首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   5896篇
  免费   459篇
  国内免费   603篇
化学   755篇
晶体学   15篇
力学   741篇
综合类   87篇
数学   4168篇
物理学   1192篇
  2024年   14篇
  2023年   74篇
  2022年   155篇
  2021年   128篇
  2020年   193篇
  2019年   176篇
  2018年   160篇
  2017年   191篇
  2016年   180篇
  2015年   135篇
  2014年   228篇
  2013年   443篇
  2012年   276篇
  2011年   354篇
  2010年   301篇
  2009年   458篇
  2008年   421篇
  2007年   399篇
  2006年   354篇
  2005年   327篇
  2004年   240篇
  2003年   235篇
  2002年   203篇
  2001年   161篇
  2000年   172篇
  1999年   158篇
  1998年   177篇
  1997年   128篇
  1996年   100篇
  1995年   53篇
  1994年   51篇
  1993年   39篇
  1992年   43篇
  1991年   32篇
  1990年   22篇
  1989年   20篇
  1988年   22篇
  1987年   19篇
  1986年   17篇
  1985年   12篇
  1984年   18篇
  1983年   5篇
  1982年   10篇
  1981年   10篇
  1980年   9篇
  1979年   9篇
  1978年   10篇
  1975年   2篇
  1974年   3篇
  1972年   3篇
排序方式: 共有6958条查询结果,搜索用时 15 毫秒
991.
This paper is concerned with the numerical simulation of the flow structure around a square cylinder in a uniform shear flow. The calculations were conducted by solving the unsteady 2D Navier–Stokes equations with a finite difference method. The effect of the shear parameter K of the approaching flow on the vortex-shedding Strouhal number and the force coefficients acting on the square cylinder is investigated in the range K=0·0–0·25 at various Reynolds numbers from 500 to 1500. The computational results are compared with some existing experimental data and previous studies. The effect of shear rate on the Strouhal number and the force acting on the cylinder has a tendency to reduce the oscillation. The Strouhal number, mean drag and amplitude of the fluctuating force tend to decrease as the shear rate increases, but show no significant change at low shear rate. Increasing the Reynolds number decreases the Strouhal number and increases the force acting on the cylinder. At high shear rate the shedding frequencies of the fluctuating drag and lift coefficients are identical. © 1997 John Wiley & Sons, Ltd.  相似文献   
992.
We show for which (d,n) ∈ Z×N there exists a smooth self-map f:S2S2 so that deg(f)=d and Fix(fn) is a point.  相似文献   
993.
A computational study is performed on two-dimensional mixed convection in an annulus between a horizontal outer cylinder and a heated, rotating, eccentric inner cylinder. The computation has been done using a non-orthogonal grid and a fully collocated finite volume procedure. Solutions are iterated to convergence through a pressure correction scheme and the convection is treated by Van Leer's MUSCL scheme. The numerical procedure adopted here can easily eliminate the ‘Numerical leakage’ phenomenon of the mixed convection problem whereby strong buoyancy and centrifugal effects are encountered in the case of a highly eccentric annulus. Numerical results have been obtained for Rayleigh number Ra ranging from 7×103 to 107, Reynolds number Re from 0 to 1200 and Prandtl number Pr from 0.01 to 7. The mixed rotation parameter σ (=Ra/PrRe2) varies from ∞ (pure natural convection) to 0.01 with various eccentricities ε. The computational results are in good agreement with previous works which show that the mixed convection heat transfer characteristics in the annulus are significantly affected by σ and ε. The results indicate that the mean Nusselt number Nu increases with increasing Ra or Pr but decreases with increasing Re. In the case of a highly eccentric annulus the conduction effect becomes predominant in the throat gap. Hence the crucial phenomenon on whereby Nu first decreases and then increases can be found with increasing eccentricity. © 1998 John Wiley & Sons, Ltd.  相似文献   
994.
The new monomer, 3,6‐endo‐methylene‐1,2,3,6‐tetrahydrophthalimidoethanoyl‐5‐fluorouracil (ETEFU), was synthesized from 5‐fluorouracil (5‐FU) and 3,6‐endo‐methylene‐1,2,3,6‐tetrahydophthalimidoethanoyl chloride (ETEC). Its homopolymer and copolymers with acrylic acid (AA) and vinyl acetate (VAc) were prepared by photopolymerization reactions using 2,2‐dimethoxy‐2‐phenylacetophenone (DMP) as the photoinitiator. The synthesized ETEFU and polymers were identified by FT‐IR, 1H‐NMR, and 13C‐NMR spectra. The contents of ETEFU units in poly(ETEFU‐co‐AA) and poly(ETEFU‐co‐VAc) were 20 and 17 mol%, respectively. The number‐average molecular weights of the synthesized polymers determined by gel permeation chromatography (GPC) were 4,600 to 10,700 g mol−1. In vitro cytotoxicities of samples were evaluated with cancer cell lines [mouse mammary carcinoma (FM3A), mouse leukemia (P388), and human histiocytic lymphoma (U937)] and a normal cell line [mouse liver cells (AC2F)]. Cytotoxicities of 5‐FU and synthesized samples against the cancer cell lines were ranked as follows: ETEFU > poly(ETEFU) > 5‐FU > poly(ETEFU‐co‐AA) > poly(ETEFU‐co‐VAc). The in vivo antitumor activities of poly(ETEFU) and poly(ETEFU‐co‐AA) against Balb/C mice bearing the sarcoma 180 tumor cells were greater than those of 5‐FU at all doses except for the activity of poly(ETEFU) at 0.8 mg/kg. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 1589–1595, 1999  相似文献   
995.
若干图的强染色   总被引:1,自引:0,他引:1  
图 G(V,E)的一正常 k-染色 σ称为 G(V,E)的 - k-强染色当且仅当对任何两个不同顶点 u和 v,只要d(u,v)≤ 2 ,则 u、v染不同颜色 (这里 d(u,v)表示 u,v之间的距离 ) ,并称 xs(G) =min{ k|存在 G的 - k-强染色 }为 G的强色数 ,本文得到 θ-图 ,Cm,n图 ,Halin图的强色数 xs(G)  相似文献   
996.
The electrolytes for lithium metal batteries (LMBs) are plagued by a low Li+ transference number (T+) of conventional lithium salts and inability to form a stable solid electrolyte interphase (SEI). Here, we synthesized a self-folded lithium salt, lithium 2-[2-(2-methoxy ethoxy)ethoxy]ethanesulfonyl(trifluoromethanesulfonyl) imide (LiETFSI), and comparatively studied with its structure analogue, lithium 1,1,1-trifluoro-N-[2-[2-(2-methoxyethoxy)ethoxy)]ethyl]methanesulfonamide (LiFEA). The special anion chemistry imparts the following new characteristics: i) In both LiFEA and LiETFSI, the ethylene oxide moiety efficiently captures Li+, resulting in a self-folded structure and high T+ around 0.8. ii) For LiFEA, a Li−N bond (2.069 Å) is revealed by single crystal X-ray diffraction, indicating that the FEA anion possesses a high donor number (DN) and thus an intensive interphase “self-cleaning” function for an ultra-thin and compact SEI. iii) Starting from LiFEA, an electron-withdrawing sulfone group is introduced near the N atom. The distance of Li−N is tuned from 2.069 Å in LiFEA to 4.367 Å in LiETFSI. This alteration enhances ionic separation, achieves a more balanced DN, and tunes the self-cleaning intensity for a reinforced SEI. Consequently, the fast charging/discharging capability of LMBs is progressively improved. This rationally tuned anion chemistry reshapes the interactions among Li+, anions, and solvents, presenting new prospects for advanced LMBs.  相似文献   
997.
We investigate periodic orbits and zoom-whirl behaviors around a Kerr Sen black hole with a rational number q in terms of three integers(z,w,v),from which one can immediately read off the number of leaves(or zooms),the ordering of the leaves,and the number of whirls.The characteristic of zoom-whirl periodic orbits is the precession of multi-leaf orbits in the strong-field regime.This feature is analogous to the counterpart in the Kerr space-time.Finally,we analyze the impact of the charge parameter b on the zoom-whirl periodic orbits.Compared to the periodic orbits around the Kerr black hole,it is found that typically lower energies are required for the same orbits in the Kerr Sen black hole.  相似文献   
998.
Generating many Majorana modes (MMs) within one single system is a constructive method for experimental observation of MMs in condensed-matter systems. In this paper, we show that by adding periodic δ-function kicks on the chemical potential, a large number of MMs can be generated in the one-dimensional p-wave superconductor system with second-neighbor couplings. The Floquet theory has been used to analyze the stroboscopic properties and the winding number can be used to characterize the topological properties. We have analyzed the influence of the kicking parameters and second-neighbor couplings on the topological phase transitions.  相似文献   
999.
探索原子核的壳层演化,验证奇特核的幻数结构是香港大学核物理研究的重要方向。目前,科研团队利用在束伽玛谱学技术已经研究了30Ne的N=20幻数消失和78Ni(Z=28,N=50)附近原子核的双幻数结构,而即将开展的53,56Ca在束伽玛谱学实验会对新幻数N=34的定量研究,以及到N=40核的壳层演化提供重要的数据。下一步的研究目标是探索100Sn(N=Z=50)的奇特结构,特别是研究它的第一个2+激发态与其邻近原子核的低激发态性质。100Sn处于质子滴线以及核天体快质子俘获路径上,因此,它的幻数结构及其临近原子核单粒子性能研究将会极大增强对核力和核合成机制的认识。为了进一步提高物理实验统计,香港大学在数量上增加了30% NaI(Tl)晶体从而全面升级了DALI2伽玛探测阵列。此外,为了探索远离稳定线核区的新物理,开展更高精度在束伽玛谱学实验,香港大学与中国科学院近代物理研究所、中国原子能科学研究院计划合作研制基于溴化镧晶体的新一代伽玛探测器阵列。这套阵列主要在兰州重离子加速器(HIRFL)和将来建成的强流重离子加速器(HIAF)等大科学装置上开展实验,从而在奇特核研究方面取得大量重要的成果,促进科研人员全面认识、理解核力以及天体核合成过程。Exploring the evolution of shell closures and examining the magicity of extremely exotic nuclei are the main research interests of HKU (University of Hong Kong) experimental nuclear physics group. The group has employed in-beam gamma-ray spectroscopy technique to investigate the vanishing of N=20 magicity in 30Ne (N=20) and the strong magicity in nuclei around 78Ni (Z=28, N=50). The approved future's experiment on spectroscopy of 53,56Ca, proposed by HKU, will give quantitative information for the "magic index" of N=34 and shell evolution toward N=40. The next goal is to investigate the structure of 100Sn (N=Z=50), particularly the energy of the first 2+ state, and the low-lying states in the neighboring nuclei. 100Sn lies on the proton drip-line and on the astrophysical rp-process path. Characterizing the magicity of 100Sn and the nature of single-particle states in its neighboring nuclei is therefore essential to the fundamental understanding of nuclear forces and nucleo-synthesis. To significantly increase the data statistics for our physics goals, HKU group has prepared the upgrade of gamma-ray spectrometer DALI2 with 30% more NaI(Tl) detectors integrated into a new array configuration. On the other hand, next significant insights into the structure of nuclei would require new gamma-ray detection array capable for higher precision gamma-ray spectroscopy. HKU group in collaboration with IMP and CIAE therefore proposes to construct a new-generation gamma-ray detection array based on the novel scintillator LaBr3(Ce) to explore the new physics in nuclei far from the valley of stability. Utilizing the radioactive beams at the Chinese large-scale facilities such as the Heavy Ion Research Facility in Lanzhou (HIRFL) in IMP and the future's High Intensity heavy-ion Accelerator Facility (HIAF), this novel LaBr3(Ce) array would lead to a significant boost to the frontiers of exotic-nuclei research, which will guide scientists towards the comprehensive and even beyond-traditional understanding of nuclear forces and nucleosynthesis.  相似文献   
1000.
The probability of gamma or X-ray interactions with important 14 antioxidants have been discussed for total photon interactions in the wide energy range of 1?keV–100?GeV using the WinXCOM code. The variations of mass attenuation coefficient (μρ), effective atomic number (Zeff) and electron density (Nel) with photon energy were plotted for total photon interactions. It was found that the values of μρ, Zeff and Nel depend on the incoming photon energy and chemical compositions of antioxidant. The highest values of these parameters were found at a low-energy zone where the photoelectric effect is the dominant interaction process. When antioxidants were compared with each other, it was seen that Zeff has the highest values for Oenin chloride and Delphinidin chloride which contain the Cl element. This investigation is thought to be useful for medical applications where radiation exposure is present.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号