog (MS) growth medium with 1 ppm NSS promoted the root growth of Arabidopsis seedlings, but root growth was inhibited by supplementation with 10 ppm NSS. To investigate whether the NSS complex could induce plant defense responses, the expression of pathogenesis-related (PR) genes that are implicated in systemic acquired resistance (SAR) in Arabidopsis plants was examined. PR1, PR2 and PR5 were significantly up-regulated by each application of 10 ppm NSS complex or Ag⁰ to the rosette leaves. Furthermore, pretreatment with the NSS complex induced more pathogen resistance to the virulent pathogen Pseudomonas syringae pv. tomato DC3000 (Pst) compared to water treatment in Arabidopsis plants.     

C波段机载合成孔径雷达海面风场反演新方法

针对基于散射计地球物理模型函数的机载合成孔径雷达(SAR)海面风场反演中存在的风向获取依赖于图像风条纹或数值预报、 散射计数据和浮标等背景场资料, 风向与SAR图像时空分辨率不匹配, 进而影响机载SAR海面风场反演精度等问题, 本文根据机载SAR对海探测特点, 研究一种适用于C波段机载SAR的海面风场反演新方法. 利用SAR图像距离向不同入射角的后向散射系数, 依据地球物理模型构造最小代价函数, 通过代价函数的求解直接从机载SAR数据同时反演出海面风速和风向. 利用论文提出的海面风场反演方法分别对仿真SAR数据和实测C波段机载SAR数据进行风向、 风速的反演误差分析及试验验证.研究结果表明, 该方法适用于机载SAR海面风场反演, 可不依赖背景风向直接反演出精度较高的风速和风向; 雷达后向散射系数误差是决定海面风速、风向反演精度的关键因素, 辐射定标精度越高则反演误差越小; 海面风速反演误差随着风速的提高而增大, 当海面风速大于18 m/s时, 风速反演误差显著增加, 而海面风向的反演误差与风速无明显关系. 关键词： 机载合成孔径雷达 海面风场 多入射角     

Calculated ionization energies for a series of sesquiterpenes: comparisons with experimental vertical ionization energies and comments on related structure–activity relationships (SARs)

The energies of the highest-occupied molecular orbitals (HOMOs) are known to be excellent predictors of the reactivities of biogenic hydrocarbons, such as terpenes, with reactive atmospheric oxidants including O₃, OH, and NO₃. Structure–Activity Relationships (SARs) have also been effectively employed in such studies and related to HOMO energies and lowest ionization energies (ionization potentials). This study employs density function theory (DFT), at the B3LYP/6-31G** level, to predict vertical ionization energies (IP_v) for a structurally diverse group of sesquiterpenes, each of which has been reported in air samples collected in the lower troposphere. The availability of published UV photoelectron spectra for nine sesquiterpenes permits comparison of experimental and theoretical vertical ionization energy data. The experimental and theoretical data show a good correlation (average discrepancy ± 0.07 eV). This enables predictions of reactivities for sesquiterpenes whose tropospheric lifetimes may last only a few hours before their transformations into secondary organic aerosols (SOA) close to their emission sources.     

A Class of Global Optimization Problems as Models of the Phase Unwrapping Problem

Let I={(i,j) i=1, 2,..., N ₁, j=1, 2,..., N ₂} and let U=U_i,j, (i,j)I be a discrete real function defined on I. Let []₂ be modulus 2, we define W:I , ) as follows W=[U]₂. The function U will be called phase function and the function W will be called wrapped phase function. The phase unwrapping problem consists in recovering U from some knowledge of W. This problem is not well defined, that is infinitely many functions U correspond to the same function W, and must be `regularized' to be satisfactorily solvable. We propose several formulations of the phase unwrapping problem as an integer nonlinear minimum cost flow problem on a network. Numerical algorithms to solve the minimum cost flow problems obtained are proposed. The phase unwrapping problem is the key problem in interferometry, we restrict our attention to the SAR (Synthetic Aperture Radar) interferometry problem. We compare the different formulations of the phase unwrapping problem proposed starting from the analysis of the numerical experience obtained with the numerical algorithms proposed on synthetic and real SAR interferometry data. The real data are taken from the ERS missions of the European Space Agency (ESA).     

Quantitative Studies on Structure－Activity Relationships （QSAR） of Cytokinin－Active Phenyl Urea Derivatives（PUD）

ＱｕａｎｔｉｔａｔｉｖｅＳｔｕｄｉｅｓｏｎＳｔｒｕｃｔｕｒｅ－ＡｃｔｉｖｉｔｙＲｅｌａｔｉｏｎｓｈｉｐｓ（ＱＳＡＲ）ｏｆＣｙｔｏｋｉｎｉｎ－ＡｃｔｉｖｅＰｈｅｎｙｌＵｒｅａＤｅｒｉｖａｔｉｖｅｓ（ＰＵｎ）ＱＩＡＯＬｉ－ｘｉｎ；ＬＩＺｈｅｎｇ－ｍｉｎｇ...     

Synthesis of Cytotoxic Sinapyl Alcohol Derivatives fromLigularia nelumbifolia

Total synthesis of two cytotoxic natural products, nelumol A(1) and nelumal A(2), were carried out by two different paths. 4-O-Benzyl substitute analogues 26 and 27, as well as the 4-O-(2-methyl-butenyl) derivatives 29 and 30 were also synthesized for a SAR invesigation. 1 and 2 were also measured on different tumor cell line.     

紫杉醇构效关系研究新进展

综述了近年来在紫杉醇类似物构效研究中的最新进展,按照紫杉醇的A,B, C,D环修饰的顺序总结了新得到的40余种紫杉醇类似物结构与其生物活性之间的关系。