激光等离子体相互作用中Weibel不稳定性

利用粒子模拟法对超强激光与等离子体相互作用中产生的Weibel不稳定性及其产生机制进行了详细的研究。给出不稳定性的线性色散关系和饱和磁场与各向异性参数之间的函数关系,发现Weibel不稳定性的存在使超强激光在等离子体中激发的自生磁场饱和,饱和自生磁场的存在使粒子速度分布在激光传播方向上表现出各向异性。讨论了Weibel不稳定性的线性和非线性饱和过程,对更好地理解快点火物理中自生磁场的产生、快电子输运等过程有重要意义。     

饱和土中端承桩纵向振动特性研究

基于饱和多孔介质理论研究了三维轴对称条件下端承桩在饱和土中的纵向耦合振动. 首先通 过引入势函数对Biot动力固结方程解耦，采用算子分解方法及分离变量法求得饱和土层振动 解，进而利用桩土完全耦合条件得到桩土系统定解. 然后对桩顶的频率和时域响应进行参数 研究，结果表明，桩的长径比和桩土模量比对桩顶动力响应有较大影响，而渗透力对其影响 较小. 最后将幅频及时域反射波理论拟合结果与桩基实测结果加以对比，结果表明理论曲线 与实测曲线规律一致.     

横观各向同性饱和地基上无限板的稳态振动

研究了横观各向同性饱和土地基上无限板的稳态振动问题. 基于直角坐标系下横观各向同性饱和介质Biot波动方程的一般解，采用双重Fourier积分变换技术，建立了饱和地基与无限矩形板相互作用的动力方程，利用数值方法求解该方程，得到任意谐振荷载作用下饱和半空间体上无限板稳态响应的一般解. 数值结果表明，横观各向同性饱和地基上无限板的振动与各向同性饱和地基上的无限板的振动特性存在明显差异.     

高效液相色谱-气相色谱在线联用同时测定土壤中饱和烃和芳香烃

为加强对土壤中石油烃类污染物的风险管控,生态环境部已将石油烃类列为土壤中的重点监测项目.石油烃源于石油与合成油,是涵盖一定碳数范围的碳氢化合物,主要分为饱和烃和芳香烃两大类.芳香烃通常是高度烷基化的单环、双环与多环芳烃,其对人和动物的毒性较饱和烃大很多,因此,仅仅测定土壤中总石油烃含量难以准确评估其环境毒性.目前环境领...     

非线性Volterra-Stieltjes积分方程的解

利用Schauder不动点定理和饱和解的理论,研究下列非线性Volterrastieltjes积分方程x(t)=h(t) ∫t0u(t,s,x(s))dsg(t,s).在适当的条件下,证明了上述方程在[0, ∞)上有连续解.     

黄土中压力型锚索锚固段应力分析

为研究黄土地区压力型锚索锚固机理,根据压力型锚索锚固段受力状态,基于三线型剪切-滑移模型,推导了注浆体与岩土体界面在弹性阶段所对应的剪应力及轴向应力分布的闭合解.根据相关压力型锚索锚固试验数据,采用推导的闭合解计算了不同张拉荷载作用下界面的剪应力分布,并与试验结果进行了对比.结果表明,各级张拉荷载作用下注浆体/岩土体界面剪应力的分布及其最大值与试验结果基本吻合,验证了本文提出解析模型的正确性与可靠性;压力型锚索锚固界面剪应力呈指数分布规律,在承压板附近剪应力分布集中且应力较大,随着离承压板距离的增大,剪应力逐渐减小;压力型锚索锚固界面剪应力峰值随外荷载增大而增大.研究结果可为压力型锚索的设计和计算提供一种理论参考.     

天然产物液体组分饱和蒸汽压间接测定实验方法

根据物理化学中的相平衡体系热力学理论设计了间接测定天然产物液体组分饱和蒸汽压数据的实验方法,采用改进的Ellis或Rose平衡釜测定不同压力下高浓度的天然产物溶液汽液平衡数据,推算不同温度下天然产物液体组分的饱和蒸汽压,回归出Antoine方程的各参数A,B,C,建立天然产物液体组分饱和蒸汽压与温度的关联式.应用该方法测定了蒎烷、对孟烷与长叶烯的饱和蒸汽压,所得结果与文献值吻合良好,为天然产物液体组分饱和蒸汽压的实验测定与关联提供了一种便捷的途径.     

Confirmation of n-Hexane as an Inert Co-Solvent in the Production of Functionalized Silicon Nanoparticles from Reactive High-Energy Ball Milling

Alkanes such as n-hexane have been used as co-solvents in the production of functionalized semiconductor nanoparticles from alkenes and alkynes using Reactive High Energy Ball Milling (RHEBM) under the assumption that they are non-reactive under typical milling conditions. In this paper, a comparative study with two hydrocarbon solvents of comparable chain length, 1-hexyne, and n-hexane, and their milling products using three different commercially available silicon precursors, namely single crystal silicon wafers and polycrystalline particles having a nominal size of 4 µm and 1 mm, is reported. It is found that nanoparticle formation and surface functionalization in all the three silicon systems occurs only with 1-hexyne; n-hexane is non-reactive and does not lead to appreciable functionalized nanoparticle formation under the conditions studied. Nanoparticles (where formed) and microparticle byproducts of appropriate samples are characterized by Transmission electronic microscope (TEM), Fourier transform infrared  (FTIR), Photoluminiscence spectroscopy (PL), Nuclear magnetic resonance ¹H/¹³C NMR, and thermogravimetry TGA to separately confirm nanoparticle formation and surface functionalization.     

Foodomics revealed the effects of ultrasonic extraction on the composition and nutrition of cactus fruit (Opuntia ficus-indica) seed oil

Cactus is a tropical fruit with a high nutritional value; however, little information is available regarding the comprehensive utilization of its byproducts. This study aimed to explore the composition and nutritional value of cactus fruit seed oil (CFO) and reveal the effects of ultrasound-assisted extraction and traditional solvent extraction on oil quality. Foodomics analysis showed that CFO extracted using a traditional solvent is rich in linolenic acid (9c12cC18:2, 57.46 ± 0.84 %), α-tocopherol (20.01 ± 1.86 mg/100 g oil), and canolol (200.10 ± 1.21 μg/g). Compared to traditional solvent extraction, ultrasound-assisted extraction can significantly increase the content of lipid concomitants in CFO, whereas excessive ultrasound intensity may lead to the oxidation of oils and the formation of free radicals. Analysis of the thermal properties showed that ultrasound had no effect on the crystallization or melting behavior of CFO. To further demonstrate the nutritional value of CFO, a lipopolysaccharide (LPS)-induced lipid metabolism imbalance model was used. Lipidomics analysis showed that CFO significantly reduced the content of oxidized phospholipids stimulated by LPS and increased the content of highly bioactive metabolites such as ceramides, thus alleviating LPS-induced damage in C. elegans. Hence, CFO is a functional oil with high value, and ultrasound-assisted extraction is advocated. These findings provide new insights into the comprehensive utilization of cactus fruits.     

Ferricyanide Armed Anodes Enable Stable Water Oxidation in Saturated Saline Water at 2 A/cm2

The direct seawater electrolysis at high current density and low overpotential affords an effective strategy toward clean and renewable hydrogen fuel production. However, the severe corrosion of anode as a result of the saturation of Cl⁻ upon continuous seawater feeding seriously hamper the electrolytic process. Herein, cobalt ferricyanide / cobalt phosphide (CoFePBA/Co₂P) anodes with Cap/Pin structure are synthesized, which stably catalyze alkaline saturated saline water oxidation at 200–2000 mA cm⁻² over hundreds of hours without corrosion. Together with the experimental findings, the molecular dynamics simulations reveal that PO₄³⁻ and Fe(CN)₆³⁻ generated by the electrode play synergistic role in repelling Cl⁻ via electrostatic repulsion and dense coverage, which reduced Cl⁻ adsorption by nearly 5-fold. The novel anionic synergy endow superior corrosion protection for the electrode, and is expected to promote the practical application of saline water electrolysis.