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351.
We establish a duality formula for the problem Minimize f(x)+g(x) for h(x)+k(x)<0 where g, k are extended-real-valued convex functions and f, h belong to the class of functions that can be written as the lower envelope of an arbitrary family of convex functions. Applications in d.c. and Lipschitzian optimization are given. 相似文献
352.
A simple and commonly used method to approximate the total claim distribution of a (possibly weakly dependent) insurance collective is the normal approximation. In this article, we investigate the error made when the normal approximation is plugged in a fairly general distribution-invariant risk measure. We focus on the rate of convergence of the error relative to the number of clients, we specify the relative error’s asymptotic distribution, and we illustrate our results by means of a numerical example. Regarding the risk measure, we take into account distortion risk measures as well as distribution-invariant coherent risk measures. 相似文献
353.
Hong-yi Fan 《Annals of Physics》2007,322(4):866-885
Via the route of applying Newton-Leibniz integration rule to Dirac’s symbolic operators, we show that the density operator e−βH, where H is multi-mode quadratic interacting boson operators, is a mapping of symplectic transformation in the coherent state representation appearing in the form of non-symmetric ket-bra operator integration. By virtue of the technique of integration within an ordered product (IWOP) of operators, we deduce its normally ordered form which directly leads to the generalized partition function formula and the Wigner function. Some new representations, such as displacement-squeezing correlated squeezed coherent states, constructed by the IWOP technique, also bring convenience in deriving partition functions. 相似文献
354.
With the intention of determining the local thickness within a crystalline thin foil specimen, by means of transmission electron microscopy (TEM), a method previously proposed by Zuo and Shi [J.M. Zuo, Y.F. Shi, Microsc. Microanal. 7 (Suppl. 2) (2001) 224-225] was applied. Using the convergent beam technique, with the incident beam parallel to a zone axis with low indices, diffraction patterns were obtained for some aluminum alloys with low solute content. These patterns were contrasted with those obtained from simulations based on the dynamic theory with Bloch's waves formalism. The local thickness of the thin foil was then obtained by visually comparing the simulated patterns with the experimental one.Comparison of the proposed method with that based on the analysis of two-beam convergent beam patterns [P.M. Kelly, A. Jostsons, R.G. Blake, J.G. Napier, Phys. Stat. Solidi (a) 31 (1975) 771-780] and with that based on the ratio of intensity of the zero loss peak to the total intensity in an electron energy loss spectrum [R.F. Egerton, Electron Energy Loss Spectroscopy in the Electron Microscope, second ed., Plenum Press, New York, 1996] was carried out. A very good agreement between thicknesses determined using the different methods was found. The sensitivity of the method of Zuo et al. was found to be about 1 or 2 nm. The advantages and limitations of the different methods are discussed. The method of Zuo et al. can provide fast and reliable results and can be applied in all modern instruments. 相似文献
355.
The damping of the motion of domain walls of a sandwich domain structure by the eddy currents magnetic fields, the stray fields and the hysteresis friction fields is investigated. The blocking of the motion of domain walls by the eddy currents magnetic fields is discovered. 相似文献
356.
《Natural product research》2012,26(2):87-93
3,4-Dihydroxy-7,8-dihydro- -ionone 3- O - - d -glucopyranoside 1 has been isolated from a methanolic extract of apple ( Malus domestica ) leaves by XAD-2 adsorption chromatography and subsequent purification by high speed countercurrent chromatography (HSCCC) and HPLC. Under acidic conditions this glycoside gives rise to a number of volatile compounds including 1,1,6-trimethyl-1,2-dihydronaphthalene (TDN) 2 , which is known as an off-flavor compound in wine. In the course of the study, six additional glycoconjugates were isolated from apple leaves, i.e. roseoside 3 , 3-oxo- -ionol - d -glucopyranoside 4 , benzoic acid - d -glucose ester 5 , kaempferol 3- O -rhamnoside 6 , (+)-syringaresinol - d -glucopyranoside 7 and 4-hydroxy-5-(3\"-methyl-2\"-butenyl)-benzoic acid methylester 3- - d -glucopyranoside 8 . The latter compound has been isolated for the first time in nature. In order to avoid the 'kerosene-off-flavor' caused by TDN, the methanolic extract has been subjected to yeast fermentation. This treatment reduced the amount of TDN formed and resulted in an improved flavor impression of the methanolic extract. 相似文献
357.
《Integral Transforms and Special Functions》2012,23(6):397-408
In the present article the authors introduce several new integral transforms including the ℒ4-transform and the 𝒫4-transform as generalizations of the classical Laplace transform and the classical Stieltjes transform, respectively. It is shown that the second iterate of the ℒ4-transform is essentially the 𝒫4-transform. Using this relationship, a number of new Parseval–Goldstein type identities are obtained for these and many other well-known integral transforms. The identities proven in this article give rise to useful corollaries for evaluating infinite integrals of special functions. Some examples are also given as illustrations of the results presented here. 相似文献
358.
Hussein Moustafa Mohamed E. Elshakre Huwaida M. E. Hassaneen Salwa Elramly 《中国化学会会志》2019,66(12):1666-1681
Electronic spectra of 2,4‐diphenyl‐1,5‐benzothiazepine and some of its derivatives in 1,2‐dichloromethane and ethanol are investigated experimentally and theoretically using the time dependent density functional theory (TD‐DFT) method at the B3LYP/6‐311G** level of the theory. The origin of the spectrum of the parent compound is found to be an additive one. The observed ultra violet (UV) spectra in both solvents show two bands S1 in the range between 312–334 nm and S2 in the range between 248–272 nm. The solvent effect is investigated experimentally and theoretically and a blue shift is observed, which is explained in terms of a hydrogen bond model between the solvent and the most negative site of the solute (N atom). This theoretical model is robust in reproducing the experimental blue shift and calculating the hydrogen bond energy and hydrogen bond length. The extent of delocalization and charge transfer processes of the studied compounds is estimated and discussed in terms of natural bond orbital (NBO) analysis and second order perturbation interactions (E2) between donors and acceptors. The effect of substituents of the studied compounds in both solvents shows a noticeable red shift attributed to hyperconjugation effects of the π electron systems of the different moieties. 相似文献
359.
Joachim Loup Uttam Dhawa Fabio Pesciaioli Joanna Wencel‐Delord Lutz Ackermann 《Angewandte Chemie (International ed. in English)》2019,58(37):12803-12818
Molecular syntheses largely rely on time‐ and labour‐intensive prefunctionalization strategies. In contrast, C?H activation represents an increasingly powerful approach that avoids lengthy syntheses of prefunctionalized substrates, with great potential for drug discovery, the pharmaceutical industry, material sciences, and crop protection, among others. The enantioselective functionalization of omnipresent C?H bonds has emerged as a transformative tool for the step‐ and atom‐economical generation of chiral molecular complexity. However, this rapidly growing research area remains dominated by noble transition metals, prominently featuring toxic palladium, iridium and rhodium catalysts. Indeed, despite significant achievements, the use of inexpensive and sustainable 3d metals in asymmetric C?H activations is still clearly in its infancy. Herein, we discuss the remarkable recent progress in enantioselective transformations via organometallic C?H activation by 3d base metals up to April 2019. 相似文献
360.
Wenhui Zhang Qingquan Wu Allen G. Oliver Anthony S. Serianni 《Acta Crystallographica. Section C, Structural Chemistry》2019,75(6):610-615
The crystal structure of methyl α‐d ‐mannopyranosyl‐(1→3)‐2‐O‐acetyl‐β‐d ‐mannopyranoside monohydrate, C15H26O12·H2O, ( II ), has been determined and the structural parameters for its constituent α‐d ‐mannopyranosyl residue compared with those for methyl α‐d ‐mannopyranoside. Mono‐O‐acetylation appears to promote the crystallization of ( II ), inferred from the difficulty in crystallizing methyl α‐d ‐mannopyranosyl‐(1→3)‐β‐d ‐mannopyranoside despite repeated attempts. The conformational properties of the O‐acetyl side chain in ( II ) are similar to those observed in recent studies of peracetylated mannose‐containing oligosaccharides, having a preferred geometry in which the C2—H2 bond eclipses the C=O bond of the acetyl group. The C2—O2 bond in ( II ) elongates by ~0.02 Å upon O‐acetylation. The phi (?) and psi (ψ) torsion angles that dictate the conformation of the internal O‐glycosidic linkage in ( II ) are similar to those determined recently in aqueous solution by NMR spectroscopy for unacetylated ( II ) using the statistical program MA′AT, with a greater disparity found for ψ (Δ = ~16°) than for ? (Δ = ~6°). 相似文献