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891.
本文采用同位素稀释和相对灵敏度因子法相结合,定量分析了高纯Tb4O7中的20多种微量元素的含量,测定检测限0.0x-0.00xμg/g,大多数元素的相对标准偏差在30%以内,用同位素稀释法分析了Cu,Ba,Dy三元素,其相对标准偏差均在10%以内。 相似文献
892.
Aryl oxalate chemiluminescence detection for high-performance liquid chromatography offers ultrahigh sensitivity for interactive fluorophores. With optimal analytes, attomole limits of detection can be obtained with conventional instrumentation 相似文献
893.
CEN Ying-zhou 《高等学校化学研究》1992,(3)
Two novel constituents were isolated from the roots of Chinese medicinal herbs, Salvia miltiorrhiza. Their structures were determined by spectroscopic technique. The compounds were named 13,14-dihydroxy-15-methyl-benzo[2,3-a]-7,7-dimethyl-12-oxa-tricyclo[4,4,21.4,0]dodecane(1) and 16-methyl-tropono[2,3-c]-7,7-dimethyl-12-oxa-tricyclo[4,4,21.4,0]dodecane(2). 相似文献
894.
Chen Chen Mei Liangmo Department of Physics Shandong University Jinan P.R.China Guo Huiqun Zhao Jiangao State Key Lab. of Magnetism Institute of Physics Chinese Academy of Sciences Beijing P.R.China 《原子与分子物理学报》1997,(2)
GIANTMAGNETO-IMPEDANCEINFe-BASEDSOFTFERROMAGNETICRIBBONSChenChenMeiLiangmoDepartmentofPhysics,ShandongUniversity,Jinan250100... 相似文献
895.
J. Du S. Gnanarajan A. Bendavid 《Physica C: Superconductivity and its Applications》2004,400(3-4):143-152
The effect of magnesium oxide (MgO) surface conditions on in-plane grain orientation and critical current density of epitaxial YBa2Cu3O7 (YBCO) films was systematically investigated. The MgO substrates were either “as received” or stored for some time, cleaned using different methods and lithographically prepared for our step-edge junction devices. The YBCO films were grown via reactive thermal co-evaporation by Theva, GmbH. The surface characterisation of MgO substrates was studied using X-ray photoelectron spectroscopy (XPS). The in-plane grain orientation of the YBCO films was studied by means of X-ray diffraction (XRD) φ-scan and the critical current density was measured for the XRD scanned samples. The surface condition of the MgO substrates was found to have a strong influence on the in-plane grain orientation and the critical current density of the YBCO films. The MgO substrates with a degraded or contaminated surface gave rise to 45° grain misorientation in YBCO films and reduced the critical current density. A final process step using a low energy Ar ion beam etching (IBE) of the MgO substrates prior to the YBCO film deposition was found effective in removing the in-plane grain misorientation and promoting the growth of perfectly aligned c-axis YBCO films. 相似文献
896.
研究了以溴代十六烷基吡啶和TritonX 100为增溶剂,以5 Br PADN为显色剂,在pH为9.7的氨 氯化铵介质下连续测定铜和镍的方法。铜、镍与5 Br PADN的配合物在547nm处均有较大的吸收,其表观摩尔吸光系数为εCu=3.94×104L·mol-1·cm-1,εNi=3.64×104L·mol-1·cm-1,配合物至少可稳定12h,铜、镍分别在0~10μg/10ml和0~8μg/10ml范围内服从比耳定律,方法用于铸铁中铜和镍的连续测定,结果满意。 相似文献
897.
A superconducting oxide with a stoichiometry La3CaBa3Cu7O15.5+x, in which x = 0.75, was prepared. It had a tetragonal triple-perovskite structure with lattice parameters a = 3.879 Å and c = 11.637 Å. According to resistivity measurements, a sharp superconducting transition, ΔTc(10-90%) = 1.5 K, and Tc(zero) = 80 K were observed. When it was measured at a small magnetic field (10-20 gauss) with field cooling, the sintered pellet showed a positive magnetic susceptibility, but the powdered sample exhibited (he diamagnetism of a typical superconductor. However, no peculiar shielding effect was found in both the sintered and powdered samples. 相似文献
898.
899.
900.
Zhi-Heng Zhang Guo-Yin Yin Zhi-Cheng Tan Yan Yao Li-Xian Sun 《Journal of solution chemistry》2006,35(10):1347-1355
The molar heat capacities of an aqueous Li2B4O7 solution were measured with a precision automated adiabatic calorimeter in the temperature range from 80 to 356 K at a concentration of 0.3492 mol⋅kg−1. The occurrence of a phase transition was determined based on the changes in the curve of the heat capacity with temperature. A phase transition was observed at 271.72 K corresponding to the solid-liquid phase transition; the enthalpy and entropy of the phase transition were evaluated to be Δ H
m = 4.110 kJ⋅mol−1 and Δ S
m = 15.13 J⋅K−1⋅mol−1, respectively. Using polynomial equations and thermodynamic relationship, the thermodynamic functions [H
T
−H
298.15] and [S
T
−S
298.15] of the aqueous Li2B4O7 solution relative to 298.15 K were calculated in temperature range 80 to 355 K at intervals of 5 K. Values of the relative apparent molar heat capacities of the aqueous Li2B4O7 solution, C
p,φ, were calculated at every 5 K in temperature range from 80 to 355 K from the experimental heat capacities of the solution and the heat capacities of pure water. 相似文献