激光器用高频调制射频激励源的实时监测系统

介绍了基于C8051F023单片机的高速数据采集系统的设计,在LABVIEW环境下实现数据处理和分析系统的设计。两者通过串口结合能实现对射频激励源入射和反射信号的电压值、功率值、频率、占空比等参数实时监测。     

利用导波耦合角度实时控制光刻胶光栅掩模的占宽比

研究一种控制多层介质膜上的光刻胶光栅掩模占宽比(线宽与周期之比)的新方法。该方法基于下面的原理:如果某泄漏模在包层中的隐失尾较强,那么它的等效折射率受光刻胶光栅占宽比变化的影响就大,从而可以利用耦合角度来实时控制光栅占宽比。在光栅制作的显影阶段,采用实时监测技术,根据耦合角度和占宽比之间的关系预设入射光角度,在出现共振反常的时刻停止显影来控制占宽比。实验结果表明,固定适当的入射角度可以得到特定的占宽比;改变入射角度,占宽比按照预计的规律变化,因此定性地验证了这种占宽比控制方法的可行性。文中给出了监控装置和具体的实验方法,并讨论了误差来源和影响。     

用太阳光谱测量空气中NO2浓度的方法研究

根据Noxon方法 ,利用NO2 在 430— 45 0nm范围内的吸收特性 ,测量空气中NO2 的浓度 .介绍了一种利用光学差分吸收原理 ,以太阳光为光源 ,二极管阵列为探测器 ,黄山光明顶上的太阳光谱为参考光谱测量大气中NO2 浓度的新光学方法 .     

烟台市区工程地质环境质量标准的制定

笔者提出工程地质环境质量标准的概念 ,并分析了工程地质环境质量标准的制定程序 ,详细研究了烟台市区工程地质环境质量标准制定的效应指标、数学模型 ,并提出了烟台市区工程地质环境质量标准的建议值.     

A Class of Learning/Estimation Algorithms Using Nominal Values: Asymptotic Analysis and Applications

A class of estimation/learning algorithms using stochastic approximation in conjunction with two kernel functions is developed. This algorithm is recursive in form and uses known nominal values and other observed quantities. Its convergence analysis is carried out; the rate of convergence is also evaluated. Applications to a nonlinear chemical engineering system are examined through simulation study. The estimates obtained will be useful in process operation and control, and in on-line monitoring and fault detection.     

凝胶形成动态过程在线监测方法的比较

以醋酸介质中戊二醛（Ｇｌｕ）交联壳聚糖（ＣＳ）水凝胶的形成为例,研究比较了粘度法,电导法,光度法和荧光探针法用于监测凝胶形成动态过程的可行性性和特点,结果表明：粘度法具有简单、直观等优点,但粘度法不能够跟踪凝胶点（ｇｅｌｌｉｎｇｐｏｉｎｔｓ）后体系的进一步变化,旋转粘度法在测定时对体系的扰动不容忽视。电导法和光度法跟踪的是引起凝胶化的交联反应过程,但溶液到凝胶的转化往往发生在交联反应完成之前,因此所得结果未必与宏观观察结果相一致,荧光探针法具有适用面宽,可供选用的探针种类多、方法灵活等特点,对于研究凝胶形成动态过程具有普适性,该法还可用于凝胶性质的研究。     

声化学消解测定环境水样中的化学需氧量

研制了简易、安全的声化学密闭消解器 ,并用于不同环境水样的消化处理。探讨了声频、声强、消化助剂、温度等因素对其化学需氧量测定结果的影响。与K2 Cr2 O7 H2 SO4 回流消解法相比 ,此法大大加快了消解速度 ,少用或不用消化助剂。用于实际水样 (COD 15 0 2 0 0 0mg·L- 1)的分析 ,结果表明 ,标准偏差≤ 6.5 % ,加标回收率为 96% 12 0 % ,较为满意。     

22种水质监测用标准物质的研制

介绍22种水质监测用标准物质的研制过程。结果表明,该22种标准物质的均匀性、稳定性良好,定值准确、可靠、满足实际工作需求。     

A Sensitive Colorimetric Method for the Determination of Arsenic in Environmental and Biological Samples

Results of a thorough study and application of leucocrystal violet for the determination of arsenic in parts per million (ppm) levels in environmental and biological samples is described here. The proposed method is based on the reaction of arsenic with potassium iodate to liberate iodine. The liberated iodine selectively oxidises leucocrystal violet to form crystal violet dye in the presence of sodium hydroxide. The dye formed shows maximum absorbance at 592 nm. The detection limit of arsenic is 0.002 μgmL^?1 and the method obeys Beer's law over the concentration range of 0.1 μg - 1.0 μg of per 25 mL of final solution (0.004–0.04 ppm). The molar absorptivity was found to be 1.49 × 10⁶ L mol^?1 cm^?1. The proposed method was successfully applied for the determination of arsenic in various environmental and biological samples. The results are in good agreement with the standard reported method.     

Development and validation of an HPLC method for the simultaneous determination of clozapine and desmethylclozapine in plasma of schizophrenic patients

Summary A high-performance liquid chromatographic method with amperometric detection has been developed for the determination of levels of clozapine (CLZ) and its active metabolite N-desmethylclozapine (DMC) in human plasma. The analysis was performed on a 5 μm C8 reversed phase column (150×4.6 mm i.d.), with acetonitrile-phosphate buffer (pH 3.5), as the mobile phase. The detection voltage was +800 mV and the cell and column temperature were 50°C. Linear responses were obtained between 2 ng mL⁻¹ and 100 ng mL⁻¹. Absolute recovery for both clozapine and desmethylclozapine exceeded 88% and the detection limit was 1 ng mL⁻¹. Repeatability, intermediate precision and accuracy were satisfactory. The method, which is rapid, sensitive and selective, has been applied to therapeutic drug monitoring in schizophrenic patients following administration of Leponex^? tablets. In 21 patients in steady state at a mean daily clozapine dosage of 358 mg (ranging from 150 to 500 mg day⁻¹), clozapine levels averaged 379 ng mL⁻¹ (ranging from 102 to 818 ng mL⁻¹) and DMC levels averaged 233 ng mL⁻¹ (ranging from 70 to 540 ng mL⁻¹). The method requires only a very small amount of plasma (100 μL), and thus it is suitable for pharmacokinetic studies, as well as for therapeutic drug monitoring.