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841.
在研究汽车内部CAN/LIN总线组网原理的基础上,分析了2种汽车总线互连的关键点与难点——汽车网关.针对采用多个分立网关集成度较低的缺点,提出了一种基于ARM7的集成网关方案,并详细阐述了该方案的软硬件实现方法.实验室组网实验表明:该网关不仅能顺利实现高速CAN总线、低速CAN总线和LIN总线的互连,而且集成度高、性能稳定. 相似文献
842.
Chromate conversion coatings are used on aluminium alloys, primarily for their renowned corrosion resistant properties. Although these coatings are in common industrial use, neither the protection mechanisms, nor the coating interation with the intermetallic precipitation phases are fully understood. Macroscopic models have been developed in order to represent the galvanic cells present in aluminium alloys due to the presence of such intermetallic particles. Particles modelled include CuAl2, FeAl3 and Cu2FeAl7, all know to be cathodic to the aluminium matrix. Variations in deposition, both in composition and thickness, are indicative of the mechanisms of deposition over each phase. Characterisation of the coating deposition was carried out using X-ray photoelectron spectroscopy, Rutherford backscattering spectroscopy, Auger electron spectroscopy, scanning electron microscopy with X-ray analysis. Depositional characteristics have been determined for each phase. The coating on the intermetallic phases is primarily Al oxide, and is significantly thinner than the coating on the matrix. This coating on the matrix consists mainly of a mixed Cr/Al oxide. The coating on the intermetallic phases was only one tenth the thickness of the matrix coating, and contained higher levels of Fe, Al and O. Matrix coating chemistry predominated with Cr, O, Fe and N, indicative of a chromate conversion coating. The mechanism for reduced rates of deposition over intermetallic phases was found to be affected by fluorine ion attack leading to intermetallic de-alloying and decomposition of Fe(CN)62− accelerator into amide groups on the matrix. 相似文献
843.
Microalloying additions of Ag (0.1 at.%) increase the hardening response of Al–Zn–Mg alloys to elevated temperature ageing in the range 100–200°C due to the formation of a high density of very fine η′ precipitate plates. The present study employed transmission electron microscopy (TEM) and three-dimension atom probe (3DAP) to study the early stages of ageing in the alloy Al–1.8Zn–3.4Mg–0.1Ag (at.%) in an attempt to identify the role of Ag in stimulating precipitation hardening. During isothermal ageing at 90°C, the hardening response is attributed to a high density of Zn–Mg–Ag rich solute clusters and GP zones. During ageing at 150°C, η′ precipitates nucleate at Zn–Mg–Ag rich solute clusters, the former growing as {111} platelets with an average composition of approximately 20 at.% Zn, 20 at.% Mg and 1.4 at.% Ag. The 3DAP data indicates that the co-segregation of Zn and Ag and subsequently Zn and Mg atoms precedes the formation of the Zn–Mg–Ag rich solute clusters. The GP zones and η′ precipitates were observed to possess a Zn:Mg ratio close to 1:1, whereas the equilibrium η precipitates possessed compositions consistent with MgZn2. Furthermore, partitioning of Ag was observed inside all precipitate phases, viz. G.P. zones, η′ and η. 相似文献
844.
Ebrahim Karkhaneei Mohammad Hasan Zebrajadian Mojtaba Shamsipur 《Journal of inclusion phenomena and macrocyclic chemistry》2001,40(4):309-312
7Li NMR measurements were employed to monitor the stoichiometry andstability of Li+ ion complexes with 12-crown-4 (12C4), 15-crown-5 (15C5), benzo-15-crown-5 (B15C5) l8-crown-6 (18C6), dicyclohexano-18-crown-6 (DC18C6) and dibenzo-18-crown-6 (DB18C6) in binary acetone-nitrobenzene mixtures of varying composition. In all cases studied, the variation of 7Li chemical shift with the crown/Li+ mole ratio indicated the formation of 1:1 complexes. The formation constants of the resulting complexes were evaluated from computer fitting of the mole ratio data to an equation that relates the observed chemical shifts to the formation constant. In all solvent mixtures used, the stabilities of the resulting 1:1 complexes varied in the order15C5 > B15C5 > DC18C6 > 18C6 > 12C4 >DB18C6. It was found that,in the case of all complexes, an increase in the percentage of acetone in thesolvent mixtures significantly decreased the stability of the complexes. 相似文献
845.
Molten salt hydrates proved to be alternative solvents to cellulose. Toinvestigate the reasons for this dissolving ability, information about thesolvent–cellulose interactions is essential. As well as 13CHR NMR, 7Li NMR was used to obtain further insight into thisproblem.After comparing several molten salt hydrates, the 7Li NMR spectrarevealed a smaller shielding of the lithium cation for not dissolving than fordissolving and swelling cellulose systems. In most solvent systems theshieldingat the 7Li nuclei increases with the cellulose concentration. 2D7Li-1H HOESY NMR was successfully applied to verify thepresence of cellobiose, used as a model compound for cellulose, in the firstco-ordination sphere of the lithium cation. 相似文献
846.
Liquid chromatography/mass spectrometry (LC/MS) is now considered to be the most promising analytical method for the determination of biological substances, especially nonvolatile or highly polar substances However, some compounds do not show enough sensitivity in LC/MS and soft ionization methods commonly used in LC/MS, such as electrospray ionization (ESI) and atmospheric pressure chemical ionization (APCI), sometimes do not give satisfactory structural information This report presents an overview 相似文献
847.
1 Introduction Gaschromatography/massspectrometry (GC/MS)andliquidchromatography/massspectrometry (LC/MS) ,representativesofthehyphenatedtechniques ,aresomeofthemostreliableanalyticalmethods ,whicharethesynergisticcombinationoftwopowerfulanalyticaltechniques;… 相似文献
848.
报道了实验室可行、工业生产实用的l-对甲苯磺酸乳酸乙酯产率的分析方法,采用K2CrO4-K2Cr2O7混合指示剂,其最佳配比为K2CrO4:K2Cr2O7=6:1(质量比),体系的最佳pH为5.8,测得l-乳酸乙酯与对甲苯碘酰氯反应制备和的l-对甲苯磺酰乳酸乙酯的产率为94.0%。 相似文献
849.
The total capability of an atom attracting valence electrons can be measured by the sum of ionization energies of valence electron in a ground‐state free atom plus its electron affinity called Total Attracting Energy, TAE = ΣniEi + EA, where, Ei is the ionization energy of the ith valence‐shell electron in a ground‐state free atom, ni is the number of valence‐shell electron bearing energy Ei, and EA is the electron affinity. And the electronegativity χCL is proportional to the average of TAE, AAE = TAEav, divided by Σni, the number of atomic valence‐shell electrons. χCL = 0.1813 TAEav = 0.1813 AAE = 0.1813 TAE/Σni, = 0.1813 (ΣniEI + EA)/Σni. Further, the atomic valence orbital electronegativity can be also obtained from the TAE value of an atom. Some discussions were made on several special aspects such as scale of rare gases, comparisons with Pauling's and Allen's scales, etc. 相似文献
850.
以天然长叶薄荷酮[R-(+)-Pulegone]为起始原料,经过一系列立体选择性化学反应步骤,成功地建立了3个手性中心,从而完成了具有抗艾滋病活性Didemnaketals类似物的关键中间体3,7-二甲基-5,6-二羟基-辛-7-烯醛中间体的合成.发现PCC与三级环氧醇8和9的非对映选择性反应,使得9被完全氧化,而8以93%的产率回收,其de值高达98%. 相似文献