全文获取类型
收费全文 | 7431篇 |
免费 | 464篇 |
国内免费 | 689篇 |
专业分类
化学 | 5999篇 |
晶体学 | 140篇 |
力学 | 711篇 |
综合类 | 12篇 |
数学 | 152篇 |
物理学 | 1570篇 |
出版年
2024年 | 12篇 |
2023年 | 86篇 |
2022年 | 111篇 |
2021年 | 124篇 |
2020年 | 230篇 |
2019年 | 182篇 |
2018年 | 177篇 |
2017年 | 258篇 |
2016年 | 389篇 |
2015年 | 295篇 |
2014年 | 311篇 |
2013年 | 539篇 |
2012年 | 429篇 |
2011年 | 491篇 |
2010年 | 398篇 |
2009年 | 539篇 |
2008年 | 400篇 |
2007年 | 467篇 |
2006年 | 426篇 |
2005年 | 341篇 |
2004年 | 296篇 |
2003年 | 222篇 |
2002年 | 162篇 |
2001年 | 159篇 |
2000年 | 136篇 |
1999年 | 134篇 |
1998年 | 121篇 |
1997年 | 95篇 |
1996年 | 89篇 |
1995年 | 91篇 |
1994年 | 100篇 |
1993年 | 70篇 |
1992年 | 57篇 |
1991年 | 67篇 |
1990年 | 54篇 |
1989年 | 32篇 |
1988年 | 62篇 |
1987年 | 42篇 |
1986年 | 46篇 |
1985年 | 47篇 |
1984年 | 59篇 |
1983年 | 33篇 |
1982年 | 68篇 |
1981年 | 39篇 |
1980年 | 30篇 |
1979年 | 36篇 |
1978年 | 13篇 |
1976年 | 5篇 |
1973年 | 5篇 |
1957年 | 2篇 |
排序方式: 共有8584条查询结果,搜索用时 15 毫秒
31.
Blends of polyarylate of bisphenol A, PAr, with two commercial main chain liquid crystalline polymers, Vectra A950 and Vectra B950, are studied. From dynamic viscoelastic measurements it is deduced that both systems (PAr/Vectra A950 and PAr/Vectra B950) are immiscible and scanning electron microscopy (SEM) micrographs show the presence of spherical domains of the liquid crystalline polymer when PAr constitutes the matrix. Extrusion capillary measurements reveal that, under conditions of temperature and shear rate similar to those of processing, the viscosity is reduced to approximately 10% of its value when the content of liquid crystalline polymer is only 20%. This great improvement of the rheological properties is observed in both PAr/Vectra A950 and PAr/Vectra B950 blends. The effect of draw ratio on Young's modulus for different compositions is also analyzed, pointing out the reinforcing action of both liquid crystalline polymers on polyarylate: for instance, 20% of Vectra B950 in the blend gives rise to a 700% increase of the modulus of fibres prepared at a draw ratio of 50. SEM of the extrudates reveals that the spherical domains are elongated at the entrance of the capillary giving rise to a microfibrillar morphology which is related to the excellent rheological and mechanical properties of the blends. 相似文献
32.
33.
Wei Zhou Ruonong Fu Rongji Dai Zaifu Huang Yanfei Chen 《Journal of separation science》1994,17(10):719-722
A new kind of side chain liquid crystalline polysiloxane containing a crown ether with a longer spacer (PSC-11) has been prepared and coated on a fused silica capillary column. The main chroma-tographic characteristics including efficiency, polarity, and selectivity have been examined. The phase exhibits the retention properties of both liquid crystal and crown ether stationary phases and possesses higher efficiency and better selectivity than PSC-3, which has a shorter spacer between the main polysiloxane chain and liquid crystalline side chain. 相似文献
34.
Sergey P. Gladchenko Yurii Z. Kovdrya Viktor A. Nikolaenko 《Journal of Molecular Liquids》2005,120(1-3):175-179
Conductivity of electrons in a quasi-one-dimensional (Q1D) system over liquid helium in narrow channels with the parabolic profile of the potential well has been investigated at temperature T, from 0.4 to 1.8 K, for different driving electric fields and radius of channel curvature. The interval of linear electron densities varied from 2.18×103 up to 1.7×106 cm−1.
The inverse mobility (1/μeff) in the electron-ripplon scattering region at the high linear densities of charges in the channel increases with temperature decreasing. This anomalous behavior of the electron transport in the low-temperature region has been explained by either the electron ordering or the polaronic effects in confined conducting channels. The nonlinear behavior of the electron velocity as a function of a driving electric field is supposed to be due to Breg–Cherenkov radiation of the ripplons. The radiation occurred if the velocity of electrons in the channel approaches to the critical value. 相似文献
35.
《Electroanalysis》2003,15(4):294-302
Macrocyclic lipophilic polyamines were applied as the sensory elements of polymeric liquid membrane electrodes. These hosts gain the anion receptor functionality upon protons uptake from the aqueous solutions. The electrodes studied were able to distinguish potentiometricaly isomers of monocharged and doublecharged forms of ethylene and benzene dicarboxylic acids. The selectivity of interaction between protonated hosts and anionic guests relays not only on the electrostatic interactions, but on hydrogen bounds formations as well. The influence of lipophilicity of protonated hosts on the potential response generation was discussed. 相似文献
36.
M. Carme Calderer M. Gregory Forest Qi Wang 《ournal of non Newtonian Fluid Mechanics》2004,120(1-3):69
We present a systematic derivation of hydrodynamic theories for nonhomogeneous nematic liquid crystal polymers (LCPs) by approximating the molecules as rigid ellipsoids, which can be either uniaxial molecules (spheroids) or biaxial ones. The short range interaction is assumed to be dominated by the excluded volume effect. Additional molecular properties with ellipsoidal molecules, e.g., a dipole–dipole interaction in extended nematics and chiral molecular structure in cholesterics, are accounted for through additional intermolecular potentials. Long-range molecular interaction is implemented through an averaged mean-field potential characterized by interaction functions. The extra elastic stress tensor is calculated using an extended virtual work principle consistent with conservation of angular momentum on the material volume, whereas the extra viscous stress is obtained by Batchelor’s volume averaging method. In the isothermal case, the theories are shown to satisfy the second law of thermodynamics, i.e., they admit positive production of entropy or energy dissipation. In the case of cholesterics, the kinetic theory reduces to the Leslie–Ericksen theory in the limit of weak translational diffusion, weak long range interaction, and weak flow. 相似文献
37.
This paper presents the applications of digital image correlation technique to the mesoscopic damage and fracture study of
some granular based composite materials including steelfiber reinforced concrete, sandstone and crystal-polymer composite.
The deformation fields of the composite materials resulted from stress localization were obtained by the correlation computation
of the surface images with loading steps and thus the related damage prediction and fracture parameters were evaluated. The
correlation searching could be performed either directly based on the gray levels of the digital images or from the wavelet
transform (WT) coefficients of the transform spectrum. The latter was developed by the authors and showed higher resolution
and sensitivity to the singularity detection. Because the displacement components came from the rough surfaces of the composite
materials without any coats of gratings or fringes of optical interferometry, both surface profiles and the deformation fields
of the composites were visualized which was helpful to compare each other to analyze the damage of those heterogeneous materials.
The project supported by the National Natural Science Foundation of China (10125211 and 10072002), the Scientific Committee
of Yunnan Province for the Program of Steel Fiber Reinforced Concrete, and the Institute of Chemical Materials, CAEP at Mianyang 相似文献
38.
Thi Thi Nge Naruhito Hori Akio Takemura Hirokuni Ono Tsunehisa Kimura 《Journal of Polymer Science.Polymer Physics》2003,41(7):711-714
A high magnetic field of 5 T was used to fabricate a magnetically aligned, optically anisotropic, liquid‐crystalline chitin/poly(acrylic acid) composite. The aligned mesophase was fixed by photoinitiated free‐radical polymerization. From an examination of polarized optical micrographs and an X‐ray diffraction study, a high degree of orientation of 0.70 was observed for the composite with a higher liquid‐crystalline chitin concentration (10.70 wt %); the orientation was reduced with a decreased chitin concentration at a given acrylic acid concentration. The X‐ray data for the developed composite showed a uniplanar orientation for the chitin crystallites, with its molecular long axes perpendicular to the direction of the magnetic field. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 711–714, 2003 相似文献
39.
Advanced analytical models have been developed at the ILK, which offer a possibility of calculating the vibro-acoustic and damping behavior of textile-reinforced composite shells and plates with account of shear effects. The simulation models elaborated have been verified on selected examples, and the analytical results were fully corroborated by accompanying numerical calculations for typical lay-ups.__________Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 41, No. 3, pp. 289–302, May–June, 2005. 相似文献