全文获取类型
收费全文 | 2026篇 |
免费 | 280篇 |
国内免费 | 171篇 |
专业分类
化学 | 574篇 |
晶体学 | 17篇 |
力学 | 291篇 |
综合类 | 28篇 |
数学 | 464篇 |
物理学 | 1103篇 |
出版年
2024年 | 3篇 |
2023年 | 7篇 |
2022年 | 29篇 |
2021年 | 40篇 |
2020年 | 59篇 |
2019年 | 52篇 |
2018年 | 32篇 |
2017年 | 65篇 |
2016年 | 77篇 |
2015年 | 57篇 |
2014年 | 104篇 |
2013年 | 164篇 |
2012年 | 124篇 |
2011年 | 148篇 |
2010年 | 115篇 |
2009年 | 140篇 |
2008年 | 164篇 |
2007年 | 110篇 |
2006年 | 125篇 |
2005年 | 107篇 |
2004年 | 77篇 |
2003年 | 66篇 |
2002年 | 74篇 |
2001年 | 78篇 |
2000年 | 50篇 |
1999年 | 49篇 |
1998年 | 49篇 |
1997年 | 46篇 |
1996年 | 58篇 |
1995年 | 26篇 |
1994年 | 22篇 |
1993年 | 22篇 |
1992年 | 25篇 |
1991年 | 16篇 |
1990年 | 12篇 |
1989年 | 17篇 |
1988年 | 14篇 |
1987年 | 11篇 |
1986年 | 6篇 |
1985年 | 7篇 |
1984年 | 10篇 |
1983年 | 3篇 |
1982年 | 6篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1978年 | 2篇 |
1976年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有2477条查询结果,搜索用时 31 毫秒
111.
112.
凸透镜焦距的测量方法和不确定度评价已经有很多研究,本文着重研究测量方法,提出了应用实物成虚像、虚物成实像方法来测量凸透镜的焦距,并与实物成实像方法进行比较和分析。本文的实验研究拓展了透镜焦距测量的方法,同时更加深入研究了透镜成像的规律,开拓了实验思路。 相似文献
113.
114.
Lei Sun Tian Du Cheng Wang Prof. Dongling Geng Dr. Lin Li Prof. Yang Han Prof. Yunfeng Deng 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(69):17437-17443
Low-bandgap organic semiconductors have attracted much attention for their multiple applications in optoelectronics. However, the realization of narrow bandgap is challenging particularly for small molecules. Herein, we have synthesized four quinoidal compounds, i. e., QSN3 , QSN4 , QSN5 and QSN6 , with electron rich S,N-heteroacene as the quinoidal core and indandione as the end-groups. The optical bandgap of the quinoidal compounds is systematically decreased with the extension of quinoidal skeleton, while maintaining stable closed-shell ground state. QSN6 absorbs an intense absorption in the first and second near-infrared region in the solid state, and has extremely low optical bandgap of 0.74 eV. Cyclic voltammetry analyses reveal that the lowest unoccupied molecular orbital (LUMO) energy levels of the four quinoidal compounds all lie below −4.1 eV, resulting in good electron-transporting characteristics in organic thin-film transistors. These results demonstrated that the combination of π-extended quinoidal core and end-groups in quinoidal compounds is an effective strategy for the synthesis of low-bandgap small molecules with good stability. 相似文献
115.
116.
The reactivity of ethyl‐, propyl‐ and octylgallate towards diphenylpicryl hydracil radicals has been measured in homogeneous solution (ethanol) and in Triton X‐100 micellar solutions. Similar reactivities were measured in homogeneous solutions, indicating that the length of the alkyl chain does not influence the reactivity of the phenolic groups. On the other hand, different reactivities were measured in micellar solutions, particularly at low (5 mM) surfactant concentrations. Data obtained at different surfactant concentrations allow estimation of partitioning of the gallates and their intramicellar bimolecular rate constant. The values obtained indicate that all the observed differences in reactivity are attributable to differences in substrate partitioning between the micellar and aqueous pseudophases. In fact, similar values of the intramicellar rate constants were obtained, suggesting that the average location of the reactive groups inside the micelles is independent of the solute alkyl chain length. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
117.
有限长密绕圆柱形螺线管自感系数的精确表达式 总被引:1,自引:0,他引:1
对于有限长密绕圆柱形螺线管,首先用贝塞尔函数展开法推导出自感系数的积分形式的表达式,然后用直接积分的方法得出两个级数形式的自感系数表达式,最后对这两个表达式作了简要的分析与比较. 相似文献
118.
《Physics and Chemistry of Liquids》2012,50(2):257-271
This work presents experimental liquid densities and ultrasonic velocities for a collection of substituted aromatic compounds (isobutylbenzene, 1,3,5-trimethylbenzene, butylbenzene, isopropylbenzene, p-xylene, m-xylene and o-xylene) at the range of temperature 278.15–323.15 K and atmospheric pressure of a collection of halogenated and aromatic hydrocarbons. Fitting equations were applied to data in order to correlate for later computer-based design. The estimation of the studied properties was made by the application of different theoretical procedures. An equation of state based on the generalised Van der Waals theory which combines the Staverman–Guggenheim combinatorial term of lattice statistics with an attractive lattice gas expression and the free length theory (FLT) showed a good response at the studied conditions. 相似文献
119.
Two soluble isomerized polyimides(PIs)synthesized from 2,2′-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride(6FDA)with either 2,2′-dimethylbenzidine(2,2′-DMB)or 3,3′-DMB were investigated by means... 相似文献
120.
Conservation equations for mass, momentum and energy have been solved numerically for a cylindrical funnel with louvers (lateral openings on the side wall of the cylindrical funnel through which air can come into it) to compute the suction rate of air into the funnel. The nozzle placed centrally at the bottom of the cylinder ejects high‐velocity hot gaseous products so that atmospheric air gets sucked into the funnel. The objective of the work is to compute the ratio of the rate of mass suction to that of the mass ejected by the nozzle for different operating conditions and geometrical size of the funnel. From the computation it has been found that there exists optimum funnel diameter and optimum funnel height for which the mass suction is the highest. The protruding length of the nozzle into the funnel has almost no effect on the mass suction rate after a certain funnel height. The louvers opening area has a very high impact on the mass suction rate. The entrance length for such a sucking funnel is strikingly much lower compared with a simple cylindrical pipe having uniform flow at the inlet at same Reynolds number. A new correlation has been developed to propose the entrance length for a sucking pipe, the rate of mass suction into it and the exhaust plume temperature over a wide range of operating parameters that are normally encountered in a general funnel operations of naval or merchant ship. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献