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31.
高锰酸盐指数的灰色GM(1,1)预测 总被引:1,自引:0,他引:1
以中山市岐江河近7年的高锰酸盐指数监测数据为基础,采用灰色系统理论中的预测方法,建立了岐江河高锰酸盐指数的灰色预测模型。用该模型预测岐江河2006年、2007年、2008年高锰酸盐指数的值分别为5.3,5.4和5.4。 相似文献
32.
Polymers containing bicarbazolyl moieties in the main chain have been synthesized by the modified Ullmann coupling reaction from 9H,9′H-[3,3′]bicarbazolyl and different dihalo derivatives. The number-average molecular weights of the polymers synthesized were in the range of 2500-6200 with a molecular weight distribution of 1.6-3.1. Well-defined model compounds for the polymers have been synthesized by stepwise reactions. All these compounds have been found to form glasses with glass transition temperatures in the range of 57-119 °C as characterised by differential scanning calorimetry. The electron photoemission spectra of the compounds have been recorded and the ionisation potentials of 5.35-5.4 eV have been established. Room temperature hole drift mobility of the synthesized compounds molecularly dispersed in a polymer host range from 10−6 to 3 × 10−5 cm2/V s at an electric field of 106 V/cm at the room temperature. 相似文献
33.
A generalization of the existential and universal quantifier, the monotone quantifiers, are studied. It is shown that the model theory for monotone quantifiers behaves very much like classical model theory. Completeness theorems, definability theorems and preservation theorems are given. Ultraproducts, reduced products and Back and Forth arguments are studied.This work is part of the research program of the G.N.S.A.G. group of the Italian C.N.R. 相似文献
34.
J.W. Guthrie M.S.A. Salam C.A. Murimboh C.L. Chakrabarti D.C. Grégoire 《Analytica chimica acta》2005,528(2):205-218
Complexation of Ni(II), Cu(II), Zn(II), and Cd(II) by dissolved organic carbon (DOC) in some freshwater lakes in Rouyn-Noranda, Québec, Canada, where they were impacted by effluents from a nearby copper smelter, was measured by kinetic and equilibrium methods using cathodic and anodic stripping voltammetry. The measured free-metal-ion and labile metal-complex concentrations were compared with the predictions made by a widely-used computer speciation model, the Windermere Humic Aqueous Model (WHAM): WHAM V and its improved version WHAM VI. If it is assumed that 65% of the DOC is “active”, i.e. behaving as isolated humic substances such as fulvic acid, both versions of WHAM are able to predict the labile and free-metal-ion concentrations of Ni, Zn, and Cd reasonably well; however, both underestimate the free-copper-ion concentration by one to two orders of magnitude. WHAM VI is generally better than or equal to WHAM V for successfully predicting most of the free-metal-ion concentrations. The modelled competition by Al(III) and Fe(III) in the lake surface waters showed that in most cases Cu(II) was most affected by this competition. WHAM VI predicts a larger effect from the Al(III) and Fe(III) competition than does WHAM V. 相似文献
35.
In the past, few theoretical attempts have been made to describe quantitatively the adsorption of ionic surfactants at liquid
interfaces. Well-known adsorption isotherms due to Frumkin or Hill–de Boer cannot respond to the specific electrostatic and
geometric properties of the surfactant molecules. Our approach is based on a combination of the Gouy–Chapman theory with a
modified Frumkin isotherm. The modification implies that the system is free to choose an optimal head group area and an optimal
arrangement of the surfactant molecules in the interface as a function of bulk concentration. Interaction energies between
neighbouring adsorbed surfactant molecules and between surfactant and water molecules are taken into consideration. The minimum
of the Gibbs free energy of the system is equivalent to a minimal interfacial tension. Thus, the thermodynamically stable
isotherm can be obtained as the lower envelope of the family of σ versus ln c isotherms resulting from different choices of the model parameters, including the area per molecule. According to the Gibbs
equation, the Γ versus ln c adsorption isotherm is obtained as the derivative of this envelope. By variation of the model parameters, the envelope of
the calculated adsorption isotherms can be fitted to experimental data of the interfacial tension versus bulk concentration.
A computer program is used to calculate the σ versus c and the Γ versus ln c curves as well as to fit the parameters.
Received: 28 October 1999/Accepted: 8 February 2000 相似文献
36.
静态傅里叶变换光谱仪的机理及干涉条纹的校正 总被引:1,自引:0,他引:1
针对高速、瞬时光谱测量要求光谱仪的结构简单、装备方便、实时性强的特点,文章介绍了一种静态傅里叶变换光谱仪,并对其原理进行了推导与剖析。针对其调整中出现的干涉条纹的倾斜校正问题,进行了详细的理论分析和干涉条纹模型的数学推导,得出倾斜镜旋转参数和光学元件最小通光口径之间的数学关系,以及倾斜镜旋转参数和干涉条纹旋转参数之间的数学关系。通过利用Matlab7.0数学工具,对所总结推导的干涉条纹模型进行模拟,对所得的各种参数之间的数学关系进行验证。分析结果表明据此数学关系所求得的β角校正精度达到1.4%,是一种有效可行的校正方法。 相似文献
37.
阻尼对于结构动力学响应具有重要的影响,但有限元模型一般很难对阻尼特性进行精确建模.基于实测频响函数,研究了一种有限元模型阻尼特性的复参数修正方法.以待修正区域各单元质量、刚度矩阵的比例修正系数为复修正参数,建立了单元矩阵比例修正的灵敏度方程直接算法,并对比分析了复修正参数与不同阻尼特性之间的数学关系.以六自由度集中参数模型和25杆平面桁架模型为例,验证了复参数修正方法在阻尼特性修正中的有效性. 相似文献
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40.
The age of information (AoI) metric was proposed to measure the freshness of messages obtained at the terminal node of a status updating system. In this paper, the AoI of a discrete time status updating system with probabilistic packet preemption is investigated by analyzing the steady state of a three-dimensional discrete stochastic process. We assume that the queue used in the system is , which represents that the system size is 2 and the packet in the buffer can be preempted by a fresher packet with probability . Instead of considering the system’s AoI separately, we use a three-dimensional state vector to simultaneously track the real-time changes of the AoI, the age of a packet in the server, and the age of a packet waiting in the buffer. We give the explicit expression of the system’s average AoI and show that the average AoI of the system without packet preemption is obtained by letting . When is set to 1, the mean of the AoI of the system with a queue is obtained as well. Combining the results we have obtained and comparing them with corresponding average continuous AoIs, we propose a possible relationship between the average discrete AoI with the queue and the average continuous AoI with the queue. For each of two extreme cases where and , we also determine the stationary distribution of AoI using the probability generation function (PGF) method. The relations between the average AoI and the packet preemption probability , as well as the AoI’s distribution curves in two extreme cases, are illustrated by numerical simulations. Notice that the probabilistic packet preemption may occur, for example, in an energy harvest (EH) node of a wireless sensor network, where the packet in the buffer can be replaced only when the node collects enough energy. In particular, to exhibit the usefulness of our idea and methods and highlight the merits of considering discrete time systems, in this paper, we provide detailed discussions showing how the results about continuous AoI are derived by analyzing the corresponding discrete time system and how the discrete age analysis is generalized to the system with multiple sources. In terms of packet service process, we also propose an idea to analyze the AoI of a system when the service time distribution is arbitrary. 相似文献