Crystal Adaptronics: Mechanically Reconfigurable Elastic and Superelastic Molecular Crystals

Mechanically reconfigurable molecular crystals—ordered materials that can adapt to variable operating and environmental conditions by deformation, whereby they attain motility or perform work—are quickly shaping a new research direction in materials science, crystal adaptronics. Properties such as elasticity, superelasticity, and ferroelasticity, which are normally related to inorganic materials, and phenomena such as shape‐memory and self‐healing effects, which are well‐established for soft materials, are increasingly being reported for molecular crystals, yet their mechanism, quantification, and relation to the crystal structure of organic crystals are not immediately apparent. This Minireview provides a condensed topical overview of elastic, superelastic, and ferroelastic molecular crystals, new classes of materials that bridge the gap between soft matter and inorganic materials. The occurrence and detection of these unconventional properties, and the underlying structural features of the related molecular materials are discussed and highlighted with selected prominent recent examples.     

Mechanical properties of SBR-networks: I. Determination of crosslink densities by stress-strain-measurements

The tube model is applied for the treatment of stress-strain measurements on SBR networks. It is shown that this theory allows the separation of crosslink and constraint contributions to the stress-strain behavior and, also, a reliable determination of crosslink densities. The consideration of dynamical contributions is discussed and a special numerical method is developed.     

RHEOLOGICAL CHARACTERIZATION OF PROCESSABILITY OF UNVULCANIZED POLYBUTADIENE

Rheological investigation on a series ot unvulcamzed polybutadiene elastomers of different processability has been carried out by means of a capillary extrusion rheometer. It is found that the processability of unvulcanized polybutadiene can be correlated with the occurrence of unsteady flow and the wall stress, dependence of the dimensionless number e characterizing the entrance elongational elasticity which has been found to be sensitive to the branching structure and the molecular weight distribution of the samples. Interpretations based on the structural data of unvulcanized polybutadiene were discussed.     

马歇尔-勒纳条件的实证研究

本文从人民币实际汇率变动是否会对我国贸易收支产生影响出发，基于马歇尔．勒纳条件，对计算贸易弹性常用的OLS回归模型进行了改进，建立了向量自回归误差修正模型来估算我国的国际贸易弹性。实证研究表明：我国进出口需求的价格弹性之和大于1。因此人民币贬值可改善贸易收支；反之升值将使贸易收支恶化。     

弹性平面扇形域问题及哈密顿体系*

通过变量代换及变分原理,将平面弹性扇形域的方程导向哈密顿体系,从而可用分离变量法、本征函数展开等方法求解扇形域的分析单元,这样便可以与有限元的程序系统相结合。显示了哈密顿体系、辛数学的应用潜力。     

Anisotropic parameter identification using inhomogeneous tensile test

In this contribution, an inverse identification strategy of constitutive laws for elastoplastic behaviour is presented. The proposed inverse algorithm is composed on an appropriate finite element calculation combined with an optimisation procedure. It is applied to identify material anisotropic coefficients using a set up of easy performed laboratory tests. The used experimental data are the plane tensile test and the off axes tensile tests. The identified behaviour models are mainly based on Hill's quadratic yield criterion. Two cases of this yield criterion have been considered: the transverse isotropic and the orthotropic one under an associated and non-associated flow rule assumptions for each case. The yield surface has been assumed to expand isotropically (isotropic strain hardening law) as a function of the plastic work.In order to better describe anisotropic plastic properties of the studied materials, a recently planar anisotropic yield function is used. It is a non-quadratic yield criterion which takes account of anisotropic yield stresses as well as anisotropic strain ratios. It is subsequently shown that the agreement between inverse identification results and experimental measurements were improved.We prove also that the presented strategy is a good alternative to the simplified homogeneous tests assumption, especially for the plane tensile test.     

哈密顿体系与弹性楔体问题

将哈密体系引入到级坐标下的弹性力学楔体问题,利用该体系辛空间的性质,将问题化为本征值和本征向量求解上,得到了完备的解空间,从而改变了弹性力学传统的拉格朗日体系以应力函数为特征的半逆法的讨论去解决该类问题的思路,给出了一条求解该类问题的直接法。     

Sufficient conditions for strong ellipticity for a class of anisotropic materials

We provide sufficient conditions for strong ellipticity for a general class of anisotropic hyperelastic materials. This general class includes as a subclass transversely isotropic materials. Our sufficient conditions require that the first partial derivatives of the reduced-stored energy function satisfy some simple inequalities and that the second partial derivatives satisfy a convexity condition. We also characterize a restricted type of strong ellipticity for a subclass of transversely isotropic materials undergoing pure homogeneous deformations. We apply our results to a model of soft tissue from the biomechanics literature.     

Low cost a posteriori error estimators for an augmented mixed FEM in linear elasticity

We consider an augmented mixed finite element method applied to the linear elasticity problem and derive a posteriori error estimators that are simpler and easier to implement than the ones available in the literature. In the case of homogeneous Dirichlet boundary conditions, the new a posteriori error estimator is reliable and locally efficient, whereas for non-homogeneous Dirichlet boundary conditions, we derive an a posteriori error estimator that is reliable and satisfies a quasi-efficiency bound. Numerical experiments illustrate the performance of the corresponding adaptive algorithms and support the theoretical results.