Particle-induced bridging in immiscible polymer blends

Pickering emulsions are emulsions whose drops are stabilized against coalescence by particles adsorbed at their interface. Recent research on oil/water/particle systems shows that particles can sometimes adsorb at two oil/water interfaces. Such “bridging particles” can glue together drops of oil in water or vice versa. We hypothesize that the same effect should apply in immiscible polymer blends with droplet-matrix morphologies, viz., added particles should glue together drops and give rise to particle-bridged drop clusters. We test this hypothesis in PIB-in-PDMS blends [PIB, poly(isobutylene); PDMS, poly(dimethylsiloxane)] with fumed silica particles. Direct visualization shows that the particles can indeed induce clustering of the drops, and the blends appear to show gel-like behavior. Such gel-like behavior is confirmed by dynamic oscillatory experiments. However, we are unable to conclusively attribute the gel-like behavior to droplet clustering: Association of the fumed silica particles in the bulk, which itself causes gel-like behavior, confounds the results and prevents clear analysis of the gluing effect of the particles. We conclude that PIB/PDMS/fumed silica is not a good model system, for studying particle-containing polymer blends. We instead propose that spherical monodisperse silica particles can offer a far more convenient model system, and provide direct visual evidence of gluing of PIB drops in a PDMS matrix.     

矢量非傍轴厄米-拉盖尔-高斯光束的光束质量

基于矢量Rayleigh-Sommerfeld衍射积分，推导出矢量非傍轴圆偏振厄米-拉盖尔-高斯(HLG)光束的远场解析表达式.矢量非傍轴圆偏振高斯光束可作为一般公式的特例给出.将桶中功率(PIB)概念推广到非傍轴范畴，用以描述矢量非傍轴光束的远场光束质量，其中光强用时间平均坡印廷矢量的z分量取代.数值计算和分析表明，矢量非傍轴HLG光束的PIB不仅与束腰宽度与波长之比w₀/λ有关，而且还与α参数，模指数n和m以及所取桶的尺寸有关. 关键词： 矢量非傍轴厄米-拉盖尔-高斯光束 矢量Rayleigh-Sommerfeld衍射积分 桶中功率     

The influences of plasma ion bombarded on crystallization, electrical and mechanical properties of Zn-In-Sn-O films

The quality of co-sputtering derived Zn-In-Sn-O (ZITO) film was adjusted by different gas (oxygen and argon) induced plasma ions bombarding (PIB) treatment. The result showed that the film conductivity could be improved after plasma bombardment. The increment of oxygen vacancies and plasma bombard-induced thermal energy were main reasons. Notably, the efficiency of Ar plasma bombarded for improved conductivity not only was better but also had a smoother surface morphology. Due to Ar ions will not react with metal atoms to form oxide and possessed a higher momentum. In addition, the O-rich layer on the ultra-surface not only was removed but also enhanced film reliability by plasma bombarded that could enhance the performance of optoelectronic devices.