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71.
D.A. Mazón-Montijo M. Quevedo-López H.N. Alshareef R. Ramírez-Bon 《Applied Surface Science》2007,254(2):499-505
We study the initial growth stages of CdS thin films deposited by an ammonia-free chemical bath deposition process. This ammonia-free process is more environmentally benign because it reduces potential ammonia release to the environment due to its high volatility. Instead of ammonia, sodium citrate was used as the complexing agent. We used atomic force microscopy (AFM), Rutherford backscattering (RBS) and X-ray photoelectron spectroscopy (XPS) to investigate the morphological and chemical modifications at the substrate surface during the first initial stages of the CdS deposition process. Additionally, X-ray diffraction (XRD) and optical transmission spectroscopy measurements were carried out to compliment the study. XPS results show that the first nucleation centers are composed by Cd(OH)2 which agglomerate in patterns of bands, as demonstrated by AFM results. It is also observed that the conversion to CdS (by anionic exchange) of the first nucleus begins before the substrate surface is completely covered by a homogenous film. 相似文献
72.
73.
We report on first experiments combining quasi-digital highly selective etching and atomic force microscopy (AFM) to examine the interior interfaces of semiconductor heterostructures. Lattice matched (GaIn)As/InP heterostructures grown by metalorganic vapour-phase epitaxy (MOVPE) are taken as a model system to check the capabilities of this new method. Standard selective etchants for different material systems have been optimized in selectivity and etch rate to achieve a quasi-digital etching behaviour. In this way, the real structure of interior interfaces can be determined by AFM. We find a significant difference between the surface of the heterostructure and the interior interfaces. 相似文献
75.
根据对应原理,得到了类氢原子能态平均寿命半经典的计算公式τ(n,l),然后利用相对论单通道量子数亏损理论进行推广,得到用来计算考虑总角动量J的激发态寿命公式τ(n,l,l+1/2)和τ(n,l,l-1/2),利用单通道量子数亏损理论得到了碱金属原子n、l远大于1时激发态寿命的半经典公式τ(n.l)=τ0(m+M/nm/v/+M)2v7l(l+1/2)/n4,其计算结果和实验数据符合的很好. 相似文献
76.
We consider a four-dimensional generalization of Hess–Appel’rot system and costruct its Lax pair. Both classical and algebro-geometric integration procedure are proceeded. The algebro-geometric integration is based on deep facts from geometry of Prym varieties such as the Mumford relation and Mumford-Dalalyan theory. The integration is similar to the integration of Lagrange bitop which has recetly been performed by the authors. 相似文献
77.
Ken‐ichi Shinohara Tasuku Suzuki Takeshi Kitami Shingo Yamaguchi 《Journal of polymer science. Part A, Polymer chemistry》2006,44(2):801-809
We fabricated a micrometer‐long supramolecular chain in which π‐conjugated polyrotaxane was coupled. A new experimental setup was designed and constructed, and the simultaneous direct imaging of the structure and fluorescent function was achieved. Furthermore, we identified the formation of a polymer intertwined network and observed novel fluorescence due to a long‐range interaction via this intertwined network over a distance of 5 μm or more without quenching over 15 min in the near field. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 801–809, 2006 相似文献
78.
Wolfgang H. Binder Laura Petraru Robert Sachenshofer Ronald Zirbs 《Monatshefte für Chemie / Chemical Monthly》2006,137(7):835-841
Summary. The surface modification of nanoparticles via azide/alkine-1,3-dipolar cycloaddition-reactions is described. Ligand exchange onto various nanoparticles was monitored by
1H NMR spectroscopy and formed the basis for the attachment of ligands onto the nanoparticles and their subsequent modification
by dipolar cycloaddition reactions. Nanoparticle-surfaces were monitored by binding onto self-assembled monolayers derivatized
with matching supramolecular interactions after derivatization. 相似文献
79.
Ricardo de Souza Pereira Nivaldo AntÔnio Parizotto Vitor Baranauskas 《Applied biochemistry and biotechnology》1996,59(2):135-143
Different strains of baker’s yeast(Saccharomyces cerevisiae) were imaged with an atomic force microscope (AFM). The images of uncoated and nonfixed samples were reproducible with high-constrast
and nanometer-resolution. Molecules from the polysaccharide surface of the cell wall were pictured and the distance of atoms
was measured. The preparation of samples was easy, suggesting that AFM is a useful tool in this type of analyses. 相似文献
80.
A study of body waves in fractured porous media saturated by two fluids is presented. We show the existence of four compressional and one rotational waves. The first and third compressional waves are analogous to the fast and slow compressional waves in Biot's theory. The second compressional wave arises because of fractures, whereas the fourth compressional wave is associated with the pressure difference between the fluid phases in the porous blocks. The effects of fractures on the phase velocity and attenuation coefficient of body waves are numerically investigated for a fractured sandstone saturated by air and water phases. All compressional waves except the first compressional wave are diffusive-type waves, i.e., highly attenuated and do not exist at low frequencies.Now at Izmir Institute of Technology, Faculty of Engineering, Gaziosmanpasa Bulvari, No.16, Cankaya, Izmir, Turkey. 相似文献