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41.
An exfoliated poly(4,4′-oxybis(benzene)disulfide) (POBDS)/vermiculite (VMT) nanocomposite was prepared by using cyclo(4,4′-oxybis(benzene)disulfide) (COBDS) oligomers and cetyltrimethyl ammonium bromide exchanged VMT. The POBDS/VMT nanocomposites were fabricated in two steps. First, the COBDS oligomers were used to swell and exfoliate organo VMT to afford COBDS-VMT nanocomposite precursor. Subsequently, the exfoliated POBDS-VMT nanocomposite can be made via in situ and instant melt ring-opening polymerization of the COBDS-VMT nanocomposite precursor. High molecular weight POBDS polymer can be formed in a few minutes. The nano scale dispersion of VMT layers within POBDS polymer was confirmed by both the X-ray diffraction patterns and TEM examinations. This methodology provides a potential approach to synthesize high performance polymer nanocomposite. 相似文献
42.
灰色模型的最优化及其参数的直接求法 总被引:2,自引:0,他引:2
基于灰色模型的内涵表达式和白化方程响应式均为等比级数的观点,提出了一种不用求ago值、均值,不涉及灰色微分方程,白化微分方程概念,直接求灰色模型参数a,c的方法,通过此方法建立的新模型不仅从理论上可保证是在满足给定评价标准为模拟绝对误差平方和最小(或模拟相对误差平方和最小)、给定精度条件下的最优化模型,从而结束了灰色模型只有更优,没有最优的历史.并从理论上证明了新模型具有白化指数律重合性、白化系数律重合性,伸缩变换一致性.最后通过实例编程验证该方法具有可操作性,且预测精度高,效果好. 相似文献
43.
A layer of stratified combination composed of selected radiation shielding materials acquires better shielding property. Albedo
is used in such measurements as an integral measure ofγ-ray scattering. The stratified slabs of alternating heterogeneous layers have been found to have a virtual homogeneous property
with a definite effective atomic number. The angular distribution of back-scattered photons as well as the total number albedo
values for iron, aluminium and concrete in stratified combination for 662 keV and 1250 keV photons are reported. 相似文献
44.
R. Wei 《Discrete Mathematics》2002,250(1-3):291-298
Balanced sampling plans excluding contiguous units (or BSEC) were first introduced by Hedayat, Rao and Stufken in 1988. In this note, we discuss constructions of these designs having cyclic automorphisms. We use Langford sequences to construct all possible cyclic BSEC (or CBSEC) with block size 3 and λ = 1,2, which establishes the necessary and sufficient conditions for such designs. Some constructions of the balanced sampling plan avoiding adjacent units, a generalization of BSEC, are also given for fixed λ. 相似文献
45.
46.
Conducting drop tests to investigate impact behavior and identify failure mechanisms of small-size electronic products is
generally expensive and time-consuming. Nevertheless, strict drop/impact performance criteria for hand-held electronic products
such as cellular phones play a decisive role in the design because they must withstand unexpected shocks. The design of product
durability on impact has heavily relied on the designer's intuition and experience. In this study, a reliable drop/impact
simulation for a cellular phone is carried out using the explicit code LS-DYNA. Subsequently globallocal experimental verification
is accomplished by means of high-speed photography and impact response measurement. Using this methodology, we predict potential
damage locations in a cellular phone and compare them with real statistical data. It is envisaged that development of a reliable
methodology of drop/impact simulation will provide us with a powerful and efficient vehicle for improvement of the design
quality and reduction of the product development cycle. 相似文献
47.
48.
葛仙米对丁草胺胁迫的响应 总被引:2,自引:0,他引:2
研究了丁草胺对可食用蓝藻葛仙米(Nostoc sphaeroides)生理和代谢活性的影响.用不同浓度的丁草胺处理葛仙米,结果显示低浓度(5 mg·L-1)丁草胺使其光合作用、呼吸作用和光合系统Ⅱ活性增强,高浓度丁草胺(>5 mg·L-1)限制其光合作用、呼吸作用和光合系统Ⅱ活性.同时丁草胺对葛仙米膜结构和功能具有破坏作用,随着丁草胺处理浓度增大,质膜透性不断增大,丙二醛和超氧自由基阴离子含量升高;在低浓度丁草胺处理时,类胡萝卜素含量增加,超氧化物歧化酶(SOD)活性增强,高浓度丁草胺处理时,类胡萝卜素含量降低,SOD活性下降;表明葛仙米对低浓度的丁草胺胁迫具有一定的耐受能力,但高浓度的丁草胺对其生理和代谢构成威胁;针对目前葛仙米野生生境中丁草胺的用量,建议限制丁草胺在葛仙米产地的使用,以保护日益稀缺的葛仙米资源. 相似文献
49.
Jon Samseth Richard J. Spontak Kell Mortensen 《Journal of Polymer Science.Polymer Physics》1993,31(4):467-474
Poly(siloxaneimide) (PSI) segmented copolymers exhibit organized microdomains if the blocks are sufficiently incompatible. As with neat diblock and triblock copolymers, the processing route employed to prepare films of PSI materials is expected to influence the dimensions and/or morphology of the resultant microstructure. In this work, small-angle neutron scattering (SANS) is utilized to characterize the disordered microstructure found in films of a series of PSI copolymers which are subjected to solvent casting and various thermal treatments. Microstructural dimensions such as the periodicity and correlation length are deduced from the Teubner-Strey (TS) model for disordered microemulsions. The scattering intensity of each copolymer up to q = 5.0 nm?1, where q is the scattering vector, is found to scale as q?2.8+?0.1. Results indicate that processing the materials as cast films or as melt-pressed films allowed to cool slowly has a small, but discernible, effect on microstructural characteristics. SANS profiles of films quenched from elevated temperatures reveal a clear transition in microdomain periodicity, which correlates well with the glass transition temperature of the imide microphase in these and other materials of similar chemical structure. © 1993 John Wiley & Sons, Inc. 相似文献
50.
This paper reports on the experimental investigation of the dynamic large deflection response of a portal frame impacted at its midspan by a body moving at a certain speed. Both the deflection and velocity vs. time curves of the midspan and the dynamic history of a number of desired locations were recorded during the process of response. On the basis of the test data, the momentum and kinetic energy conversion between the frame and the moving body in the impact process are realized, and the occurrence and expansion of plastic regions are described. Investigation results show that the initial collision is approximately ideally inelastic, and that the elastic deformation plays a considerable role in the response though the input energy is much larger than the maximum elastic energy capacity of the beam member; therefore, in a general impact, the energy ratio should not be regarded as a sufficient criterion for a rigid—plastic solution. The ratios of the impulse transferred to and the energy absorbed by the frame in the initial collision to that carried by the moving body before impact is only related to the ratiobetween the equivalent mass of the frame paticipating in the initial collision and the mass of the impacting body, having nothing to do with the impacting velocity to a certain extent. 相似文献