壳装炸药殉爆实验和数值模拟

进行了壳装固黑铝炸药殉爆实验,通过观察残留炸药、壳体和见证板变形,判断被发炸药的爆炸情况,得到了炸药临界殉爆距离。建立了壳装炸药殉爆实验计算模型,采用非线性有限元计算方法,对壳装固黑铝炸药殉爆实验进行了数值模拟。计算中采用预设壳体单元破片方法描述主发炸药壳体破片的形成和破片对被发炸药的撞击起爆,炸药临界殉爆距离的计算结果与实验结果基本一致。主要是主发炸药中部的壳体破片撞击到被发炸药,被发炸药起爆位置也在装药中部。炸药壳体厚度主要影响破片速度和质量、被发炸药的防护性能,从而影响炸药临界殉爆距离。 更多还原     

爆轰合成超细金刚石机理探讨

就爆轰合成超细金刚石的机理进行探讨：１．传统的碳相图已不能作为爆轰合成过程的依据;２．由于存在等离子体－晶体的直接相变,整个过程可能有几种相变作用共存;３．爆炸容器中的介质对产物有重要的影响。最后,提出了对整个问题进行研究所应遵循的规律。     

氢氧燃烧及爆轰驱动激波管

分析并观察了沿驱动段轴向分布多火塞燃烧驱动段的性能．提出主膜处同一管截面均匀分布三火花塞引燃的点火方法．用这种点火方法驱动产生的入射激波强度重复性较高,激波后气流速度、温度和压力的定常性亦大大改善,可满足气动试验实际要求．提出在驱动段尾端串接卸爆段来消除爆轰波反射高压,从而可使反向爆轰驱动段用来产生高焓高密度试验气流．这种反向爆轰驱动产生的入射激波重复性高,激波衰减弱．在主膜处的收缩段产生的反射波可缓解爆轰波后跟随的稀疏波的不利影响,从而使前向爆轰驱动具有实用性．在产生的入射激波强度相同条件下,前向爆轰驱动所需的爆轰驱动段可爆混合气初始压力可较反向爆轰低近一个量级．     

非理想爆轰产物流场的程序燃烧计算法

研究了用程序燃烧法计算非理想爆轰时引进不真实反应速率和人为粘性对化学反应区终点处参数的影响,证实不会引起流体力学波和程序燃烧波的分离。还给出了一般炸药状态方程情况的爆速曲率关系和对化学反应区终点参数计算误差的估计。     

Numerical simulation of oxide nanoparticle growth characteristics under the gas detonation chemical reaction by space-time conservation element–solution element method

Under harsh conditions (such as high temperature, high pressure, and millisecond lifetime chemical reaction), a long-standing challenge remains to accurately predict the growth characteristics of nanosize spherical particles and to determine the rapid chemical reaction flow field characteristics. The growth characteristics of similar spherical oxide nanoparticles are further studied by successfully introducing the space-time conservation element–solution element (CE/SE) algorithm with the monodisperse Kruis model. This approach overcomes the nanosize particle rapid growth limit set and successfully captures the characteristics of the rapid gaseous chemical reaction process. The results show that this approach quantitatively captures the characteristics of the rapid chemical reaction, nanosize particle growth and size distribution. To reveal the growth mechanism for numerous types of oxide nanoparticles, it is very important to choose a rational numerical method and particle physics model.     

带隔板装药爆轰波马赫反射理论研究和数值模拟

基于三波理论和Whitham方法对带隔板装药爆轰波相互作用后发生的正规反射和非正规反射进行了理论分析,给出了爆轰波发生马赫反射时临界入射角和马赫杆增长角等参数的变化规律,提出了马赫杆高度的计算模型。基于凝聚炸药爆轰Jones-Wilkins-Lee(JWL)模型和冲击起爆的Lee-Tarver模型,利用有限元计算软件对带隔板装药爆轰波的传播过程进行了数值模拟。结果表明,发生马赫反射后,随着爆轰波的传播,马赫杆的高度不断增加。数值模拟结果与理论计算结果吻合较好,说明本文中采用的理论模型和数值模拟方法能够较准确地描述带隔板装药爆轰波马赫反射的传播过程。     

CL-20混合炸药的爆轰波结构

基于爆轰数值模拟计算,分析了CL-20混合炸药爆轰反应的特征,设计了炸药与窗口的界面粒子速度测量实验装置;采用激光干涉法,测量了C-1炸药(CL-20/粘合剂/94/6)与窗口的界面粒子速度; 运用先求导、再分段拟合的方法,对界面粒子速度随时间的变化曲线进行了数据处理,确定了炸药爆轰CJ点对应的时间位置;根据CJ点对应的粒子速度,计算获得了炸药的爆轰反应区宽度和CJ爆轰压力。结果显示:密度为1.943 g/cm3的C-1炸药的爆轰反应时间为38 ns,CJ压力为34.2 GPa。     

利用液体炸药爆轰制备石墨烯薄片

强氧化性酸的环境下,石墨易形成石墨层间化合物(GICs),利用石墨这一特性,将天然石墨置于发烟硝酸中,并加入硝基甲烷,配制成液体炸药,使用塑料容器盛装后放入爆轰反应釜中引爆。收集爆轰产物,并利用XRD、EDX、SEM、TEM、Raman光谱、比表面积与孔隙度分析仪进行分析,结果显示:制备出的石墨烯具有良好的晶体特性并呈现极薄的片状结构,其比表面积达到天然石墨的9.16倍,平均厚度约为14.73 nm。     

A double-front structure of detonation wave as the result of phase transitions

Using thermochemical code calculations, we show that the nanographite–nanodiamond phase transition, which may occur in the detonation products of a number of carbon containing explosives, can affect the detonation properties and can cause a specific detonation regime with some unusual peculiarities. Among them, we first note the failure of the Chapman–Jouguet condition and the presence of the sonic plane, where the Mach number is equal to unity, in a detonation product expansion wave at a lower pressure than that at the Chapman–Jouguet point. The peculiarities of this detonation regime are demonstrated by the example of TNT, HNS, and RDX. The computed detonation velocities are in excellent agreement with experiments over a wide range of initial charge densities for all of the investigated explosives. The results of this work allow one to explain, e.g., contradictory experimental data on the detonation pressure and on the length of the reaction zone for TNT. We believe that some other solid–solid, solid–liquid, and liquid–liquid phase transformations in the detonation products may also cause a detonation regime with the same features as shown here for the nanographite–nanodiamond transition. We suggest a computational study that should facilitate proposing detonation experiments strongly arguing in favor of the model presented. PACS 47.40.-x; 47.40.Rs; 64.70.-p; 64.70.Kb; 05.70.-a; 05.70-.CeThis paper was based on the work that was presented at the 19th International Colloquium on the Dynamics of Explosions and Reactive Systems, Hakone, Japan, July 27–August 1, 2003.     

以RDX为基的含铝炸药中铝粉粒度和氧化剂形态对加速金属能力的影响

利用激光速度干涉仪研究了含微米铝粉和纳米铝粉复合炸药加速金属平板的能力,结果表明纳米铝粉的引入能够获得更大的金属平板自由面速度,其反应时间比微米复合含铝炸药缩短35.1%。研究了氧化剂的形态对含铝炸药性能的影响,用物理化学手段获得的RDX/AP复合粒子复合粒子制作的含铝炸药加速金属平板的能力优于机械混合RDX/AP的含铝炸药,前者的反应时间也比后者短。此外,还研究了以富氧炸药取代RDX获得的含铝炸药的性能,结果表明其加速金属平板的速度比RDX/Al复合炸药提高10%。