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11.
将反射光谱和吸收光谱用于黄铁矿处理酸性重金属废水的研究,探讨了黄铁矿的表面反应以及黄铁矿与重金属的相互作用。漫反射红外光谱分析证实,在处理废水过程中,黄铁矿中表面羟基与重金属离子发生反应;并通过考察黄铁矿中碳酸盐,合理解释了黄铁矿处理酸性重金属废水后的溶液自然均趋于中性(pH 7)的现象。可见区的反射光谱用于表征处理过程中的黄铁矿的颗粒及比表面变化,解释了黄铁矿在重复使用时其活性反而增强的原因。吸收光谱及XPS表征表明,黄铁矿处理含Cr(Ⅵ)废水,是一个由Cr(Ⅵ)到Cr3+再到Cr(OH)3的吸附沉淀过程。 相似文献
12.
13.
An investigation into the rapid detection of mycotoxin-producing fungi on corn by two mid-infrared spectroscopic techniques was undertaken. Corn samples from a single genotype (RWA2, blanks, and contaminated with Fusarium graminearum) were ground, sieved and, after appropriate sample preparation, subjected to mid-infrared spectroscopy using two different accessories (diffuse reflection and attenuated total reflection). The measured spectra were evaluated with principal component analysis (PCA) and the blank and contaminated samples were classified by cluster analysis. Reference data for fungal metabolites were obtained with conventional methods. After extraction and clean-up, each sample was analyzed for the toxin deoxynivalenol (DON) by gas chromatography with electron capture detection (GC-ECD) and ergosterol (a parameter for the total fungal biomass) by high-performance liquid chromatography with diode array detection (HPLC-DAD). The concentration ranges for contaminated samples were 880–3600 g/kg for ergosterol and 300–2600 g/kg for DON. Classification efficiency was 100% for ATR spectra. DR spectra did not show as obvious a clustering of contaminated and blank samples. Results and trends were also observed in single spectra plots. Quantification using a PLS1 regression algorithm showed good correlation with DON reference data, but a rather high standard error of prediction (SEP) with 600 g/kg (DR) and 490 g/kg (ATR), respectively, for ergosterol. Comparing measurement procedures and results showed advantages for the ATR technique, mainly owing to its ease of use and the easier interpretation of results that were better with respect to classification and quantification. 相似文献
14.
M. Vatasescu F. Masnou-Seeuws 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,21(2):191-204
The paper contains a time-dependent investigation of the tunneling effect observed in the photoassociation spectrum of Cs2 and attributed to the 0g
-(6s, 6p
3/2) double well. When by photoassociation of two cold cesium atoms a vibrational level of the outer well is populated, tunneling
is an efficient mechanism for transferring the population to the inner well (R < 15a
0), where spontaneous emission may lead to formation of cold molecules in low vibrational levels of the a
3Σ+
u(6s, 6s) electronic state. This tunneling effect is analyzed by wavepackets propagation, first considering the double well potential
alone, and following a packet made by a superposition of states initially located at large distances. Characteristic times
for the vibration dynamics, corresponding to a beating phenomenon between the two wells, to partial “revival” at large distances,
and to maxima in the population localized in the inner well are reported and discussed. Second, we simulate the two-channels
a
3Σ+
u(6s, 6s)↦0g
-(6s, 6p
3/2) photoassociation at detunings around 2.9 cm-1: the inner well can be populated either by the excitation of a vibrational level of the external well (resonant excitation),
or by tuning the photoassociation laser at the energy of the inner well level which displays tunneling (“off-resonance excitation”).
In the first case the photoassociation is efficient, while the tunneling probability is small; in the second, the tunneling
probability is large, so that despite the poor efficiency of the photoassociation process, more population can be transferred
to the inner well. This second choice is shown to be very sensitive to the laser intensity, which could be used to control
the population of the inner well and hence the formation of ultracold molecules in low vibrational levels.
Received 19 April 2002 Published online 1st October 2002
RID="a"
ID="a"e-mail: francoise.masnou@lac.u-psud.fr 相似文献
15.
Diffuse ultrasonic waves for structural health monitoring offer the advantages of simplicity of signal generation and reception, sensitivity to damage, and large area coverage; however, there are the serious disadvantages of no accepted methodology for analyzing the complex recorded signals and sensitivity to environmental changes such as temperature and surface conditions. Presented here is a methodology for applying diffuse ultrasonic waves to the problem of detecting structural damage in the presence of unmeasured temperature changes. This methodology is based upon the prediction and observation that the first order effect of a temperature change on a diffuse ultrasonic wave is a time dilation or compression. A multi-step procedure is implemented to (1) record a set of baseline waveforms from the undamaged specimen at temperatures spanning the expected operating range, (2) select a waveform from the baseline set whose temperature is the closest to that of a subsequently measured signal, (3) adjust this baseline waveform to best match the signal, and (4) calculate an error parameter between the signal and the adjusted waveform and compare this parameter to a threshold to determine the structural status. This procedure is applied to experimental data from aluminum plate specimens with artificial flaws. Probability of detection and the minimum flaw size detected are presented as a function of the size of the baseline waveform set. It is shown that a probability of detection of over 95% can be achieved with a small number of baseline waveforms. 相似文献
16.
A spectrophotometer system for spectral characterization of materials in the infrared has been built around a bench-top Fourier transform instrument. Its capabilities include the measurement of directional-hemispherical reflectance from 1 to 18 μm. The spectral reflectance measurement is performed with an integrating sphere with an incidence angle of 8°. Both relative and absolute measurements can be made. Several methods can be used to determine the absolute value of the directional-hemispherical reflectance of samples. The primary method used is independent of the integrating sphere theory and the requisite assumptions associated with its use. The calibration of a standard reference material (SRM) is described. This SRM has a reflectance value near 0.9 over the complete calibration range 2–18 μm. As part of the calibration procedure the spatial uniformity of the sphere throughput and the bi-directional reflectance distribution function (BRDF) of the SRM material are evaluated. 相似文献
17.
Alexandra Fidalgo Tessy M. Lopez Laura M. Ilharco 《Journal of Sol-Gel Science and Technology》2009,49(3):320-328
Wet sol–gel silica matrices produced under different hydrolysis conditions were used as delivery devices to the active principle
of an antiepileptic drug (phenytoin sodium), encapsulated during the condensation stage. Post-incorporation into dry silica
powder was an alternative loading procedure. It was proven by infrared spectroscopy that neither the silica network nor the
drug loose integrity by encapsulation. The kinetics of in vitro drug release was studied at 37 °C, to water and to artificial
cerebrospinal fluid (ACSF). Emphasis has been given to the release to ACSF under dynamic conditions (with fluid renovation,
emulating what occurs in the brain). Different delivery regimes were identified and correlated with the loading method and
the matrix structure. Matrices with lower total porosity and smaller average pore size proved to be better for a long term
release. Renovation of ACSF is relevant to assure a constant concentration of phenytoin in the vicinity of the device. 相似文献
18.
The purpose of this Note is to propose new diffusive capillary models of Korteweg type and discuss their mathematical properties. More precisely, we introduce viscous models which provide some additional information on the behavior of the density close to vacuum. We actually prove that if some compatibility conditions between diffusion and capillarity are satisfied, some extra regularity information on a quantity involving the density is available. We obtain a non-trivial equality deduced from the special structure of the momentum equation. This Note generalizes to some extent the authors' previous works on the Korteweg model (with constant capillary coefficient) and on the shallow water equation. To cite this article: D. Bresch, B. Desjardins, C. R. Mecanique 332 (2004). 相似文献
19.
The Optical Technology Division of NIST has developed a new instrument for measuring ISO standard visual diffuse transmission densities using the diffuse influx mode. This instrument is used to calibrate both X-ray and photographic film step tablet Standard Reference Materials. The design, characterization, and operation of the instrument are detailed. The instrument was fully characterized both to verify compliance with the applicable international standards and to determine the combined uncertainty in transmission density associated with the calibrations. Results from comparisons with other laboratories are also presented. 相似文献
20.
Y. Kimura 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2006,38(1):175-184
In a magnetic field, Cs2 molecules were excited from the ground X1Σ+g(vX=0,JX=55) level to the D 1Σ+u(v=46,J=54) level by dissociation laser light linearly polarized parallel to the field, for which the magnetic sublevels were
degenerated and thus all the transitions between them were simultaneously stimulated. Probe laser light excited the dissociated
Cs 6p2P3/2 atomic fragments to 6p2D3/2 level and the resultant 6p2P1/2 - 6d2D3/2 emission was detected as the function of the wavelength of the probe light. The populations of the 6p2P3/2,mj magnetic sublevels were determined from the relative strengths of the
6p2P3/2,mj - 6d2D3/2,m'j
transitions induced by the probe light. Non-zero orientation O0 was found in the ensemble of dissociated Cs
6p2P3/2
atomic fragments. The orientation O0 increased as the magnetic field strength increased. It was demonstrated both experimentally and theoretically that the orientation
O0 was induced through the interference in the excitation and dissociation paths in the presence of an external magnetic field,
even when all degenerated transitions between the magnetic sublevels of the molecules are simultaneously excited by the light
linearly polarized parallel to the field. 相似文献