全文获取类型
收费全文 | 5505篇 |
免费 | 429篇 |
国内免费 | 300篇 |
专业分类
化学 | 1337篇 |
晶体学 | 16篇 |
力学 | 1445篇 |
综合类 | 17篇 |
数学 | 1326篇 |
物理学 | 2093篇 |
出版年
2024年 | 10篇 |
2023年 | 104篇 |
2022年 | 72篇 |
2021年 | 84篇 |
2020年 | 160篇 |
2019年 | 113篇 |
2018年 | 104篇 |
2017年 | 169篇 |
2016年 | 184篇 |
2015年 | 164篇 |
2014年 | 302篇 |
2013年 | 395篇 |
2012年 | 277篇 |
2011年 | 360篇 |
2010年 | 260篇 |
2009年 | 409篇 |
2008年 | 401篇 |
2007年 | 367篇 |
2006年 | 309篇 |
2005年 | 247篇 |
2004年 | 232篇 |
2003年 | 198篇 |
2002年 | 174篇 |
2001年 | 134篇 |
2000年 | 156篇 |
1999年 | 96篇 |
1998年 | 103篇 |
1997年 | 84篇 |
1996年 | 67篇 |
1995年 | 51篇 |
1994年 | 59篇 |
1993年 | 57篇 |
1992年 | 43篇 |
1991年 | 35篇 |
1990年 | 29篇 |
1989年 | 34篇 |
1988年 | 29篇 |
1987年 | 18篇 |
1986年 | 20篇 |
1985年 | 23篇 |
1984年 | 18篇 |
1983年 | 9篇 |
1982年 | 16篇 |
1981年 | 17篇 |
1980年 | 10篇 |
1979年 | 12篇 |
1978年 | 6篇 |
1977年 | 5篇 |
1976年 | 3篇 |
1971年 | 2篇 |
排序方式: 共有6234条查询结果,搜索用时 15 毫秒
41.
We have studied on the solubilization of single-walled carbon nanotubes (SW-CNTs) into aqueous and organic media by the use of a variety of nanometer size-controlled fluorinated self-assemblies, which were formed by the aggregations of end-capped fluoroalkyl segments in fluoroalkyl end-capped acrylic acid oligomers [RF-(ACA)n-RF], N,N-dimethylacrylamide oligomers [RF-(DMAA)n-RF], acryloylmorpholine oligomers [RF-(ACMO)n-RF], and N-(1,1-dimethyl-3-oxobutyl)acrylamide oligomers [RF-(DOBAA)n-RF]. Fluorinated self assemblies formed in organic media (colorless solutions) could solubilize SW-CNTs into organic media to afford the transparent pale yellow solutions. The dynamic light scattering measurements showed that the size of fluorinated self-assemblies increased after the solubilization of SW-CNTs into organic media. It was suggested that the solubilization of SW-CNTs into organic media is due to the encapsulation of SW-CNTs into fluorinated assemblies. Fluorinated assemblies were also able to solubilize SW-CNTs into water to give the transparent gray solutions. Among a variety of fluorinated assemblies, fluorinated assemblies formed by RF-(ACMO)n-RF [RF = CF(CF3)OC6F13] oligomer was more effective for the solubilization of SW-CNTs into both aqueous and organic media. Contact angle measurements of dodecane and the fluorescence spectra for poly(methyl methacrylate) cast film modified by fluorinated self-assemblies—SW-CNTs complexes showed that SW-CNTs are dispersed above the PMMA surface. 相似文献
42.
磁化作用对汽油动态挥发性影响的研究 总被引:1,自引:0,他引:1
用热重(TG)分析和自行设计的原位动态挥发实验,研究了在不同条件下汽油的挥发性,结果表明,磁化空气或磁化汽油都可提高汽油的挥发性,而汽油和空气共同磁化,可更大幅度地提高汽油的挥发性。 相似文献
43.
44.
Synthesis and inversion barriers of undeca- and dodeca-substituted saddle shaped porphyrin complexes
Synthesis and barriers to inversion of a series of highly saddle shaped complexes are reported. The ΔG≠ has decreased by 8 kJ mol−1 at 243 K when the meso phenyl groups are replaced by bulkier 2,6-dichlorophenyl groups, and by 17 kJ mol−1 when one of the peripheral ethyl groups is removed. 相似文献
45.
Summary Dynamic headspace and simultaneous steam distillation-extraction techniques were used to isolate volatile components of Parmesan cheese. Identification of the substances was carried out by GC and GC-MS; 110 compounds were identified in the samples obtained using the headspace technique, 105 in the extracts; among them, about 50 compounds were isolated with both procedures. Mass spectral data showed evidence for a number of newly reported compounds such as 3-(methylthio)propanal, -tetradecalactone, 9-tetra-decenoic and 9-hexadecenoic acids. Mass spectra of some compounds are discussed and a comparison between the results obtained with the two sampling methods is given. 相似文献
46.
A. V. Savilov 《International Journal of Infrared and Millimeter Waves》1994,15(11):1819-1828
The negative-mass (space-charge) instability is studied within the model of a flat thin electron beam moving along the stationary uniform magnetic field in the case of nonsymmetrical perturbations. It is shown that due to the phenomenon of "phase mixing" of electron bunches the instability increments are small for perturbations with spatial scales smaller than the Larmor diameter. 相似文献
47.
48.
A novel extraction method, namely dynamic ultrasound-assisted extraction, is investigated. This technique is efficient with respect to both time and solvent consumption because it utilizes ultrasonic energy in dynamic mode during extraction. Polyphenols (chlorogenic acid, esculetin, rutin, scopoletin, and quercitrin) are extracted from a tobacco (Nicotina tobaccum L.) sample for 10 min with 6 mL of solvent. Fresh solvent is continuously pumped through the sample, with which the analytes can be rapidly extracted, and the possibility of degradation efficiently avoided. Methanol involving 0.5% w/v ascorbic acid was used as extraction solvent; optimal flow rate and extraction time were investigated. The extract was cleaned up by C18 disposable cartridge. The spiked and nonspiked tobacco samples were used for the evaluation of the proposed method. Recoveries obtained were varied from 96 to 108% and RSDs from 2.0 to 4.6%. This extraction technique was revealed to recover larger amounts of polyphenols from tobacco, compared to the static ultrasound-assisted extraction method. 相似文献
49.
M. Baru A. Danilov I. Vagenina E. Gorbunova S. Moshnikov L. Mustaeva V. Cherskii 《Chromatographia》1997,45(1):351-354
Summary The design of new dynamic, axial-compression columns with a system for continous packed bed adjustment and monitoring of the
floating adapter position is described. The columns are meant for liquid chromatography at low pressures (up to 8 bar) in
aqueous and organic media with stationary phases of all types. The columns have adapter position pickups for continuous automatic
monitoring of the bed height (original “swellographic” monitoring). The column described with gas pressurisation was tested
with soft Sephadex G-10 and G-25. In spite of the reduction in external porosity there was no dramatic increase in back-pressure.
The column proved to provide long-term stability of the packed bed and improvement in resolution.
Presented at the 21st ISC held in Stuttgart, Germany, 15th–20th September, 1996 相似文献
50.
Using a very simple trial function and unperturbed electron densities calculated by a new procedure, the frequency-dependent dipole polarizability () of Ne, Ar, Kr and Xe has been calculated in the range 0 0.45 a.u., by a Karplus-Kolker-type variation-perturbation method. Results progressively worsen for larger systems so that, for Xe, (0) is only 75% of the experimental value. Probable reasons for this are discussed. 相似文献