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121.
表面增强拉曼光谱(SERS)技术是一种基于贵金属纳米结构基底对被检测物进行高灵敏度检测的一种方法.具有特殊纳米结构的贵金属表面受到激光的照射时,金属表面的自由电子会受到极大的振荡,当入射光频率与振荡频率相近时,则会发生表面等离子体共振现象(SPR),使金属表面的局域电场强度极大增强,入射光强度和散射光强度都得到成倍的放大,从而使吸附在贵金属纳米结构表面的分子的拉曼散射信号得到有效的增强.使用NaBH4还原-酸刻蚀模板法,制备了八面体Au/Ag复合纳米笼,其形貌规整,尺寸均匀约为600 nm,无Cu2O模板的残留,Au元素均匀负载在Ag纳米笼上,质量分数约为16.8%;Au/Ag复合纳米笼的紫外可见吸收峰相对于Ag纳米笼发生了红移,更重要的是,Au和Ag元素协同赋予了复合纳米笼超高的SERS灵敏度和重复性,Au/Ag复合纳米笼实现了对罗丹明6G的痕量检测(5×10-14 mol/L),通过时域有限差分法(FDTD)模拟证实:这主要归因于等离子共振作用产生的高电磁场强度;此外,Au元素的加入使Au/Ag复合纳米笼具有优异的抗氧化性和化学稳定性,即使在1%的H2O2溶液中浸泡3 h,仍然能够保持优异的SERS性能.八面体Au/Ag复合纳米笼有望成为一种具有应用前景的高灵敏度、高稳定性的SERS基底.  相似文献   
122.
为实现PTS系列频率综合器的微机控制,设计了一种简单的控制电路。在微机的控制下,通过该电路与微机的并行通讯口,用C语言编写的控制程序可以很方便的控制频率综合器的输出频率。控制程序采用菜单操作,电路所需的+5V电源由微机提供,整个控制系统简单实用,值得推广。  相似文献   
123.
A study was carried out to determine if rotational correlation time of spin-labeled hen egg lysozyme (HEL) interacting with ultrafiltration membranes could be used to infer protein-membrane interaction. Polysulfone and cellulosic membranes, which have notably different adsorption properties, and membranes with varying pore sizes were used in this study. Based on this study, it was determined that the rotational correlation time does reflect variations in protein adsorption and pore plugging on membranes. The rotational correlation times for the highly adsorbent polysulfone (2.82 × 10−8 s) were significantly higher than those obtained from proteins on cellulosic membranes (0.62 × 10−8 s) and from those in solution (0.17 × 10−8 s). Rotational correlation time was also increased due to steric hindrance associated with pore plugging, although it was not as significant as the adsorption effect. This study indicates that the rotational time constant can be used to infer the type of protein-membrane interaction.  相似文献   
124.
The aggregation properties of ammonium perfluorooctanoate (NH4-PFO) in concentrated aqueous phases have been investigated by magnetic resonance techniques and have been compared with the aggregation properties in dilute solutions. Magnetic resonance methods indicated that NH4-PFO—water systems with surfactant concentrations below 45% (w/w) behaved as isotropic purely micellar solutions in the temperature range 285–340 K. For higher concentrations the system exhibited a rather complex structure, having both isotropic and anisotropic components. The nematic nature of the anisotropic fraction was demonstrated by 19F NMR studies. The 19F NMR and EPR of nitroxides (TempTMA+, 5- and 16-DXSA) inserted as paramagnetic probes into the concentrated NH4-PFO—water systems allowed us to establish that the lamellar phase could be mechanically oriented between quartz slides. The EPR investigation also gave details concerning the dynamics of both the oriented and non-oriented structures.  相似文献   
125.
Control of the optical properties of gel-derived oxide films containing fine metal particles is described. The duration of the aging of Si(OC2H5)4-derived sols and the amount of water for hydrolyzing Si(OC2H5)4 were found to greatly affect the size and the shape of Au particles formed in the silica matrix, and accordingly the optical absorption of the Au/SiO2 composite films. Employing dielectric media with high refractive indices like TiO2 was shown to shift the absorption peak of Au particles to longer wavelengths. Pd/TiO2 and Pt/TiO2 composite films showed absorption in the visible region.  相似文献   
126.
We obtained the association constants Ka of estrogen (E2) and environmental chemicals by the surface plasmon resonance (SPR) assay using the immobilized mono-6-O-α-maltosyl-β-CD (G2βCD) compared with the immobilized β-CD and the immobilized estrogen receptor (ER). The association behavior of G2βCD was shown as a ER model compound. The calibration curve was determined by the initial rate of association depending on the various concentrations, and the minimum detectable concentrations in the order of parts per billion were calculated. The SPR assay has advantages that the pre-treatment of the sample is not necessary and the immobilized ligand is stable and useful for the repeated measurement.  相似文献   
127.
活性酚醛树脂中羟甲基含量的测定   总被引:12,自引:0,他引:12  
王锋  赵临五 《分析化学》1995,23(9):1063-1065
本文提出一种酚醛树脂中羟甲基含量的化学分析法,分别以^13CNMR和化学分析法测定酚醛树脂的羟甲基含量。将两种测试结果与已知的投料量进行比较,证明所建立的化学分析法可行。  相似文献   
128.
    
The synthesis and characterisation of five newβ-aminodiketones is reported: (a) 3,3,5,8,10,10-hexamethyl-5,8-diazadodecane-2,11-dione; (b) 3,3,11,11-tetramethyl-5,8-diazatridecane-2,12-dione; (c) 3,3,12,12-tetramethyl-5,10-diazatetradecane-2,13-dione; (d) 3,3,10,10-tetramethyl-5,8-diphenyl-5,8-diazadodecane-2,11,dione and (e) 6,7-benzo-3,3,10,10-tetramethyl-5,8-diazadodecane-2,11-dione. These compounds are discussed as potential precursors in the synthesis of tetra-aza macrocyclic complexes.  相似文献   
129.
Introduction Humanserumalbumin(HSA)isawell known transportproteinforavarietyofmoleculesandions[1].Thebindingofadrugtoserumalbuminhasimportant pharmacokineticconsequencesbecauseitinfluences distribution,excretionandpharmacologicaleffectsof thedruginthebody…  相似文献   
130.
A novel sensitive method for the determination of nucleic acid (DNA) using the resonance light scattering (RLS) spectra of pentamethoxyl red has been developed. It is based on the effects on the resonance light scattering of Pentamethoxyl Red. The effective factors and the optimum conditions were studied, and the enhanced intensity of RLS is in proportion to the concentration of nucleic acids in the range of 0–2.54 µg mL−1 for ct-DNA, 0–4.54 µg mL−1 for hs-DNA. The limits of detection are 1.1 and 2.1 ng mL−1, respectively. Most foreign substances do not interfere in the determination, and the method has good selectivity and high sensitivity. It has been applied to the determination of DNA in synthetic samples and in real samples with satisfactory results.  相似文献   
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