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81.
82.
Liu-Niu Tong Yi-Chao Wang Xian-Mei He Huai-Bin Han Ai-Lin Xia Jin-Lian Hu 《Journal of magnetism and magnetic materials》2012
We explore the effects of hydrogen annealing on the room temperature ferromagnetism and optical properties of Cr-doped ZnO nanoparticles synthesized by the sol-gel method. X-ray diffraction and x-ray photoelectron spectroscopy data show evidence that Cr has been incorporated into the wurtzite ZnO lattice as Cr2+ ions substituting for Zn2+ ions without any detectable secondary phase in as-synthesized Zn0.97Cr0.03O nanopowders. The room temperature magnetization measurements reveal a large enhancement of saturation magnetization Ms as well as an increase of coercivity of H2-annealed Zn0.97Cr0.03O:H samples. It is found that the field-cooled magnetization curves as a function of temperature from 40 to 400 K can be well fitted by a combination of a standard Bloch spin-wave model and Curie–Weiss law. The values of the fitted parameters of the ferromagnetic exchange interaction constant a and the Curie constant C of H2-annealed Zn0.97Cr0.03O:H nanoparticles are almost doubled upon H2-annealing. Photoluminescence measurements show evidence that the shallow donor defect or/and defect complexes such as hydrogen occupying an oxygen vacancy Ho may play an important role in the origin of H2-annealing induced enhancement of ferromagnetism in Cr-H codoped ZnO nanoparticles. 相似文献
83.
The head-on collision of a planar shock wave with a dust-air suspension is studied numerically. In this study the suspension
is placed inside a conduit adjacent to its rigid end-wall. It is shown that as a result of this collision two different types
of transmitted shock waves are possible, depending on the strength of the incident shock wave and the dust loading ratio in
the suspension. One possibility is a partially dispersed shock wave, the other is a compression wave. The flow fields resulting
in these two options are investigated. It is shown that in both cases, at late times after the head-on reflection of the transmitted
shock wave from the conduit end-wall a negative flow (away from the end-wall) is evident. The observed flow behavior may suggest
a kind of dust particle lifting mechanism that could shed new light on the complex phenomenon of dust entrainment behind sliding
shock waves.
相似文献
84.
The complete solution for the pressure and the velocity field up to O(De) of a dilute suspension of neutrally buoyant, non-Brownian rigid spheres suspended in an unbounded, weakly viscoelastic matrix fluid, where is the solid volume fraction and De is the Deborah number of the matrix fluid, is presented. The spheres are subjected to an arbitrary linear velocity profile at infinity. The analytical solution is used for the prediction of the bulk stress, and specifically for the calculation of the first and the second normal stress differences in simple shear and uniaxial elongational flows. A comparison of the results with available values reported in the literature is also offered. The final expressions for the bulk normal stress differences in shear and uniaxial elongational flow fully agree with those reported earlier by Greco et al., J. Non-Newton. Fluid Mech., 147 (2007) 1–10. 相似文献
85.
Nonequilibrium stretching dynamics of dilute and entangled linear polymers in extensional flow 总被引:1,自引:0,他引:1
We propose an extension of the FENE-CR model for dilute polymer solutions [M.D. Chilcott, J.M. Rallison, Creeping flow of dilute polymer solutions past cylinders and spheres, J. Non-Newtonian Fluid Mech. 29 (1988) 382–432] and the Rouse-CCR tube model for linear entangled polymers [A.E. Likhtman, R.S. Graham, Simple constitutive equation for linear polymer melts derived from molecular theory: Rolie–Poly equation, J. Non-Newtonian Fluid Mech. 114 (2003) 1–12], to describe the nonequilibrium stretching dynamics of polymer chains in strong extensional flows. The resulting models, designed to capture the progressive changes in the average internal structure (kinked state) of the polymer chain, include an ‘effective’ maximum contour length that depends on local flow dynamics. The rheological behavior of the modified models is compared with various results already published in the literature for entangled polystyrene solutions, and for the Kramers chain model (dilute polymer solutions). It is shown that the FENE-CR model with an ‘effective’ maximum contour length is able to describe correctly the hysteretic behavior in stress versus birefringence in start-up of uniaxial extensional flow and subsequent relaxation also observed and computed by Doyle et al. [P.S. Doyle, E.S.G. Shaqfeh, G.H. McKinley, S.H. Spiegelberg, Relaxation of dilute polymer solutions following extensional flow, J. Non-Newtonian Fluid Mech. 76 (1998) 79–110] and Li and Larson [L. Li, R.G. Larson, Excluded volume effects on the birefringence and stress of dilute polymer solutions in extensional flow, Rheol. Acta 39 (2000) 419–427] using Brownian dynamics simulations of bead–spring model. The Rolie–Poly model with an ‘effective’ maximum contour length exhibits a less pronounced hysteretic behavior in stress versus birefringence in start-up of uniaxial extensional flow and subsequent relaxation. 相似文献
86.
The dynamics of homogeneous, isotropic turbulence seeded with finite sized particles or bubbles is investigated in a series of numerical simulations, using the force-coupling method for the particle phase and low wavenumber forcing of the flow to sustain the turbulence. Results are given on the modulation of the turbulence due to massless bubbles, neutrally buoyant particles and inertial particles of specific density 1.4 at volumetric concentrations of 6%. Buoyancy forces due to gravity are excluded to emphasize finite size and inertial effects for the bubbles or particles and their interactions with the turbulence. Besides observing the classical entrapment of bubbles and the expulsion of inertial particles by vortex structures, we analyze the Lagrangian statistics for the velocity and acceleration of the dispersed phase. The turbulent fluctuations are damped at mid-range wavenumbers by the bubbles or particles while the small-scale kinetic energy is significantly enhanced. Unexpectedly, the modulation of turbulence depends only slightly on the dispersion characteristics (bubble entrapment in vortices or inertial sweeping of the solid particles) but is closely related to the stresslet component (finite size effect) of the flow disturbances. The pivoting wavenumber characterizing the transition from damped to enhanced energy content is shown to vary with the size of the bubbles or particles. The spectrum for the energy transfer by the particle phase is examined and the possibility of representing this, at large scales, through an additional effective viscosity is discussed. 相似文献
87.
Discrete dislocations in graphene 总被引:1,自引:0,他引:1
In this work, we present an application of the theory of discrete dislocations of Ariza and Ortiz (2005) to the analysis of dislocations in graphene. Specifically, we discuss the specialization of the theory to graphene and its further specialization to the force-constant model of Aizawa et al. (1990). The ability of the discrete-dislocation theory to predict dislocation core structures and energies is critically assessed for periodic arrangements of dislocation dipoles and quadrupoles. We show that, with the aid of the discrete Fourier transform, those problems are amenable to exact solution within the discrete-dislocation theory, which confers the theory a distinct advantage over conventional atomistic models. The discrete dislocations exhibit 5-7 ring core structures that are consistent with observation and result in dislocation energies that fall within the range of prediction of other models. The asymptotic behavior of dilute distributions of dislocations is characterized analytically in terms of a discrete prelogarithmic energy tensor. Explicit expressions for this discrete prelogarithmic energy tensor are provided up to quadratures. 相似文献
88.
Lattice-Boltzmann Simulations of Particle-Fluid Suspensions 总被引:10,自引:0,他引:10
This paper reviews applications of the lattice-Boltzmann method to simulations of particle-fluid suspensions. We first summarize the available simulation methods for colloidal suspensions together with some of the important applications of these methods, and then describe results from lattice-gas and lattice-Boltzmann simulations in more detail. The remainder of the paper is an update of previously published work,(69, 70) taking into account recent research by ourselves and other groups. We describe a lattice-Boltzmann model that can take proper account of density fluctuations in the fluid, which may be important in describing the short-time dynamics of colloidal particles. We then derive macro-dynamical equations for a collision operator with separate shear and bulk viscosities, via the usual multi-time-scale expansion. A careful examination of the second-order equations shows that inclusion of an external force, such as a pressure gradient, requires terms that depend on the eigenvalues of the collision operator. Alternatively, the momentum density must be redefined to include a contribution from the external force. Next, we summarize recent innovations and give a few numerical examples to illustrate critical issues. Finally, we derive the equations for a lattice-Boltzmann model that includes transverse and longitudinal fluctuations in momentum. The model leads to a discrete version of the Green–Kubo relations for the shear and bulk viscosity, which agree with the viscosities obtained from the macro-dynamical analysis. We believe that inclusion of longitudinal fluctuations will improve the equipartition of energy in lattice-Boltzmann simulations of colloidal suspensions. 相似文献
89.
Julien Férec Marie-Claude Heuzey José Pérez-González Lourdes de Vargas Gilles Ausias Pierre J. Carreau 《Rheologica Acta》2009,48(1):59-72
The behavior of short glass fiber–polypropylene suspensions in extensional flow was investigated using three different commercial
instruments: the SER wind-up drums geometry (Extensional Rheology System) with a strain-controlled rotational rheometer, a
Meissner-type rheometer (RME), and the Rheotens. Results from uniaxial tensile testing have been compared with data previously
obtained using a planar slit die with a hyperbolic entrance. The effect of three initial fiber orientations was investigated:
planar random, fully aligned in the stretching flow direction and perpendicular to it. The elongational viscosity increased
with fiber content and was larger for fibers initially oriented in the stretching direction. The behavior at low elongational
rates showed differences among the various experimental setups, which are partly explained by preshearing history and nonhomogenous
strain rates. However, at moderate and high rates, the results are comparable, and the behavior is strain thinning. Finally,
a new constitutive equation for fibers suspended into a fluid obeying the Carreau model is used to predict the elongational
viscosity, and the predictions are in good agreement with the experimental data. 相似文献
90.
A model relating the translational and rotational transport of orientation distribution function (ODF) of fibers to the gradient of mean ODF and the dispersion coefficients is proposed to derive the mean equation for the ODE Then the ODF of fibers is predicted by numerically solving the mean equation for the ODF together with the equations of turbulent boundary layer flow. Finally the shear stress and first normal stress difference of fiber suspensions are obtained. The results, some of which agree with the available relevant experimental data, show that the most fibers tend to orient to the flow direction. The fiber aspect ratio and Reynolds number have significant and negligible effects on the orientation dis- tribution of fibers, respectively. The additional normal stress due to the presence of fibers is anisotropic. The shear stress of fiber suspension is larger than that of Newtonian solvent, and the first normal stress difference is much less than the shear stress. Both the additional shear stress and the first normal stress difference increase with increasing the fiber concentration and decreasing fiber aspect ratio. 相似文献