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101.
A previously proposed model describing the trapping site of the interstitial atomic hydrogen in borate glasses is analyzed. In this model the atomic hydrogen is stabilized at the centers of oxygen polygons belonging to B–O ring structures in the glass network by van der Waals forces. The previously reported atomic hydrogen isothermal decay experimental data are discussed in the light of this microscopic model. A coupled differential equation system of the observed decay kinetics was solved numerically using the Runge Kutta method. The experimental untrapping activation energy of 0.7×10−19 J is in good agreement with the calculated results of dispersion interaction between the stabilized atomic hydrogen and the neighboring oxygen atoms at the vertices of hexagonal ring structures. 相似文献
102.
A.P. Srivastava D. Srivastava K. Sudarshan S.K. Sharma P.K. Pujari B. Majumdar K.G. Suresh G.K. Dey 《Journal of magnetism and magnetic materials》2012
Amorphous ribbons of different thicknesses of Co64.5Fe3.5Si16B14Ni2 alloy were synthesized using the melt spinning technique by varying wheel speed. The effect of cooling rate on the ribbon thickness and their soft magnetic properties have been studied. The amorphous structure has been characterized in terms of structural free volume and medium range order (MRO) by positron annihilation spectroscopy and fluctuation electron microscopy techniques. Positron lifetime spectra of amorphous samples showed two lifetime components. The first component was found to be correlated with MRO whereas, the second lifetime component was found to be associated with nanovoid type of defects, and the second component was strongly dependent on processing conditions. It could be established that the coercivity of the amorphous samples produced by the rapid solidification technique mainly depends on the defects formed during processing rather than change induced in MRO. 相似文献
103.
Thermal, structural and optical properties of Nd3+ ions in tellurite glass (TeO2-ZnO-Na2O-Li2O-Nb2O5) have been investigated. Differential thermal analysis revealed reasonably good forming tendency of the glass composition. FTIR spectra were used to analyze the functional groups present in the glass. Judd-Ofelt intensity parameters were derived from the absorption spectrum and used to calculate the radiative lifetime, branching ratio and stimulated emission cross-section of the 4F3/2→4I9/2, 11/2, 13/2 transitions. The quantum efficiency of the 4F3/2 level is comparable as well as higher than the typical value of the other tellurite based glasses. The decay from the 4F3/2 level is found to be single exponential for different concentrations of Nd3+ ions with a shortening of lifetime with increasing concentration. The experimental values of branching ratio and saturation intensity of 4F3/2→4I11/2 transition indicate the favourable lasing action with low threshold power. 相似文献
104.
Aditya M. Vora 《Central European Journal of Physics》2008,6(2):253-262
The theoretical investigations of the superconducting state parameters (SSP) viz. electron-phonon coupling strength λ, Coulomb pseudopotential μ*, transition temperature T
C
, isotope effect exponent α and effective interaction strength N
O
V of six binary La100-C
Ga
C
(C = 16, 20, 22, 24, 26 and 28 at. %) metallic glasses have been reported using Ashcroft’s empty core (EMC) model potential
for the first time. Five local field correction functions proposed by Hartree (H), Taylor (T), Ichimaru-Utsumi (IU), Farid
et al. (F) and Sarkar et al. (S) are used in the present investigation to study the screening influence on the aforesaid properties. It is observed that
the electron-phonon coupling strength λ and the transition temperature T
C
are quite sensitive to the selection of the local field correction functions, whereas the Coulomb pseudopotential μ*, isotope effect exponent α and effective interaction strength N
O
V show weak dependences on the local field correction functions. The T
C
obtained from H-local field correction function are found in qualitative agreement with available experimental data and show
almost linear nature with the concentration (C) of ‘Ga’ element. A linear T
C
equation is proposed by fitting the present outcomes for H-local field correction function, which is in conformity with other
results for the experimental data. Also, the present results are found to be in qualitative agreement with other such earlier
reported data, which confirms the superconducting phase in the metallic glasses.
相似文献
105.
Aditya M. Vora 《Central European Journal of Physics》2008,6(2):238-252
Ashcroft’s empty core (EMC) model potential is used to study the superconducting state parameters (SSPs) viz. electron-phonon
coupling strength λ, Coulomb pseudopotential μ*, transition temperature T
C
, isotope effect exponent αand effective interaction strength N
O
V of some binary metallic glasses based on the superconducting (S), conditional superconducting (S’) and non-superconducting
(NS) elements of the periodic table. Five local field correction functions proposed by Hartree (H), Taylor (T), Ichimaru-Utsumi
(IU), Farid et al. (F) and Sarkar et al. (S) are used for the first time with EMC potential in the present investigation to study the screening influence on the aforesaid
properties. The T
C
obtained from the H-local field correction function are in excellent agreement with available theoretical or experimental
data. In the present computation, the use of the pseudo-alloy-atom model (PAA) was proposed and found successful. Present
work results are in qualitative agreement with such earlier reported experimental values which confirm the superconducting
phase in all metallic glasses. A strong dependency of the SSPs of the metallic glasses on the valence ‘Z’ is identified.
相似文献
106.
Studies of dielectric relaxation and ac conductivity have been made on three samples of sodium tungsten phosphate glasses over a temperature range of 77–420 K. Complex relative permitivity data have been analyzed using dielectric modulus approach. Conductivity relaxation frequency increases with the increase of temperature. Activation energy for conductivity relaxation has also been evaluated. Measured ac conductivity (σm(ω)) has been found to be higher than σdc at low temperatures whereas at high temperature σm(ω) becomes equal to σdc at all frequencies. The ac conductivity obeys the relation σac(ω)=Aω S over a considerable range of low temperatures. Values of exponent S are nearly equal to unity at about 78 K and the values decrease non-linearly with the increase of temperature. Values of the number density of states at Fermi level (N(E F)) have been evaluated at 80 K assuming values of electron wave function decay constant α to be 0.5 (Å)?1. Values of N(E F) have the order 1020 which are well within the range suggested for localized states. Present values of N(E F) are smaller than those for tungsten phosphate glasses. 相似文献
107.
M. Sasaki V. Dupuis J.-P. Bouchaud E. Vincent 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,29(3):469-479
We study the deviations from perfect memory in negative temperature cycle spin glass experiments. It is known that the a.c.
susceptibility after the temperature is raised back to its initial value is superimposed to the reference isothermal curve
for large enough temperature jumps ΔT (perfect memory). For smaller ΔT, the deviation from this perfect memory has a striking non monotonous behavior: the `memory anomaly' is negative for small ΔT's, becomes positive for intermediate ΔT's, before vanishing for still larger ΔT's. We show that this interesting behavior can be reproduced by simple Random Energy trap models. We discuss an alternative
interpretation in terms of droplets and temperature chaos.
Received 23 May 2002 Published online 14 October 2002
RID="a"
ID="a"e-mail: sasaki@ipno.in2p3.fr 相似文献
108.
This paper reports a comparative study of shear banding in BMGs resulting from thermal softening and free volume creation.
Firstly, the effects of thermal softening and free volume creation on shear instability are discussed. It is known that thermal
softening governs thermal shear banding, hence it is essentially energy related. However, compound free volume creation is
the key factor to the other instability, though void-induced softening seems to be the counterpart of thermal softening. So,
the driving force for shear instability owing to free volume creation is very different from the thermally assisted one. In
particular, long wave perturbations are always unstable owing to compound free volume creation. Therefore, the shear instability
resulting from coupled compound free volume creation and thermal softening may start more like that due to free volume creation.
Also, the compound free volume creation implies a specific and intrinsic characteristic growth time of shear instability.
Finally, the mature shear band width is governed by the corresponding diffusions (thermal or void diffusion) within the band.
As a rough guide, the dimensionless numbers: Thermal softening related number B, Deborah number (denoting the relation of instability growth rate owing to compound free volume and loading time) and Lewis
number (denoting the competition of different diffusions) show us their relative importance of thermal softening and free
volume creation in shear banding. All these results are of particular significance in understanding the mechanism of shear
banding in bulk metallic glasses (BMGs).
Supported by the Chinese Academy of Sciences under the project “Multi-Scale Complex System” (Grant No. KJCX-SW-L08), the National
Natural Science Foundation of China (Grant Nos. 10725211 and 10721202), and the Doctorial Start-up Fund of Hunan University
of Science and Technology (Grant No. E50840) 相似文献
109.
The specific heat of Fermi–Pasta–Ulam systems has until now been estimated through the energy fluctuations of a suitable subsystem, and opposite answers were apparently provided concerning its possible vanishing for vanishing temperatures. In the present paper a more realistic numerical implementation of the specific heat measurement is discussed, which mimics the interaction of the FPU system with a calorimeter. It is found that there exists a freezing critical temperature below which the relaxation times to equilibrium between FPU system and calorimeter become relevant, so that the system presents aging and hysteresis features very similar to those familiar in glasses and spin glasses. In particular, in the framework of such a point of view involving finite long times, the specific heat appears to vanish for vanishing temperatures. 相似文献
110.
C. Djurberg K. Jonason P. Nordblad 《The European Physical Journal B - Condensed Matter and Complex Systems》1999,10(1):15-21
Experiments on the temperature and time dependence of the response function and the field cooled magnetisation of a Cu(Mn)
spin glass at temperatures below the zero field spin glass temperature are used to explore the non-equilibrium nature of the
underlying spin configuration. The results imply that a certain spin configuration is imprinted on the system as the temperature
is decreased at a constant cooling rate. The cooling rate governs the magnitude of the FC magnetisation ((H,T)). Any intermittent halt at a constant temperature, , imprints an extended spin configuration, a process that is reflected e.g. in a downward relaxation of . On continued cooling at the same rate, the magnitude of (T) remains at a lower level than that of a continuous cooling curve. These results are put into the context of the corresponding
behaviour of the response function as observed in measurements of the relaxation of the zero field cooled magnetisation.
Received 27 October 1998 and Received in final form 30 November 1998 相似文献