Birefringence in polycarbonate: Molecular orientation induced by cooling stresses. I. Free quenching

The residual birefringence distributions in polycarbonate disks quenched in a liquid bath under various conditions are determined. Unbalanced distributions of approximately parabolic shape are obtained in the cross-sections in general. A systematic influence of the initial quench temperature on the imblance of the birefringence distributions is observed, with higher initial temperatures leading to a strong shift of birefringence in the positive direction. The systematic variation of the birefringence distribution with quenching conditions is interpreted in terms of a stress and an orientation contribution. The distributions are predicted correctly by a numerical program making use of the linear stress-optical rule with a different stress-optical coefficient above and below the glass-transition temperature. The contribution of molecular orientation is distinguished experimentally from the stress contribution by annealing experiments. © 1993 John Wiley & Sons, Inc.     

Elastic silicon-film-based nanoshells: Formation, properties, and applications

Controllable formation and properties of solid single-crystal micro-and nanoshells of various shapes (tubes and spirals, vertically positioned rings and cylinders, and bent and trough-shaped cantilevers) are briefly reviewed, and new results are given. The shells and complicated structures of prescribed size and shape are formed with the use of elastic energy of initial strained SiGe/Si films of nanometer thickness and methods of highly selective and directed detachment of the films from the silicon substrates. It is experimentally demonstrated that the diameters of the fabricated SiGe/Si nanotubes are several times smaller than the values predicted by the continuum elasticity theory. The properties of the shells made of semiconductor and hybrid (metal-semiconductor and metal-dielectric-semiconductor) films and their applications in micro-and nanoscale electrical engineering are discussed. __________ Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 47, No. 6, pp. 114–128, November–December, 2006.     

Dislocation structure of shear bands in single crystals

A mathematical model is proposed for the development of a shear band in crystals. The model is based on the mechanism of double cross-slips of screw-dislocation segments. Equations are derived to study instability of the uniform distribution of dislocations. A solution is found in the form of a traveling wave, which describes the shear-band structure. __________ Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 47, No. 6, pp. 102–113, November–December, 2006.     

On Some Nonclassical Problems of Fracture Mechanics Taking into Account the Stresses Along Cracks

The paper reports on the results from analysis of some nonclassical fracture problems that allow for stresses along cracks. The results have been obtained by the author and his collaborators at the Institute of Mechanics (Kiev) since 1980     

X-ray diffraction measurements on PE 2000 between 10 K and 300

Summary It was possible to obtain film exposures of the WAXS-diagram (2 50°) of a PE-fraction in the temperature range from 10 K to 300 K by using a special low temperature Guinier-chamber. The crystallographica-,b-andc-axis has been calculated from the positions of all reflexions. The different behaviour of their expansion coefficients can be explained by activation of rotational- and torsional-vibrations. If we take the number of net planes as constant and consider a temperature-independent part resulting from paracrystalline disorder (built up during crystallization), we can describe the linear increasing of the integral widths of the reflexions with decreasing temperature (10 ... 100%) with building up of inherent stresses inside the crystals.

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Zusammenfassung Eine spezielle Tieftemperatur-Guinier-Kammer ermöglichte es, Filmaufnahmen der Röntgenweitwinkelstreukurve (2 50°) einer hochkristallinen Polyäthylen-Fraktion im Bereich von ca. 10 K bis 300 K zu erhalten. Das unterschiedliche Temperaturverhalten der Ausdehnungskoeffizienten der kristallographischena-,b- undc-Achse, berechnet aus der Lage aller auswertbaren Reflexe, kann durch Anregung von Torsions- und Rotationsschwingungen erklärt werden. Unter der Annahme konstanter Kristallitgrößen sowie eines temperaturunabhängigen parakristallinen Gitterstörungsanteils (hervorgerufen durch Defekteinbau bei der Kristallisation), kann die starke Zunahme der integralen Breiten der Reflexe (bis ca. 100%) zu tiefen Temperaturen auf Eigenspannungen in den Kristalliten zurückgeführt werden.

     

GaN基蓝绿光LED电应力老化分析

对InGaN/GaN多量子阱蓝光和绿光LED进行了室温20,40,60 mA加速电流下的电应力老化研究,发现蓝光与绿光样品经过60 mA电流老化424 h后,其电学性能表现出一定的共性与差异性:在小测量电流下,绿光样品的光衰减幅度较蓝光样品大~9%;而在较大测量电流 (20 mA)下,两者的光衰减幅度基本相同 (18%)。同时,蓝绿光样品的正向电学性能随老化时间的变化幅度基本一致,反映出它们具有相似的退化机制,绿光样品老化后增多的缺陷大部分体现为简单的漏电行为,而并非贡献于非辐射复合中心。在此基础上对GaN基外延结构进行了优化,优化后的LED长期老化的光衰减幅度较参考样品降低了3%。     

有环壳过渡段的锥—柱组合壳的应力和稳定性

用解析方法计算了受静水外压载荷作用的有环壳过渡段的锥—柱组合壳中的应力值，并用瑞利法计算了其失稳临界载荷。计算结果说明，利用环壳过渡值锥—柱壳形成光滑连接，可使连接部位的局部应力值显著降低，并使失稳临界载荷有所提高     

Analytical model of transient compressive stress evolution during growth of high diffusivity thin films on substrates

We present an analytical model of transient compressive stress evolution during growth of thin films with high surface and grain boundary diffusivities on substrates. The model provides a closed-form analytical solution which compares well with numerical analysis as well as recent experimental data on transient stress evolution during electrodeposition of Sn films on substrates.     

Size-dependent thermal stresses in the core–shell nanoparticles

The thermal stress in a magnetic core–shell nanoparticle during a thermal process is an important parameter to be known and controlled in the magnetization process of the core–shell system. In this paper we analyze the stress that appears in a core–shell nanoparticle subjected to a cooling process. The external surface temperature of the system, considered in equilibrium at room temperature, is instantly reduced to a target temperature. The thermal evolution of the system in time and the induced stress are studied using an analytical model based on a time-dependent heat conduction equation and a differential displacement equation in the formalism of elastic displacements. The source of internal stress is the difference in contraction between core and shell materials due to the temperature change. The thermal stress decreases in time and is minimized when the system reaches the thermal equilibrium. The radial and azimuthal stress components depend on system geometry, material properties, and initial and final temperatures. The magnitude of the stress changes the magnetic state of the core–shell system. For some materials, the values of the thermal stresses are larger than their specific elastic limits and the materials begin to deform plastically in the cooling process. The presence of the induced anisotropy due to the plastic deformation modifies the magnetic domain structure and the magnetic behavior of the system.     

“A new approach to formulate the general strength theories for anisotropic discontinuous materials” Part B General form of polynomial to describe the strength of anisotropic discontinuous materials

A new approach to describe the failure hypersurface on the basis of assumptions presented in Part A reveals the new form of failure stress polynomial. In the presented theory new terms such as: unit tensor object, object formed on the basis of unit tensor object, the first, second and third form of the anisotropy failure function, and the first and the second type of object axis, were defined. On the basis of these terms the coefficients of their polynomials were formulated as values of the appropriate objects. The presented theory divides the six dimensional hyperspace of stresses into eight parts in which eight intersected hypersurfaces constitute the failure hypersurface. Six hypersurfaces may be assigned to two of three mutually coupled sets of elements. In general cases the theory may be used to describe the failure hypersurface for anisotropic structures where tensorial relationships do not occur. The obtained polynomial is transformed to tensor polynomial on the assumption that the failure stress tensorial relationships describe the failure hypersurface of anisotropic materials.