水热法制备均一形貌的ZnO微米棒

以Zn（Ac）2· 2H2O、KI和N2H4· H2O反应物,在未使用任何表面活性剂的简单水热反应体系中制得了ZnO微米棒.采用X射线粉末衍射仪（XRD）、扫描电子显微镜（SEM）对产物的晶体结构、形貌进行了表征和分析.测试结果表明,所得产物为六方纤锌矿结构ZnO微米棒,平均直径为1μm,长度4μm.     

基于近红外谱形分析的中药提取过程终点判断

中药提取是中药生产的重要环节,其终点的判断直接影响到中药疗效与制药成本.本文提出一种基于近红外光谱谱形分析的典型中药提取过程终点判断方法,该方法为满足工业需求以水的光谱作为近红外参考光谱,根据最小二乘拟合原理去除基线,并且采用滑动窗口相关系数的方法描述谱形差异.实验结果表明：该方法能有效判断中药提取过程终点,方便快速,适合于在线过程分析.     

电子电气产品中挥发性有机化合物的释放量测定

采用小型释放舱-热脱附-气相色谱-质谱联用技术测定了电子电气产品中8种挥发性有机化合物（苯、甲苯、邻二甲苯、间二甲苯、对二甲苯、乙苯、乙酸丁酯和苯乙烯）的释放量.对一级脱附参数（一级脱附温度、一级脱附流量、一级脱附时间）、冷阱温度、捕集管脱附温度、脱附时间条件进行了优化,并进行了线性关系、回收率、精密度等试验.结果表明：本方法可用于测定电子电气产品中释放的8种常见的挥发性有机化合物的释放量,线性范围10-1000ng,当采样量为6L时,定量限为1.7μg/m3,回收率范围在89.5％-106％之间,相对标准偏差小于7％.     

褐煤腐植酸中微量金属元素的赋存状态

以褐煤为原料,采用碱溶酸析法提取腐植酸,光栅摄谱法定性确定含有金属元素钙、铝、铜和钛.采用逐级提取分离法将腐植酸中金属元素分为：可交换态、碳酸盐结合态、氧化物结合态、有机物结合态、残渣态;采用ICP-AES定量测定腐植酸中微量金属元素的赋存状态.结果表明：残渣态铜占99.13％;有机物结合态铝占74.84％、残渣态铝占21.05％;有机物结合态钛占9.04％、残渣态钛占80.18％;可交换态钙占14.14％、有机物结合态钙占11.82％、残渣态钙占68.27％.所以,腐植酸中的铜主要是以残渣态存在,钛和铝主要是以有机物结合态和残渣态存在,钙主要是以可交换态、有机物结合态和残渣态存在.可交换态和氧化物结合态中的金属离子主要是钙、次之是铝;有机物结合态中的金属离子主要是钙、次之是铝和铜;有机物结合态中的金属离子主要是铝、次之是钙.     

The method of variation on parameters for integration of a generalized Birkhoffian system

This paper focuses on studying the integration method of a generalized Birkhoffian system.The method of variation on parameters for the dynamical equations of a generalized Birkhoffian system is presented.The procedure for solving the problem can be divided into two steps:the first step,a system of auxiliary equations is constructed and its general solution is given;the second step,the parameters are varied,and the solution of the problem is obtained by using the properties of generalized canonical transformation.The method of variation on parameters for the generalized Birkhoffian system is of universal significance,and we take a nonholonomic system and a nonconservative system as examples to illustrate the application of the results of this paper.     

New formula for drag coefficient of cylindrical particles

The drag force on a cylindrical particle is calculated using lattice Boltzmann method.The results show that the drag coefficient of a particle with different orientation angles decreases with increasing Reynolds number.When the principal axis of the particle is parallel to flow,the drag coefficient is much larger than that of others and decreases fastest with increasing Reynolds number,which becomes more obvious with increasing particle aspect ratio.When the principal axis of the particle is inclined to flo...     

The bivariate noncentral chi-square distribution - A compound distribution approach

This paper proposes the bivariate noncentral chi-square (BNC) distribution by compounding the Poisson probabilities with the bivariate central chi-square distribution. The probability density and cumulative distribution functions of the joint distribution of the two noncentral chi-square variables are derived for arbitrary values of the correlation coefficient, degrees of freedom(s), and noncentrality parameters. Computational procedures to calculate the upper tail probabilities as well as the percentile points for selected values of the parameters, for both equal and unequal degrees of freedom, are discussed. The graphical representation of the distribution for different values of the parameters are provided. Some applications of the distribution are outlined.     

Non-linear response of a magneto-elastic translating beam with prismatic joint for higher resonance conditions

The non-linear response of a magneto-elastic translating beam having prismatic joint for higher resonance conditions is studied. A periodically varying transverse magnetic field is applied to the system. Two frequencies of prismatic motion and oscillating transverse magnetic field are implemented to the system. The method of multiple scales as one of the perturbation techniques is used to derive two first order ordinary differential equations that govern the time variation of the amplitude and phase of the response. Then a stability analysis is conducted for subharmonic resonance and simultaneous resonance conditions. A parametric study is performed to investigate the effect of magnetic field strength, amplitude of prismatic motion, damping and payload mass on the frequency response curves for both the resonance conditions. The catastrophic failure of the system may occur due to the presence of saddle-node and pitchfork bifurcations. The results obtained by method of multiple scales are compared with those obtained by numerically integrating the reduced equations and are found to be in good agreement. The developed results can be applied to control the vibration of a beam with prismatic joint subjected to magnetic field for third order subharmonic resonance and simultaneous resonance conditions.     

Experimental investigation in pool boiling heat transfer of ammonia/water mixture and heat transfer correlations

The nucleate pool boiling heat transfer coefficient of ammonia/water mixture was investigated on a cylindrical heated surface at low pressure of 4-8 bar and at low mass fraction of 0 < x_NH3 < 0.3 and at different heat flux. The effect of mass fraction, heat flux and pressure on boiling heat transfer coefficient was studied. The results indicate that the heat transfer coefficient in the mixture decreases with increase in ammonia mass fraction, increases with increase in heat flux and pressure in the investigated range. The measured heat transfer coefficient was compared with existing correlations. The experimental data were predicted with an accuracy of ±20% by the correlation of Calus&Rice, correlation of Stephan-Koorner and Inoue-Monde correlation for ammonia/water mixture in the investigated range of low ammonia mass fraction. The empirical constant of the first two correlations is modified by fitting the correlation to the present experimental data. The modified Calus&Rice correlation predicts the present experimental data with an accuracy of ±18% and the modified Stephan-Koorner correlation with an accuracy of ±16%.     

Reconstruction of multiply-scattered arrivals from the cross-correlation of waves excited by random noise sources in a heterogeneous dissipative medium

Imagining a medium composed of an arbitrary distribution of point-like heterogeneities, we study the reconstruction of scattered waves in Green's function derived from the cross-correlation function of waves excited by random noise sources of which the distribution is stationary and homogeneous. We show that the reconstruction process is intimately related to generalized forms of the optical theorem. The role of absorption in the formulation of the theorem is discussed. The reconstruction of multiply-scattered arrivals from the cross-correlation of two random wavefields is demonstrated to all orders of scattering for the simple case of two point scatterers, through application of the optical theorem for a single scatterer. In the case of N point scatterers, the cross-correlation of two Green's functions is expressed in the form of Feynman-like diagrams. The wavepaths that contribute to the reconstruction of an arbitrary multiply-scattered arrival of Green's function are identified. Repeated application of the generalized optical theorem, formulated as a diagrammatic rule, demonstrates the destructive interference between all spurious multiply-scattered arrivals.