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31.
Sa?a?NovakEmail author Susana?Maria?Henriques?Olhero José?Maria?Fonte?Ferreira Andreja?Zupan?i? 《Rheologica Acta》2004,43(5):559-566
Due to the hygroscopic nature of fine alumina powders, the presence of water may have a detrimental effect on the rheological properties of a suspension in melted paraffin for low-pressure injection moulding (LPIM). For this reason, a modification of the powder surface from hydrophilic to hydrophobic is essential for the production of high-quality moulded ceramics. In our paper, the efficiency of the application and the chemisorption of protective monomolecular layers of a long-chain carboxylic acid or its salts will be presented. The effect of the powder treatment on the shear viscosity and the viscoelastic properties of the suspensions for LPIM as well as on their stability in terms of the detrimental effect of water will be discussed.This paper was presented at the first Annual European Rheology Conference (AERC) held in Guimarães, Portugal, September 11-13, 2003. 相似文献
32.
33.
When the stagnation temperature of a perfect gas increases, the specific heats and their ratio do not remain constant any
more and start to vary with this temperature. The gas remains perfect and its state equation always remains valid, except
it will be called a calorically imperfect gas. The aim of this research is to develop the relations of the necessary thermodynamics
and geometrical ratios and to study the supersonic flow at high temperature (lower than the threshold of dissociation). The
results are found by the resolution of nonlinear algebraic equations and integration of complex analytical functions where
the exact calculation is impossible. The dichotomy method is used to solve the nonlinear equation, and the Simpson algorithm
is used for the numerical integration of the found integrals. A condensation of the nodes is used, since the functions to
be integrated have a high gradient at the extremity of the interval of integration. A comparison is made with a calorifcally
perfect gas to determine the error of this. An application is made for air in a supersonic nozzle.
The text was submitted by the authors in English. 相似文献
34.
A dual mode multi-section gain-coupled distributed feedback laser with tunable mode spacing is subharmonically injection locked at 0.315 THz. The injected signal consists of an optical comb with harmonics 35 GHz apart and a bandwidth of approximately 1.9 THz. The optical comb is a result of strong four-wave mixing in a highly-nonlinear dispersion-shifted fiber. In order to observe locking of the multi-section laser, the output is optically downconverted to RF frequencies using the same optical comb. The locked multi-section DFB laser is a coherent and tunable optical source suitable for continuous-wave terahertz generation systems. 相似文献
35.
F. J. Baltá Calleja D. R. Rueda T. Secall R. K. Bayer M. Schlimmer 《Journal of Macromolecular Science: Physics》2013,52(4):461-469
Native potato starch was prepared using different processing methods. The samples were characterized by wide-angle X-ray scattering (WAXS), optical microscopy, differential scanning calorimetry (DSC), and microhardness. Compression molding of the starch granules led to sintered relatively brittle materials. Here, the amylopectin crystals of the native powder remained grossly preserved. Preparation of dry films from aqueous gels resulted in disintegration of the structure of the native starch granules and in the formation of a new semicrystalline structure comprised of crystallized amylose molecules. Injection molding of native starch was found to be a processing method that gives rise to amorphous materials with superior mechanical properties. 相似文献
36.
Hirokazu Sato Shusaku Hamada Roberto M. Sertkawa Tatsuya Nishimura Takashi Usui Hideo Sekino 《高压研究》2013,33(1-6):403-413
Abstract Continuous flames have been observed in Supercritical water oxidation (scWO) of isopropyl alcohol (IPA), using a vertical continuous reactor with sapphire windows and a mixing nozzle. Two types of continuous flame were confirmed: the one was long pale blue colored and the other was red short cone shaped, changing blue to red at around air ratio 2.0. The flame was strongly influenced by IPA concentration, air ratio and design of the mixing nozzle. Results for decomposition of PA are presented for IPA concentrations ranging from 600 up to 28260 ppm as TOC and initial reactor temperatures, were mostly around 490°C, at 25 MPa. Decomposition rate at steady state was over 99.9%. Experimentally measured CO2 and O2 concentrations at the flue gas were in good agreement with theoretically calculated values. Even for low air ratio as 1.1, high decomposition rate without CO, NO, NO2 was achieved. 相似文献
37.
Aouatef Ladhari Hedi Belhadjsalah Johanne Denault 《Polymer Degradation and Stability》2010,95(4):429-13298
The behaviour of polypropylene nanocomposites containing different amounts of commercial nanoclay upon exposure to distilled water and sea water at different temperatures was investigated and compared with that of neat polypropylene. In the initial stages, the weight gain (moisture absorption) follows Fick's second law, but at longer times deviations are observed owing to physical degradation and in some cases a loss of mass. Distilled water diffuses more rapidly than sea water. As the nanoclay content increases, both the rate of moisture absorption and the maximum moisture content increase, owing to the hydrophilic nature of the nanoclay and the added compatibilizing agent. Although the moisture absorption decreases the flexural properties of both the nanocomposites and neat PP, because the unexposed (as-moulded) nanocomposites are significantly superior to the neat PP they remain so even after prolonged exposure. 相似文献
38.
A simple and direct approach was developed for thermochemolytic analysis of a wide range of biomolecules present in plant materials using an injection port of a gas chromatograph/mass spectrometer (GC/MS) and a novel solids injector consisting of a coiled stainless steel wire placed inside a modified needle syringe. Optimum thermochemolysis (or Thermally Assisted Hydrolysis/Methylation) was achieved by using a suitable methanolic solution of trimethylsulfonium hydroxide (TMSH) or tetramethylammonium hydroxide (TMAH) with an injection port temperature of 350 °C. Intact, methylated flavonoids, saccharides, phenolic and fatty acids, lignin dimers and diterpene resin acids were identified. Samples include tea leaves, hemicelluloses, lignin isolates and herbal medicines. Unexpected chromatographic results using TMAH reagent revealed the presence of intact methylated trisaccharides (658 Da) and structurally informative dimer lignin markers. 相似文献
39.
推导出了停流法流动注射络合滴定的理论公式,计算了简单易实现的流路图,详细观察分析了流动注射络合滴定中的样品带与试剂流混合后在流通池中的吸光度变化。从理论上分析并预测了停流流动注射络合滴定的性质。 相似文献
40.
A numerical study has been carried out to investigate the gas flows in a micronozzle using a continuum model under both slip and no‐slip boundary conditions. The governing equations were solved with a finite volume method. The numerical model was validated with available experimental data. Numerical results of exit thrust showed good agreement with experimental data except at very low Reynolds numbers. For parametric studies on the effect of geometric scaling, the nozzle throat diameter was varied from 10 to 0.1 mm, whereas throat Reynolds number was varied from 5 to 2000. A correlation has also been developed to calculate the specific impulse at specified throat diameter and Reynolds number. The effect of different gases on the specific impulse of the nozzle, such as helium, nitrogen, argon and carbon dioxide, was also examined. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献