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41.
Summary Enantiomeric separation of (–)-menthyl chloroformate derivatives of some chiral cardioactive drugs, on porous graphitic carbon (PGC), Hypercarb-S, is described. Capacity and separation factors of derivatives of the calcium channel blockers; amlodipine and UK52.829, the -blockers; atenolol, sotalol and propranolol, and mexiletine were studied in different chromatographic systems based on dichloromethane. A high content of a carboxylic acid in the mobile phase was found to decrease the retention and positively affect the stereoselectivity of the derivatives. A mobile phase with dichloromethane, acetonitrile and formic acid gave baseline separation of the enantiomers of amlodipine in less than 8 minutes. Results show that acetic acid and formic acid, may be regarded as strong organic solvents in PGC chromatography with nearly the same elution power as dichloromethane. 相似文献
42.
The electric conduction in the fibrous medium constructed by a homogeneous array of parallel, identical, charged, circular cylinders having an arbitrary zeta potential filled with the solution of a symmetrically charged electrolyte is analytically examined. The thickness of the electric double layers surrounding the dielectric cylinders is assumed to be small relative to the radius of each cylinder and to the gap width between two neighboring cylinders, but the polarization of the mobile ions in the diffuse layers is allowed. The effect of interactions among individual cylinders is taken into explicit account by employing a unit cell model. The appropriate equations of conservation of electrochemical potential energies of ionic species are solved for each cell, in which a cylinder is envisaged to be surrounded by a coaxial cylindrical shell of the fluid solution. Analytical expressions for the effective electric conductivity are obtained in closed forms as functions of the porosity of the fiber matrix and other characteristics of the porous system. Comparisons of the results of the cell model with different conditions at the outer boundary of the cell are made. Under an otherwise identical condition, the electric conductivity in a porous medium composed of an array of parallel cylinders in the transverse direction is smaller than that of a suspension of spheres. The effect of interactions among the cylinders or spheres on the effective conductivity can be quite significant under appropriate conditions. 相似文献
43.
微孔型固体偏氟乙烯-六氟丙烯共聚物电解质 总被引:4,自引:0,他引:4
将固体聚合物电解质 (Solidpolymerelectrolyte)用于锂离子电池的研究已经有 3 0年的历史[1] ,从物理角度来看 ,研究过干态型 (DrySPE)、凝胶型 (GelledSPE)和微孔型固体聚合物电解质 (PorousSPE)三大类型[2 ] ;从化学角度来看 ,研究过含氧、含氮、和含氟的等聚合物[1~ 6 ] .微孔型固体含氟聚合物电解质是近 1 0年来才开始研究并受到产业界很大关注的一种SPE .固体聚合物电解质的应用可以解决液体电解质锂离子电池的漏液问题 ,并提高其安全性 ,还可以通过使用塑料包装来减小电池的重量… 相似文献
44.
Thermal oxidative treatment enhances the activity of a schungite rock in the sorption of petrochemicals from aqueous solutions.
The effect of the thermal oxidative activation on the content and distribution of carbon in the rock and the dependence of
the sorption activity on the texture of sorbents were studied.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2233–2238, October, 2005. 相似文献
45.
The starting electrophoretic motion of a porous, uniformly charged, spherical particle, which models a solvent-permeable and ion-penetrable polyelectrolyte coil or floc of nanoparticles, in an arbitrary electrolyte solution due to the sudden application of an electric field is studied for the first time. The unsteady Stokes/Brinkman equations with the electric force term governing the fluid velocity fields are solved by means of the Laplace transform. An analytical formula for the electrophoretic mobility of the porous sphere is obtained as a function of the dimensionless parameters , , , and , where a is the radius of the particle, κ is the Debye screening parameter, λ is the reciprocal of the square root of the fluid permeability in the particle, ρp and ρ are the mass densities of the particle and fluid, respectively, ν is the kinematic viscosity of the fluid, and t is the time. The electrophoretic mobility normalized by its steady-state value increases monotonically with increases in and , but decreases monotonically with an increase in , keeping the other parameters unchanged. In general, a porous particle with a high fluid permeability trails behind an identical porous particle with a lower permeability and a corresponding hard particle in the growth of the normalized electrophoretic mobility The normalized electrophoretic acceleration of the porous sphere decreases monotonically with an increase in the time and increases with an increase in from zero at . 相似文献
46.
Zhenya Zhang Taisheng Quan Pomin Li Yansheng Zhang Norio Sugiura Takaaki Maekawa 《Applied biochemistry and biotechnology》2004,115(1-3):1033-1039
We studied biogas fermentation from alcohol waste fluid to evaluate the anaerobic digestion process and the production of
vitamin B12 as a byproduct. Anaerobic digestion using acclimated methanogens was performed using the continuously stirred tank reactor
(CSTR) and fixed-bed reactor packed with rock wool as carrier material at 55°C. We also studied the effects of metal ions
added to the culture broth on methane and vitamin B12 formation. Vitamin B12 production was 2.92 mg/L in the broth of the fixed-bed reactor, twice that of the CSTR. The optimum concentrations of trace
metal ions added to the culture liquid for methane and vitamin B12 production were 1.0 and 8 mL/L for the CSTR and fixed-bed reactor, respectively. Furthermore, an effective method for extracting
and purifying vitamin B12 from digested fluid was developed. 相似文献
47.
H. J. Cortes C. D. Pfeiffer B. E. Richter T. S. Stevens 《Journal of separation science》1987,10(8):446-448
Porous ceramic bed supports for fused silica packed capillary columns utilized in liquid chromatography were prepared by polymerizing solutions containing potassium silicate in-situ within a column to create a mechanically stable, rugged, and easily constructed termination. The effect of the bed support length on efficiency, and comparisons to glass wool bed supports, were considered in terms of column efficiencies and hydrodynamic variables. Results obtained indicate better performance for the ceramic bed support. 相似文献
48.
J. Benaventea G. Jonsson 《Colloids and surfaces. A, Physicochemical and engineering aspects》1998,140(1-3):339-346
Electrical and electrokinetic phenomena (electrical resistance, streaming potential and membrane potential) in a porous polysulfone membrane was studied in the framework of the linear thermodynamics of irreversible processes and the phenomenological coefficients were determined for different concentrations of NaCl and MgCl2 solutions (10−3M<5×10−2M). From experimental values, other characteristic membrane parameters such as the concentration of fixed charge in the membrane (=−3×10−3M), the ionic transport numbers and permeabilities through the membrane (t(Na+)=0.392 and t(Mg+2)=0.363; P(Na+)=3.5×l0−8m/sec and P(Mg+2)=2.9×10−8m/sec) were also obtained. Membrane surface-electrolyte solution interface was characterized by zeta potential values. The effect of both salt concentration and pH on zeta potential results was also studied. 相似文献
49.
Heng-dao Quan Hui-e Yang Masanori Tamura Akira Sekiya 《Journal of fluorine chemistry》2004,125(7):1169-1172
A novel fluorination reagent and catalyst, SbF5/PAF (porous aluminum fluoride), was prepared by impregnating SbCl5 into PAF and then treating with anhydrous hydrogen fluoride. The prepared reagent had an excellent catalytic activity in halogen-exchange, and also improved the properties of SbF5, such as hydroscopicity, corrosion, and toxicity. SbF5/PAF was successfully used in organic synthesis as a fluorinating reagent, and a fixed bed catalyst for F/Cl exchange. 相似文献
50.