外载荷作用下水泥砂浆复合材料中的弹性波波速分析

为研究水泥基复合材料中弹性波频散特性,应用主频分别为50kHz、300kHz和1MHz三种声波探头,对钢纤维体积含量分别为0.5%、1.0%和3.0%的三种钢纤维增强水泥砂浆试件进行了单轴压缩下的弹性波测试实验。结果表明:在加载初始阶段,P波波速随着载荷增大而明显增大,但这种增大趋势逐渐减弱,并达到一个较稳定的值。随着钢纤维体积含量增加,波速有增大趋势。S波具有类似趋势,但其增幅比P波小得多。三种材料均表现出一定的频散效应。为消除材料在初始加载过程的非线性特性影响,采用了相对波速的方法,并讨论了相对波速的频散效应。结合多组份未胶结模型和Hashin-Shtrikman上限模型,应用一种无量纲理论模型,对比分析了弹性波波速频散规律。     

Preparation of a polyacrylonitrile/multi-walled carbon nanotubes composite by surface-initiated atom transfer radical polymerization on a stainless steel wire for solid-phase microextraction

We report on the fabrication and performances of a solid-phase microextraction (SPME) fiber based on a stainless steel wire coated with a covalently attached polyacrylonitrile (PAN)/multi-walled carbon nanotubes (MWCNTs) composite. This new coating is obtained by atom transfer radical polymerization (ATRP) of acrylonitrile mixed with MWCNTs. ATRP is initiated from 11-(2-bromo-2-methylpropionyloxy)-undecyl-phosphonic acid molecules grafted on the wire surface via the phosphonic acid group. The extraction performances of the fibers are assessed on different classes of compounds (polar, non-polar, aromatic, etc.) from water solutions by headspace extraction. The optimization of the parameters affecting the extraction efficiency of the target compounds was studied as well as the reproducibility and the repeatability of the fiber. The fibers sustain more than 200 extractions during which they remain chemically stable and maintain good performances (detection limits lower than 2 μg/l, repeatability, etc.). Considering their robustness together with their easy and inexpensive fabrication, these fibers could constitute promising alternatives to existing products.     

合金元素及模拟热处理对2205双相不锈钢之孔蚀性质影响

本文研究了Ｎｉ元素及不同模拟焊后热影响区（ＨＡＺ）组织对２２０５双相不锈钢孔蚀性质之影响。结果发现：在研究成分范围内，不同Ｎｉ含量对于底材电化学极化曲线之影响不大，其Ｅｎｐ和Ｅｎｐ均在１１００￣１２００ｍＶ之间。     

1H and 13C NMR analysis of 2‐acetamido‐3‐mercapto‐3‐methyl‐N‐aryl‐butanamides and 2‐acetamido‐3‐methyl‐3‐nitrososulfanyl‐N‐aryl‐butanamide derivatives

The complete assignment of the ¹H and ¹³C NMR spectra of various 2‐acetamido‐3‐mercapto‐3‐methyl‐N‐aryl‐butanamides and 2‐acetamide‐3‐methyl‐3‐nitrososulfanyl‐N‐aryl‐butanamides with p‐methoxy, o‐chloro and m‐chloro substituents is reported. Copyright © 2013 John Wiley & Sons, Ltd.     

Experiments on 40 Gb/s Transmission with Wavelength Conversion: Results from the IST ATLAS Project

In this article we report the main experimental results obtained in the framework of the IST ATLAS project regarding the transmission at 40 Gb/s over long terrestrial links, including the frequency conversion of a signal. We report the single-channel 40 Gb/s transmission over a link 500 km long with an amplifier spacing of 100 km, both with G.652 fibers and G.653 fibers by periodically compensating the chromatic dispersion with dispersion-compensating fibers. We report the single-channel transmission at 40 Gb/s, also, after the wavelength conversion of a channel with both PPLN and semiconductor optical amplifier devices. In particular, 500 km distances are obtained with PPLN wavelength conversion and 300 km distances with semiconductor optical amplifiers. Some results have been reported for electronic devices operating at 40 Gb/s.     

Indirect enantioresolution of (R,S)‐mexiletine by reversed‐phase high‐performance liquid chromatography via diastereomerization with [(S,S)‐O,O'‐di‐p‐toluoyl tartaric acid anhydride], (S)‐naproxen and nine chiral reagents synthesized as variants of Marfey's reagent

Eleven chiral derivatizing reagents (CDRs) were used for preparation of diastereomers of (R,S)‐mexiletine containing a primary amino group in close proximity to the stereogenic center. One anhydride, namely [(S,S)‐O,O'‐di‐p‐toluoyl tartaric acid anhydride] was synthesized and (S)‐naproxen was used as such as the chiral derivatizing reagent. The other nine CDRs were synthesized by substituting one of the fluorine atoms in 1,5‐difluoro‐2,4‐dinitrobenzene with six amino acid amides and three amino acids. The diastereomers were separated by reversed‐phase high‐performance liquid chromatography. The method was validated for linearity, accuracy, limit of detection and limit of quantification. The limit of detection was found in the range of 10–30 pmol. Copyright © 2010 John Wiley & Sons, Ltd.     

A highly sensitive LC‐MS/MS method for the determination of S‐citalopram in rat plasma: application to a pharmacokinetic study in rats

A highly sensitive, rapid assay method has been developed and validated for the estimation of S‐citalopram (S‐CPM) in rat plasma with liquid chromatography coupled to tandem mass spectrometry with electrospray ionization in the positive‐ion mode. The assay procedure involves a simple liquid–liquid extraction of S‐CPM and phenacetin (internal standard, IS) from rat plasma with t‐butyl methyl ether. Chromatographic separation was operated with 0.2% formic acid:acetonitrile (20:80, v/v) at a flow rate of 0.50 mL/min on a Symmetry Shield RP₁₈ column with a total run time of 3.0 min. The MS/MS ion transitions monitored were 325.26 → 109.10 for S‐CPM and 180.10 → 110.10 for IS. Method validation and pre‐clinical sample analysis were performed as per FDA guidelines and the results met the acceptance criteria. The lower limit of quantitation achieved was 0.5 ng/mL and the linearity was observed from 0.5 to 5000 ng/mL. The intra‐ and inter‐day precisions were in the range of 1.14–5.56 and 0.25–12.3%, respectively. This novel method has been applied to a pharmacokinetic study and to estimate brain‐to‐plasma ratio of S‐CPM in rats. Copyright © 2010 John Wiley & Sons, Ltd.     

Cracking in D6ac steel

This paper examines the results of an extensive test program undertaken to study crack growth in D6ac steel and shows that in each case the increment in the crack length per cycle (da/dN) conforms to the Generalised Frost-Dugdale crack growth law. This is found to be true for both constant K_max, constant R ratio load increasing, and compression-compression pre-cracking tests in the L-T, T-L and the S-T directions.