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101.
离子特异性效应在固-液界面反应中是普遍存在的. 近期研究指出, 在较低电解质浓度的某些体系中, 离子特异性效应可能并非来源于色散力、经典诱导力、离子半径或水合半径的大小等, 而是界面附近强电场中的离子极化作用. 这种作用可使界面附近的吸附态反号离子被强烈极化(高达经典极化的104倍). 强烈极化的结果将导致离子在界面附近受到的库仑力远远超过离子电荷所能产生的库仑力, 这体现在离子的有效电荷将远大于离子的实际电荷. 因此胶体体系中基于这种强极化的离子有效电荷可以用来定量表征离子特异性效应的强度. 本研究在蒙脱石-胡敏酸混合悬液凝聚过程中发现了Na+、K+、Ca2+、Cu2+四种离子的离子特异性效应, 提出了基于激光散射技术测定离子有效电荷的方法, 并成功获得了被强烈极化后的离子有效电荷数值. 实验测得的Na+、K+、Ca2+、Cu2+四种离子的有效电荷值分别为: ZNa(effective)=1.46, ZK(effective)=1.86, ZCa(effective)=3.92, ZCu(effective)=6.48.该结果表明: (1) 离子在强电场中的极化将大大提高离子的有效电荷, 从而极大地增强离子所受的库仑作用力;(2) 离子的电子层数越多, 离子极化越强烈, 离子的有效电荷增加越多. 相似文献
102.
Akinori Ohshita Masaaki Okuhara Chiharu Matsuya Koichi Hata Kazuo Iida 《Mikrochimica acta》2006,155(1-2):225-228
A new electron holographic method is presented to directly visualize pure phase objects such as electromagnetic microfields,
which is achieved by superposition of two kinds of electron holograms. The method is very simple and is twice as sensitive
as the conventional double-exposure electron holography and the four-electron-wave interference. Using this technique, an
electric field around a charged latex sphere and a magnetic field around a barium ferrite particle have been directly observed. 相似文献
103.
针对固体火箭发动机环境载荷的诸多不确定性,提出了环境载荷FHW量化评估算法.对比分析了火箭发动机的典型环境条件及其影响,采用熵值法确定了指标权重,基于FHW方法建立了火箭发动机的环境载荷评估模型,根据环境因素的分布特征给出评估指标的隶属函数,并获取其相应的灰色关联系数.算例验证了不同环境载荷因素对火箭发动机的影响程度,结果表明FHW评估策略和算法简单易行、精度高,在装备环境载荷量化评估中具有参考和应用价值. 相似文献
104.
HL-2M 装置供电系统研制 总被引:2,自引:0,他引:2
为满足 HL-2M 装置的供电需求,须配套建设相应的供电系统。通过仿真计算 HL-2M 装置的总体供 电需求,考虑到 HL-2A 装置现有的供电系统设备,提出了兼顾 HL-2A 和 HL-2M 装置供电需求的总体配置方案。介绍了国内首台 300MVA 立式交流脉冲发电机组、磁体电源、高压电源和电源控制系统的研制情况。 相似文献
105.
A. Hussain C.W. Ahn H.J. Lee I.W. Kim J.S. Lee S.J. Jeong S.K. Rout 《Current Applied Physics》2010,10(1):305-310
We have fabricated lead-free Bi0.5(Na0.75K0.25)0.5TiO3 (BNKT) ceramics by a conventional process (CP) and reactive templated grain growth (RTGG) methods. The effect of grain orientation on structure, dielectric, complex impedance and electrical properties was investigated. The phase formation and grain morphology of BNKT ceramics were examined by X-ray diffraction (XRD) and scanning electron microscope (SEM), respectively. High dielectric constant and low dielectric loss was observed for grain oriented (textured) BNKT ceramics. Complex impedance, temperature dependent ac and dc conductivity were performed to explore the conduction behavior of the prepared BNKT ceramics. 相似文献
106.
The Onsager reciprocity relation and generalized efficiency of a thermal Brownian motor 总被引:1,自引:0,他引:1 下载免费PDF全文
Based on a general model of Brownian motors, the Onsager
coefficients and generalized efficiency of a thermal Brownian motor
are calculated analytically. It is found that the Onsager
reciprocity relation holds and the Onsager coefficients are not
affected by the kinetic energy change due to the particle's motion.
Only when the heat leak in the system is negligible can the
determinant of the Onsager matrix vanish. Moreover, the influence of
the main parameters characterizing the model on the generalized
efficiency of the Brownian motor is discussed in detail. The
characteristic curves of the generalized efficiency varying with
these parameters are presented, and the maximum generalized
efficiency and the corresponding optimum parameters are determined.
The results obtained here are of general significance. They are used
to analyze the performance characteristics of the Brownian motors
operating in the three interesting cases with zero heat leak,
zero average drift velocity or a linear response relation, so that
some important conclusions in current references are directly
included in some limit cases of the present paper. 相似文献
107.
Conduction stability of high-density polyethylene/carbon black (HDPE/CB) composites with a CB volume fraction slightly above the percolation threshold is studied in relation to electric field action at various ambient temperatures below the melting point of HDPE. It is found that resistance of the composites shows considerable changes after the electric field is switched off. Influence of irradiation crosslinking of HDPE on the conduction stability is also discussed. 相似文献
108.
109.
110.
A novel method of computing the nonlinear differential equations relating to the transient behaviour of an induction motor using a polynomial series, is presented. The stator and rotor currents and the angle of rotation are expressed as polynomial series dependent on time. These are then substituted into the differential equations of the induction motor to compute the polynomial coefficients and, consequently, the transient quantities. Since the equations are nonlinear, the computations are carried out using the step-by-step method. The stator and rotor currents, speed and torque are calculated for acceleration and braking conditions. The results are compared both analytically and experimentally. 相似文献